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A sodium-cooled fast reactor is a
fast neutron reactor A fast-neutron reactor (FNR) or fast-spectrum reactor or simply a fast reactor is a category of nuclear reactor in which the fission nuclear chain reaction, chain reaction is sustained by fast neutrons (carrying energies above 1 Electronvolt, MeV, ...
cooled by liquid
sodium Sodium is a chemical element; it has Symbol (chemistry), symbol Na (from Neo-Latin ) and atomic number 11. It is a soft, silvery-white, highly reactive metal. Sodium is an alkali metal, being in group 1 element, group 1 of the peri ...
. The initials SFR in particular refer to two
Generation IV reactor Generation IV (Gen IV) reactors are nuclear reactor design technologies that are envisioned as successors of generation III reactors. The Generation IV International Forum (GIF) – an international organization that coordinates the development of ...
proposals, one based on existing
liquid metal cooled reactor A liquid metal cooled nuclear reactor (LMR) is a type of nuclear reactor where the primary coolant is a liquid metal. Liquid metal cooled reactors were first adapted for breeder reactor power generation. They have also been used to power nuclear ...
(LMFR) technology using
mixed oxide fuel Mixed oxide fuel (MOX fuel) is nuclear fuel that contains more than one oxide of fissile material, usually consisting of plutonium blended with natural uranium, reprocessed uranium, or depleted uranium. MOX fuel is an alternative to the low-e ...
(MOX), and one based on the metal-fueled
integral fast reactor The integral fast reactor (IFR), originally the advanced liquid-metal reactor (ALMR), is a design for a nuclear reactor using fast neutrons and no neutron moderator (a "fast" reactor). IFRs can breed more fuel and are distinguished by a nuclea ...
. Several sodium-cooled fast reactors have been built and some are in current operation, particularly in Russia. Others are in planning or under construction. For example, in the US, TerraPower (using its Traveling Wave technology) is building its own reactors along with molten salt energy storage in partnership with GEHitachi's PRISM integral fast reactor design, under the ''Natrium'' appellation in
Kemmerer, Wyoming Kemmerer is the largest city in and the county seat of Lincoln County, Wyoming, United States. Its population was 2,415 at the 2020 census. History Explorer John C. Frémont discovered coal in the area during his second expedition in 1843. Th ...
. Aside from the Russian experience, Japan, India, China, France and the USA are investing in the technology.


Fuel cycle

The
nuclear fuel cycle The nuclear fuel cycle, also known as the nuclear fuel chain, describes the series of stages that nuclear fuel undergoes during its production, use, and recycling or disposal. It consists of steps in the ''front end'', which are the preparation o ...
employs a full
actinide The actinide () or actinoid () series encompasses at least the 14 metallic chemical elements in the 5f series, with atomic numbers from 89 to 102, actinium through nobelium. Number 103, lawrencium, is also generally included despite being part ...
recycle with two major options: One is an intermediate-size (150–600 MWe) sodium-cooled reactor with
uranium Uranium is a chemical element; it has chemical symbol, symbol U and atomic number 92. It is a silvery-grey metal in the actinide series of the periodic table. A uranium atom has 92 protons and 92 electrons, of which 6 are valence electrons. Ura ...
-
plutonium Plutonium is a chemical element; it has symbol Pu and atomic number 94. It is a silvery-gray actinide metal that tarnishes when exposed to air, and forms a dull coating when oxidized. The element normally exhibits six allotropes and four ...
-minor-actinide-
zirconium Zirconium is a chemical element; it has Symbol (chemistry), symbol Zr and atomic number 40. First identified in 1789, isolated in impure form in 1824, and manufactured at scale by 1925, pure zirconium is a lustrous transition metal with a greyis ...
metal alloy fuel, supported by a fuel cycle based on pyrometallurgical reprocessing in facilities integrated with the reactor. The second is a medium to large (500–1,500 MWe) sodium-cooled reactor with mixed uranium-plutonium oxide fuel, supported by a fuel cycle based upon advanced aqueous processing at a central location serving multiple reactors. The outlet temperature is approximately 510–550 degrees C for both.


Sodium coolant

Liquid metallic sodium may be used to carry heat from the core.
Sodium Sodium is a chemical element; it has Symbol (chemistry), symbol Na (from Neo-Latin ) and atomic number 11. It is a soft, silvery-white, highly reactive metal. Sodium is an alkali metal, being in group 1 element, group 1 of the peri ...
has only one stable isotope, sodium-23, which is a weak neutron absorber. When it does absorb a neutron it produces
sodium-24 There are 20 isotopes of sodium (11Na), ranging from to (except for the still-unknown 36Na and 38Na), and five isomers (two for , and one each for , , and ). is the only stable (and the only primordial) isotope. It is considered a monoisotopi ...
, which has a half-life of 15 hours and decays to stable isotope
magnesium-24 Magnesium (12Mg) naturally occurs in three stable isotopes: , , and . There are 19 radioisotopes that have been discovered, ranging from to (with the exception of ). The longest-lived radioisotope is with a half-life of . The lighter isotopes m ...
.


Pool or loop type

The two main design approaches to sodium-cooled reactors are pool type and loop type. In the pool type, the primary coolant is contained in the main reactor vessel, which therefore includes the reactor core and a
heat exchanger A heat exchanger is a system used to transfer heat between a source and a working fluid. Heat exchangers are used in both cooling and heating processes. The fluids may be separated by a solid wall to prevent mixing or they may be in direct contac ...
. The US
EBR-2 Experimental Breeder Reactor-II (EBR-II) was a sodium-cooled fast reactor designed, built and operated by Argonne National Laboratory at the National Reactor Testing Station in Idaho. It was shut down in 1994. Custody of the reactor was transfe ...
, French
Phénix Phénix (French for phoenix) was a small-scale (gross 264/net 233 MWe) prototype fast breeder reactor, located at the Marcoule nuclear site, near Orange, France. It was a pool-type liquid-metal fast breeder reactor cooled with liquid sodium. ...
and others used this approach, and it is used by India's
Prototype Fast Breeder Reactor The Prototype Fast Breeder Reactor (PFBR) is a 500 MWe sodium-cooled, fast breeder reactor that is being constructed at the same site as the Madras Atomic Power Station in Kokkilamedu, near Kalpakkam, in Tamil Nadu state, India. The Indira ...
and China's
CFR-600 The CFR-600 (Xiapu fast reactor pilot project) is a sodium-cooled pool-type fast-neutron nuclear reactor under construction in Xiapu County, Fujian province, China, on Changbiao Island. It is a generation IV demonstration project by the Chi ...
. In the loop type, the heat exchangers are outside the reactor tank. The French
Rapsodie Rapsodie was an experimental nuclear reactor built in Cadarache in France. It was France's first fast reactor, and first achieved criticality in 1967. Rapsodie was a sodium-cooled fast neutron loop-type reactor with a thermal output of 40MW and ...
, British
Prototype Fast Reactor Dounreay (; ) is a small settlement and the site of two large nuclear establishments on the north coast of Caithness in the Highland (council area), Highland area of Scotland. It is on the A836 road west of Thurso. The nuclear establishments w ...
and others used this approach.


Advantages

All fast reactors have several advantages over the current fleet of water based reactors in that the waste streams are significantly reduced. Crucially, when a reactor runs on fast neutrons, the plutonium isotopes are far more likely to fission upon absorbing a neutron. Thus, fast neutrons have a smaller chance of being captured by the uranium and plutonium, but when they are captured, have a much bigger chance of causing a fission. This means that the inventory of
transuranic waste Transuranic waste (TRU) is stated by U.S. regulations, and independent of state or origin, to be waste which has been contaminated with alpha emitting transuranic radionuclides possessing half-lives greater than 20 years and in concentrations g ...
is non existent from fast reactors. The primary advantage of liquid metal coolants, such as liquid sodium, is that metal atoms are weak
neutron The neutron is a subatomic particle, symbol or , that has no electric charge, and a mass slightly greater than that of a proton. The Discovery of the neutron, neutron was discovered by James Chadwick in 1932, leading to the discovery of nucle ...
moderators. Water is a much stronger
neutron moderator In nuclear engineering, a neutron moderator is a medium that reduces the speed of fast neutrons, ideally without capturing any, leaving them as thermal neutrons with only minimal (thermal) kinetic energy. These thermal neutrons are immensely ...
because the hydrogen atoms found in
water Water is an inorganic compound with the chemical formula . It is a transparent, tasteless, odorless, and Color of water, nearly colorless chemical substance. It is the main constituent of Earth's hydrosphere and the fluids of all known liv ...
are much lighter than metal atoms, and therefore neutrons lose more energy in
collision In physics, a collision is any event in which two or more bodies exert forces on each other in a relatively short time. Although the most common use of the word ''collision'' refers to incidents in which two or more objects collide with great for ...
s with hydrogen atoms. This makes it difficult to use water as a coolant for a fast reactor because the water tends to slow (moderate) the fast neutrons into thermal neutrons (although concepts for reduced moderation water reactors exist). Another advantage of liquid sodium coolant is that sodium melts at 371K (98°C) and boils / vaporizes at 1156K (883°C), a difference of 785K (785°C) between solid / frozen and gas / vapor states. By comparison, the liquid temperature range of water (between ice and gas) is just 100K at normal, sea-level atmospheric pressure conditions. Despite sodium's low specific heat (as compared to water), this enables the absorption of significant heat in the liquid phase, while maintaining large safety margins. Moreover, the high thermal conductivity of sodium effectively creates a reservoir of
heat capacity Heat capacity or thermal capacity is a physical property of matter, defined as the amount of heat to be supplied to an object to produce a unit change in its temperature. The SI unit of heat capacity is joule per kelvin (J/K). Heat capacity is a ...
that provides thermal inertia against overheating. Sodium need not be pressurized since its
boiling point The boiling point of a substance is the temperature at which the vapor pressure of a liquid equals the pressure surrounding the liquid and the liquid changes into a vapor. The boiling point of a liquid varies depending upon the surrounding envi ...
is much higher than the reactor's
operating temperature An operating temperature is the allowable temperature range of the local ambient environment at which an electrical or mechanical device operates. The device will operate effectively within a specified temperature range which varies based on the de ...
, and sodium does not corrode steel reactor parts, and in fact, protects metals from corrosion. The high temperatures reached by the coolant (the Phénix reactor outlet temperature was 833K (560°C)) permit a higher
thermodynamic efficiency In thermodynamics, the thermal efficiency (\eta_) is a dimensionless performance measure of a device that uses thermal energy, such as an internal combustion engine, steam turbine, steam engine, boiler, furnace, refrigerator, ACs etc. For a he ...
than in water cooled reactors. The electrically conductive molten sodium can be moved by
electromagnetic pump An electromagnetic pump is a pump that moves liquid metal, molten salt, brine, or other electrically conductive liquid using electromagnetism. A magnetic field is set at right angles to the direction the liquid moves in, and a current is passed t ...
s. The fact that the sodium is not pressurized implies that a much thinner reactor vessel can be used (e.g. 2 cm thick). Combined with the much higher temperatures achieved in the reactor, this means that the reactor in shutdown mode can be passively cooled. For example, air ducts can be engineered so that all the
decay heat Decay heat is the heat released as a result of radioactive decay. This heat is produced as an effect of radiation on materials: the energy of the alpha particle, alpha, Beta particle, beta or gamma radiation is converted into the thermal movement ...
after shutdown is removed by natural convection, and no pumping action is required. Reactors of this type are self-controlling. If the temperature of the core increases, the core will expand slightly, which means that more neutrons will escape the core, slowing down the reaction.


Disadvantages

A disadvantage of sodium is its chemical reactivity, which requires special precautions to prevent and suppress fires. If sodium comes into contact with water it reacts to produce sodium hydroxide and hydrogen, and the hydrogen burns in contact with air. This was the case at the Monju Nuclear Power Plant in a 1995 accident. In addition, neutron capture causes it to become radioactive; albeit with a half-life of only 15 hours. Another problem is leaks. Sodium at high temperatures ignites in contact with oxygen. Such sodium fires can be extinguished by powder, or by replacing the air with
nitrogen Nitrogen is a chemical element; it has Symbol (chemistry), symbol N and atomic number 7. Nitrogen is a Nonmetal (chemistry), nonmetal and the lightest member of pnictogen, group 15 of the periodic table, often called the Pnictogen, pnictogens. ...
. A Russian breeder reactor, the BN-600, reported 27 sodium leaks in a 17-year period, 14 of which led to sodium fires.


Design goals

The operating temperature must not exceed the fuel's boiling temperature. Fuel-to-cladding chemical interaction (FCCI) has to be accommodated. FCCI is eutectic melting between the fuel and the cladding; uranium, plutonium, and
lanthanum Lanthanum is a chemical element; it has symbol La and atomic number 57. It is a soft, ductile, silvery-white metal that tarnishes slowly when exposed to air. It is the eponym of the lanthanide series, a group of 15 similar elements bet ...
(a
fission product Nuclear fission products are the atomic fragments left after a large atomic nucleus undergoes nuclear fission. Typically, a large nucleus like that of uranium fissions by splitting into two smaller nuclei, along with a few neutrons, the releas ...
) inter-diffuse with the iron of the cladding. The alloy that forms has a low eutectic melting temperature. FCCI causes the cladding to reduce in strength and even rupture. The amount of transuranic transmutation is limited by the production of plutonium from uranium. One work-around is to have an inert matrix, using, e.g.,
magnesium oxide Magnesium oxide (MgO), or magnesia, is a white hygroscopic solid mineral that occurs naturally as periclase and is a source of magnesium (see also oxide). It has an empirical formula of MgO and consists of a lattice of Mg2+ ions and O2− ions ...
. Magnesium oxide has an order of magnitude lower probability of interacting with neutrons (thermal and fast) than elements such as iron. High-level wastes and, in particular, management of plutonium and other actinides must be handled. Safety features include a long thermal response time, a large margin to coolant boiling, a primary cooling system that operates near atmospheric pressure, and an intermediate sodium system between the radioactive sodium in the primary system and the water and steam in the power plant. Innovations can reduce capital cost, such as modular designs, removing a primary loop, integrating the pump and intermediate heat exchanger, and better materials. The SFR's fast spectrum makes it possible to use available fissile and fertile materials (including
depleted uranium Depleted uranium (DU), also referred to in the past as Q-metal, depletalloy, or D-38, is uranium with a lower content of the fissile isotope Uranium-235, 235U than natural uranium. The less radioactive and non-fissile Uranium-238, 238U is the m ...
) considerably more efficiently than thermal spectrum reactors with once-through fuel cycles.


History

In 2020 Natrium received an $80M grant from the
US Department of Energy US or Us most often refers to: * Us (pronoun), ''Us'' (pronoun), the objective case of the English first-person plural pronoun ''we'' * US, an abbreviation for the United States US, U.S., Us, us, or u.s. may also refer to: Arts and entertainme ...
for development of its SFR. The program plans to use High-Assay, Low Enriched Uranium fuel containing 5-20% uranium. The reactor was expected to be sited underground and have gravity-inserted control rods. Because it operates at atmospheric pressure, a large containment shield is not necessary. Because of its large heat storage capacity, it was expected to be able to produce surge power of 500 MWe for 5+ hours, beyond its continuous power of 345 MWe.


Reactors

Sodium-cooled fast reactors have included: Most of these were experimental plants that are no longer operational. On November 30, 2019, CTV reported that the Canadian provinces of
New Brunswick New Brunswick is a Provinces and Territories of Canada, province of Canada, bordering Quebec to the north, Nova Scotia to the east, the Gulf of Saint Lawrence to the northeast, the Bay of Fundy to the southeast, and the U.S. state of Maine to ...
,
Ontario Ontario is the southernmost Provinces and territories of Canada, province of Canada. Located in Central Canada, Ontario is the Population of Canada by province and territory, country's most populous province. As of the 2021 Canadian census, it ...
and
Saskatchewan Saskatchewan is a Provinces and territories of Canada, province in Western Canada. It is bordered on the west by Alberta, on the north by the Northwest Territories, on the east by Manitoba, to the northeast by Nunavut, and to the south by the ...
planned an announcement about a joint plan to cooperate on small sodium fast modular nuclear reactors from New Brunswick-based ARC Nuclear Canada.


See also

*
Fast breeder reactor A breeder reactor is a nuclear reactor that generates more fissile material than it consumes. These reactors can be Nuclear fuel, fueled with more-commonly available isotopes of uranium and Isotopes of thorium, thorium, such as uranium-238 and t ...
*
Fast neutron reactor A fast-neutron reactor (FNR) or fast-spectrum reactor or simply a fast reactor is a category of nuclear reactor in which the fission nuclear chain reaction, chain reaction is sustained by fast neutrons (carrying energies above 1 Electronvolt, MeV, ...
*
Integral fast reactor The integral fast reactor (IFR), originally the advanced liquid-metal reactor (ALMR), is a design for a nuclear reactor using fast neutrons and no neutron moderator (a "fast" reactor). IFRs can breed more fuel and are distinguished by a nuclea ...
*
Lead-cooled fast reactor The lead-cooled fast reactor is a nuclear reactor design that uses molten lead or lead-bismuth eutectic as its coolant. These materials can be used as the primary coolant because they have low neutron absorption and relatively low melting poi ...
*
Gas-cooled fast reactor The gas-cooled fast reactor (GFR) system is a nuclear reactor design which is currently in development. Classed as a Generation IV reactor, it features a fast-neutron spectrum and closed fuel cycle for efficient conversion of fertile uranium ...
*
Generation IV reactor Generation IV (Gen IV) reactors are nuclear reactor design technologies that are envisioned as successors of generation III reactors. The Generation IV International Forum (GIF) – an international organization that coordinates the development of ...


References


External links


Idaho National Laboratory Sodium-cooled Fast Reactor Fact SheetINL SFR workshop summaryASME
* {{Nuclear fission reactors Liquid metal fast reactors Radioactive waste