Sodium Manganate
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Sodium manganate is the
inorganic compound An inorganic compound is typically a chemical compound that lacks carbon–hydrogen bonds⁠that is, a compound that is not an organic compound. The study of inorganic compounds is a subfield of chemistry known as ''inorganic chemistry''. Inorgan ...
with the
formula In science, a formula is a concise way of expressing information symbolically, as in a mathematical formula or a ''chemical formula''. The informal use of the term ''formula'' in science refers to the general construct of a relationship betwe ...
Na2 Mn O4. This deep green solid is a rarely encountered analogue of the related salt K2MnO4.
Sodium Sodium is a chemical element; it has Symbol (chemistry), symbol Na (from Neo-Latin ) and atomic number 11. It is a soft, silvery-white, highly reactive metal. Sodium is an alkali metal, being in group 1 element, group 1 of the peri ...
manganate is rare because it cannot be readily prepared from the oxidation of manganese dioxide and sodium hydroxide. Instead this oxidation reaction tends to stop at producing
sodium hypomanganate Sodium is a chemical element; it has symbol Na (from Neo-Latin ) and atomic number 11. It is a soft, silvery-white, highly reactive metal. Sodium is an alkali metal, being in group 1 of the periodic table. Its only stable isotope i ...
, Na3MnO4, and even this Mn(V) salt is unstable in solution. Sodium manganate can be produced by reduction of sodium permanganate under basic conditions: :4 NaOH + 4NaMnO4 → 4 Na2MnO4 + 2 H2O + O2 Because NaMnO4 is difficult to prepare,
sodium permanganate Sodium permanganate is the inorganic compound with the formula sodium, NaPermanganate, MnO4. It is closely related to the more commonly encountered potassium permanganate, but it is generally less desirable, because it is more expensive to produce ...
is more expensive than
potassium permanganate Potassium permanganate is an inorganic compound with the chemical formula KMnO4. It is a purplish-black crystalline salt, which dissolves in water as K+ and ions to give an intensely pink to purple solution. Potassium permanganate is widely us ...
.


References

Manganates Sodium compounds {{Inorganic-compound-stub