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Solid fuel refers to various forms of
solid Solid is a state of matter where molecules are closely packed and can not slide past each other. Solids resist compression, expansion, or external forces that would alter its shape, with the degree to which they are resisted dependent upon the ...
material that can be burnt to release energy, providing heat and light through the process of
combustion Combustion, or burning, is a high-temperature exothermic redox chemical reaction between a fuel (the reductant) and an oxidant, usually atmospheric oxygen, that produces oxidized, often gaseous products, in a mixture termed as smoke. Combustion ...
. Solid fuels can be contrasted with liquid fuels and gaseous fuels. Common examples of solid fuels include
wood Wood is a structural tissue/material found as xylem in the stems and roots of trees and other woody plants. It is an organic materiala natural composite of cellulosic fibers that are strong in tension and embedded in a matrix of lignin t ...
, charcoal,
peat Peat is an accumulation of partially Decomposition, decayed vegetation or organic matter. It is unique to natural areas called peatlands, bogs, mires, Moorland, moors, or muskegs. ''Sphagnum'' moss, also called peat moss, is one of the most ...
,
coal Coal is a combustible black or brownish-black sedimentary rock, formed as rock strata called coal seams. Coal is mostly carbon with variable amounts of other Chemical element, elements, chiefly hydrogen, sulfur, oxygen, and nitrogen. Coal i ...
, hexamine fuel tablets, dry dung,
wood pellets Pellet fuels (or pellets) are a type of solid fuel made from compressed organic material. Pellets can be made from any one of five general categories of Biomass (energy), biomass: industrial waste and co-products, food waste, Crop residue, agricul ...
,
corn Maize (; ''Zea mays''), also known as corn in North American English, is a tall stout Poaceae, grass that produces cereal grain. It was domesticated by indigenous peoples of Mexico, indigenous peoples in southern Mexico about 9,000 years ago ...
,
wheat Wheat is a group of wild and crop domestication, domesticated Poaceae, grasses of the genus ''Triticum'' (). They are Agriculture, cultivated for their cereal grains, which are staple foods around the world. Well-known Taxonomy of wheat, whe ...
,
rice Rice is a cereal grain and in its Domestication, domesticated form is the staple food of over half of the world's population, particularly in Asia and Africa. Rice is the seed of the grass species ''Oryza sativa'' (Asian rice)—or, much l ...
, rye, and other
grains A grain is a small, hard, dry fruit ( caryopsis) – with or without an attached hull layer – harvested for human or animal consumption. A grain crop is a grain-producing plant. The two main types of commercial grain crops are cereals and le ...
. Solid fuels are extensively used in rocketry as solid propellants. Solid fuels have been used throughout human history to create fire and solid fuel is still in widespread use throughout the world in the present day. Solid fuel from
biomass Biomass is a term used in several contexts: in the context of ecology it means living organisms, and in the context of bioenergy it means matter from recently living (but now dead) organisms. In the latter context, there are variations in how ...
is regarded as a
renewable energy Renewable energy (also called green energy) is energy made from renewable resource, renewable natural resources that are replenished on a human lifetime, human timescale. The most widely used renewable energy types are solar energy, wind pow ...
source which can contribute to
climate change mitigation Climate change mitigation (or decarbonisation) is action to limit the greenhouse gases in the atmosphere that cause climate change. Climate change mitigation actions include energy conservation, conserving energy and Fossil fuel phase-out, repl ...
efforts. Solid fuel from
fossil fuel A fossil fuel is a flammable carbon compound- or hydrocarbon-containing material formed naturally in the Earth's crust from the buried remains of prehistoric organisms (animals, plants or microplanktons), a process that occurs within geolog ...
s (i.e.
coal Coal is a combustible black or brownish-black sedimentary rock, formed as rock strata called coal seams. Coal is mostly carbon with variable amounts of other Chemical element, elements, chiefly hydrogen, sulfur, oxygen, and nitrogen. Coal i ...
) is not a renewable energy.


Types


Biomass

Biomass that is used for energy production can be processed into solid fuels but also into liquid or gaseous fuels. In comparison, the term
biofuel Biofuel is a fuel that is produced over a short time span from Biomass (energy), biomass, rather than by the very slow natural processes involved in the formation of fossil fuels such as oil. Biofuel can be produced from plants or from agricu ...
is nowadays mainly (but not exclusively) used for ''liquid'' or ''gaseous'' fuels, used for transportation.The EIA states: "Biofuels are transportation fuels such as ethanol and biodiesel that are made from biomass materials." https://www.eia.gov/energyexplained/index.php?page=biofuel_home Pellet fuels are made from compressed organic matter or biomass. Pellets can be made from any one of five general categories of biomass: industrial waste and co-products,
food waste The causes of food going uneaten are numerous and occur throughout the food system, during food production, production, food processing, processing, Food distribution, distribution, Grocery store, retail and food service sales, and Social clas ...
, agricultural residues, energy crops, and untreated lumber. Wood pellets are the most common type of pellet fuel.


Wood

Wood fuel can refer to several fuels such as
firewood Firewood is any wooden material that is gathered and used for fuel. Generally, firewood is not heavily processed, and is in some sort of firelog, recognizable log or branch form, compared to other forms of wood fuel like pellet fuel, pellets. ...
, charcoal, ''wood chips'' sheets, pellets, and sawdust. The particular form used depends upon factors such as source, quantity, quality and application. In many areas, wood is the most easily available form of fuel, requiring no
tool A tool is an Physical object, object that can extend an individual's ability to modify features of the surrounding environment or help them accomplish a particular task. Although many Tool use by animals, animals use simple tools, only human bei ...
s in the case of picking up dead wood, or few tools. Today,
burning Combustion, or burning, is a high-temperature exothermic redox chemical reaction between a fuel (the reductant) and an oxidant, usually atmospheric oxygen, that produces oxidized, often gaseous products, in a mixture termed as smoke. Combust ...
of wood is the largest use of
energy Energy () is the physical quantity, quantitative physical property, property that is transferred to a physical body, body or to a physical system, recognizable in the performance of Work (thermodynamics), work and in the form of heat and l ...
derived from a solid fuel
biomass Biomass is a term used in several contexts: in the context of ecology it means living organisms, and in the context of bioenergy it means matter from recently living (but now dead) organisms. In the latter context, there are variations in how ...
. Wood fuel can be used for
cooking Cooking, also known as cookery or professionally as the culinary arts, is the art, science and craft of using heat to make food more palatable, digestible, nutritious, or Food safety, safe. Cooking techniques and ingredients vary widely, from ...
and heating, and occasionally for fueling
steam engine A steam engine is a heat engine that performs Work (physics), mechanical work using steam as its working fluid. The steam engine uses the force produced by steam pressure to push a piston back and forth inside a Cylinder (locomotive), cyl ...
s and steam
turbines A turbine ( or ) (from the Greek , ''tyrbē'', or Latin ''turbo'', meaning vortex) is a rotary mechanical device that extracts energy from a fluid flow and converts it into useful work. The work produced can be used for generating electrical ...
that generate electricity. Wood may be used indoors in a furnace, stove, or fireplace, or outdoors in a furnace,
campfire A campfire is a fire at a campsite that provides light and warmth, and heat for cooking. It can also serve as a beacon, and an insect and predator deterrent. Established campgrounds often provide a stone or steel fire ring for safety. Campfires ...
, or
bonfire A bonfire is a large and controlled outdoor fire, used for waste disposal or as part of a religious feast, such as Saint John's Eve. Etymology The earliest attestations date to the late 15th century, with the Catholicon Anglicum spelling i ...
. As with any
fire Fire is the rapid oxidation of a fuel in the exothermic chemical process of combustion, releasing heat, light, and various reaction Product (chemistry), products. Flames, the most visible portion of the fire, are produced in the combustion re ...
, burning wood fuel creates numerous by-products, some of which may be useful (heat and steam), and others that are undesirable, irritating or dangerous. When harvested in a sustainable fashion wood is usually considered to be a renewable solid fuel (
renewable energy Renewable energy (also called green energy) is energy made from renewable resource, renewable natural resources that are replenished on a human lifetime, human timescale. The most widely used renewable energy types are solar energy, wind pow ...
). There is debate as to whether burning wood can be considered carbon neutral, as technically the wood cannot release more carbon than was sequestered during its growth, although this does not take account of other impacts such as deforestation and rotting has on the carbon footprint.


Peat

Peat fuel is an accumulation of partially decayed
vegetation Vegetation is an assemblage of plants and the ground cover they provide. It is a general term, without specific reference to particular Taxon, taxa, life forms, structure, Spatial ecology, spatial extent, or any other specific Botany, botanic ...
or organic matter that can be burnt once sufficiently dried. It is used widely in the country districts of
Ireland Ireland (, ; ; Ulster Scots dialect, Ulster-Scots: ) is an island in the North Atlantic Ocean, in Northwestern Europe. Geopolitically, the island is divided between the Republic of Ireland (officially Names of the Irish state, named Irelan ...
and
Scotland Scotland is a Countries of the United Kingdom, country that is part of the United Kingdom. It contains nearly one-third of the United Kingdom's land area, consisting of the northern part of the island of Great Britain and more than 790 adjac ...
where alternatives are absent or expensive. It has a relatively low calorific value, even after essential drying.


Fossil fuels


Coal

Coal is a combustible black or brownish-black
sedimentary rock Sedimentary rocks are types of rock (geology), rock formed by the cementation (geology), cementation of sediments—i.e. particles made of minerals (geological detritus) or organic matter (biological detritus)—that have been accumulated or de ...
usually occurring in rock strata in layers or veins called coal beds or coal seams. Throughout history, coal has been used as an energy resource, primarily burned for the production of electricity and heat, and is also used for industrial purposes, such as refining metals. Coal is the largest source of energy for the generation of electricity worldwide, as well as one of the largest worldwide The extraction of coal, its use in energy production and its byproducts are all associated with environmental and health effects. Variations such as smokeless coal can be formed naturally in the form of anthracite, a metamorphosed type of coal with a very high carbon content that gives off a smokeless flame when set alight. It is an important type of smokeless fuel.


Coke

Coke is a fuel with few impurities and a high
carbon Carbon () is a chemical element; it has chemical symbol, symbol C and atomic number 6. It is nonmetallic and tetravalence, tetravalent—meaning that its atoms are able to form up to four covalent bonds due to its valence shell exhibiting 4 ...
content, usually made from
coal Coal is a combustible black or brownish-black sedimentary rock, formed as rock strata called coal seams. Coal is mostly carbon with variable amounts of other Chemical element, elements, chiefly hydrogen, sulfur, oxygen, and nitrogen. Coal i ...
. It is the solid
carbon Carbon () is a chemical element; it has chemical symbol, symbol C and atomic number 6. It is nonmetallic and tetravalence, tetravalent—meaning that its atoms are able to form up to four covalent bonds due to its valence shell exhibiting 4 ...
aceous material derived from
destructive distillation Destructive distillation is a chemical process in which decomposition of unprocessed material is achieved by heating it to a high temperature; the term generally applies to processing of organic material in the absence of air or in the presence o ...
of low-ash, low-sulfur
bituminous coal Bituminous coal, or black coal, is a type of coal containing a tar-like substance called bitumen or asphalt. Its coloration can be black or sometimes dark brown; often there are well-defined bands of bright and dull material within the coal seam, ...
. Cokes made from coal are grey, hard, and porous. While coke can be formed naturally, the commonly used form is man-made. The form known as
petroleum coke Petroleum coke, abbreviated coke, pet coke or petcoke, is a final carbon-rich solid material that derives from oil refinery, oil refining, and is one type of the group of fuels referred to as Coke (fuel), cokes. Petcoke is the coke that, in parti ...
, or pet coke, is derived from oil refinery coker units or other cracking processes.


Smokeless fuel

Solid fuels which produce little smoke or volatiles are made from powdered anthracite coal and supplied in the form of briquettes usually for domestic use either in stoves or open fireplaces. The fuel is replacing coal as a fuel for open fires because of the reduction in particulate emissions and its increased efficiency. Smokeless fuel burns at a higher temperature and more slowly than a coal fire. The term also includes charcoal, made by restricted combustion of dry wood and widely used at open air
barbecue Barbecue or barbeque (often shortened to BBQ worldwide; barbie or barby in Australia and New Zealand) is a term used with significant regional and national variations to describe various cooking methods that employ live fire and smoke to coo ...
s to cook food on an open fire.


Solid fuels for special applications


Rocket propellant

Solid rocket propellant consists of a solid oxidizer (such as
ammonium nitrate Ammonium nitrate is a chemical compound with the formula . It is a white crystalline salt consisting of ions of ammonium and nitrate. It is highly soluble in water and hygroscopic as a solid, but does not form hydrates. It is predominantly us ...
) bound with flakes or powders of energy compounds (such as
RDX RDX (Research Department Explosive or Royal Demolition Explosive) or hexogen, among other names, is an organic compound with the formula (CH2N2O2)3. It is white, odorless, and tasteless, widely used as an explosive. Chemically, it is classified ...
) plus binders, plasticizers, stabilizers, and other additives. Solid propellant is much easier to store and handle than liquid propellant, and has a higher energy density so requires less space for the same amount of stored energy.


Calorific value

The heat available from each type of fuel is variable, and depends on the
carbon Carbon () is a chemical element; it has chemical symbol, symbol C and atomic number 6. It is nonmetallic and tetravalence, tetravalent—meaning that its atoms are able to form up to four covalent bonds due to its valence shell exhibiting 4 ...
and
hydrogen Hydrogen is a chemical element; it has chemical symbol, symbol H and atomic number 1. It is the lightest and abundance of the chemical elements, most abundant chemical element in the universe, constituting about 75% of all baryon, normal matter ...
content, as well as non-combustible or ash and water content. One measure of the heat produced by burning is the
heat of combustion The heating value (or energy value or calorific value) of a substance, usually a fuel or food (see food energy), is the amount of heat released during the combustion of a specified amount of it. The ''calorific value'' is the total energy relea ...
, an exact measure usually determined using bomb calorimetry and demanding complete combustion to carbon dioxide and water. Gaseous fuels like
methane Methane ( , ) is a chemical compound with the chemical formula (one carbon atom bonded to four hydrogen atoms). It is a group-14 hydride, the simplest alkane, and the main constituent of natural gas. The abundance of methane on Earth makes ...
have higher values than solid fuels like
coal Coal is a combustible black or brownish-black sedimentary rock, formed as rock strata called coal seams. Coal is mostly carbon with variable amounts of other Chemical element, elements, chiefly hydrogen, sulfur, oxygen, and nitrogen. Coal i ...
.
Peat Peat is an accumulation of partially Decomposition, decayed vegetation or organic matter. It is unique to natural areas called peatlands, bogs, mires, Moorland, moors, or muskegs. ''Sphagnum'' moss, also called peat moss, is one of the most ...
exhibits the lowest value of all common fuels. Thus methane has an HHV (Higher heating value) of 55.50 MJ/kg, the highest value of common fuels.
Diesel fuel Diesel fuel, also called diesel oil, heavy oil (historically) or simply diesel, is any liquid fuel specifically designed for use in a diesel engine, a type of internal combustion engine in which fuel ignition takes place without a spark as a re ...
has an HHV value of 44.80 MJ/kg and anthracite coal a value of 32.50 MJ/kg. Moisture and ash-free
firewood Firewood is any wooden material that is gathered and used for fuel. Generally, firewood is not heavily processed, and is in some sort of firelog, recognizable log or branch form, compared to other forms of wood fuel like pellet fuel, pellets. ...
has a lower value of 21.70 MJ/kg while dry
peat Peat is an accumulation of partially Decomposition, decayed vegetation or organic matter. It is unique to natural areas called peatlands, bogs, mires, Moorland, moors, or muskegs. ''Sphagnum'' moss, also called peat moss, is one of the most ...
has the lowest value of all common fuels of about 15.00 MJ/kg. These are somewhat ideal values and the actual heat realized by any fuel will depend on the fireplace or
combustion chamber A combustion chamber is part of an internal combustion engine in which the air–fuel ratio, fuel/air mix is burned. For steam engines, the term has also been used for an extension of the Firebox (steam engine), firebox which is used to allow a mo ...
used and its design for example. However they do give a useful guide to the heat available from any fuel. Dry wood has roughly two thirds the calorific value of coal so a greater weight is needed to make the same amount of heat.


Cost and transport

Solid fuels, compared to
liquid fuel Liquid fuels are combustible or energy-generating molecules that can be harnessed to create mechanical energy, usually producing kinetic energy; they also must take the shape of their container. It is the fumes of liquid fuels that are flammable ...
s or gaseous fuels, are often cheaper, easier to extract, more stable to transport and in many places are more readily available.
Coal Coal is a combustible black or brownish-black sedimentary rock, formed as rock strata called coal seams. Coal is mostly carbon with variable amounts of other Chemical element, elements, chiefly hydrogen, sulfur, oxygen, and nitrogen. Coal i ...
, in particular, is utilized in the generation of 38% of the world's
electricity Electricity is the set of physical phenomena associated with the presence and motion of matter possessing an electric charge. Electricity is related to magnetism, both being part of the phenomenon of electromagnetism, as described by Maxwel ...
because it is less expensive than its liquid and gas counterparts.


Damage to health and the environment

Solid fuels require more destructive methods to extract/burn and often have higher carbon, nitrate and sulphate emissions. With the exception of sustainable wood/biomass solid fuel is normally considered non-renewable as it requires thousands of years to form. Solid fuels are composed of organic materials and can contribute to poor
air quality Air pollution is the presence of substances in the Atmosphere of Earth, air that are harmful to humans, other living beings or the environment. Pollutants can be Gas, gases like Ground-level ozone, ozone or nitrogen oxides or small particles li ...
. The burning of solid fuels releases more organic aerosol than
liquefied petroleum gas Liquefied petroleum gas, also referred to as liquid petroleum gas (LPG or LP gas), is a fuel gas which contains a flammable mixture of hydrocarbon gases, specifically propane, Butane, ''n''-butane and isobutane. It can also contain some ...
and releases many
volatile organic compound Volatile organic compounds (VOCs) are organic compounds that have a high vapor pressure at room temperature. They are common and exist in a variety of settings and products, not limited to Indoor mold, house mold, Upholstery, upholstered furnitur ...
s, which can contribute to poor
air quality Air pollution is the presence of substances in the Atmosphere of Earth, air that are harmful to humans, other living beings or the environment. Pollutants can be Gas, gases like Ground-level ozone, ozone or nitrogen oxides or small particles li ...
through the formation of secondary pollutants such as ground level ozone and secondary organic aerosol. The emissions from solid fuels are major drivers of poor
air quality Air pollution is the presence of substances in the Atmosphere of Earth, air that are harmful to humans, other living beings or the environment. Pollutants can be Gas, gases like Ground-level ozone, ozone or nitrogen oxides or small particles li ...
in regions where solid fuels are a dominant
fuel A fuel is any material that can be made to react with other substances so that it releases energy as thermal energy or to be used for work (physics), work. The concept was originally applied solely to those materials capable of releasing chem ...
source.


See also

* Biomass briquettes *
Fossil fuel A fossil fuel is a flammable carbon compound- or hydrocarbon-containing material formed naturally in the Earth's crust from the buried remains of prehistoric organisms (animals, plants or microplanktons), a process that occurs within geolog ...
* Hindenburg light *
Nuclear power Nuclear power is the use of nuclear reactions to produce electricity. Nuclear power can be obtained from nuclear fission, nuclear decay and nuclear fusion reactions. Presently, the vast majority of electricity from nuclear power is produced by ...
* Synthetic fuel


References


External links

* {{Authority control