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Smart materials, also called intelligent or responsive materials, are designed materials that have one or more properties that can be significantly changed in a controlled fashion by external stimuli, such as stress, moisture,
electric Electricity is the set of physical phenomena associated with the presence and motion of matter possessing an electric charge. Electricity is related to magnetism, both being part of the phenomenon of electromagnetism, as described by Maxwel ...
or
magnetic Magnetism is the class of physical attributes that occur through a magnetic field, which allows objects to attract or repel each other. Because both electric currents and magnetic moments of elementary particles give rise to a magnetic field, m ...
fields, light,
temperature Temperature is a physical quantity that quantitatively expresses the attribute of hotness or coldness. Temperature is measurement, measured with a thermometer. It reflects the average kinetic energy of the vibrating and colliding atoms making ...
, pH, or chemical compounds. Smart materials are the basis of many applications, including
sensors A sensor is often defined as a device that receives and responds to a signal or stimulus. The stimulus is the quantity, property, or condition that is sensed and converted into electrical signal. In the broadest definition, a sensor is a devi ...
and
actuators An actuator is a component of a machine that produces force, torque, or displacement, when an electrical, pneumatic or hydraulic input is supplied to it in a system (called an actuating system). The effect is usually produced in a controlled way. ...
, or artificial muscles, particularly as electroactive polymers (EAPs).


Types

There are a number of types of smart material, of which are already common. Some examples are as following: *
Piezoelectric Piezoelectricity (, ) is the electric charge that accumulates in certain solid materials—such as crystals, certain ceramics, and biological matter such as bone, DNA, and various proteins—in response to applied stress (mechanics), mechanical s ...
materials are materials that produce a voltage when stress is applied. Since this effect also applies in a reverse manner, a voltage across the sample will produce stress within sample. Suitably designed structures made from these materials can, therefore, be made that bend, expand or contract when a voltage is applied. *
Shape-memory alloy In metallurgy, a shape-memory alloy (SMA) is an alloy that can be deformed when cold but returns to its pre-deformed ("remembered") shape when heated. It is also known in other names such as memory metal, memory alloy, smart metal, smart alloy, ...
s and shape-memory polymers are materials in which large deformation can be induced and recovered through temperature changes or stress changes (
pseudoelasticity In materials science, pseudoelasticity, sometimes called superelasticity, is an elastic (reversible) response to an applied stress, caused by a phase transformation between the austenitic and martensitic phases of a crystal. It is exhibited in ...
). The shape memory effect results due to respectively martensitic phase change and induced elasticity at higher temperatures. A common example is Nitmol. *
Photovoltaic Photovoltaics (PV) is the conversion of light into electricity using semiconducting materials that exhibit the photovoltaic effect, a phenomenon studied in physics, photochemistry, and electrochemistry. The photovoltaic effect is commercially ...
materials or
optoelectronics Optoelectronics (or optronics) is the study and application of electronic devices and systems that find, detect and control light, usually considered a sub-field of photonics. In this context, ''light'' often includes invisible forms of radi ...
convert light to electrical current. * Electroactive polymers (EAPs) change their volume by voltage or electric fields. *
Magnetostrictive Magnetostriction is a property of magnetic materials that causes them to change their shape or dimensions during the process of magnetization. The variation of materials' magnetization due to the applied magnetic field changes the magnetostrictive ...
materials exhibit a change in shape under the influence of magnetic field and also exhibit a change in their magnetization under the influence of mechanical stress. * Magnetic shape memory alloys are materials that change their shape in response to a significant change in the magnetic field. *
Smart inorganic polymers Smart inorganic polymers (SIPs) are hybrid or fully inorganic polymers with tunable (Smart polymer, smart) properties such as stimuli responsive physical properties (shape, conductivity, rheology, bioactivity, self-repair, sensing etc.). While orga ...
showing tunable and responsive properties. * pH-sensitive polymers are materials that change in volume when the pH of the surrounding medium changes. * Temperature-responsive polymers are materials which undergo changes upon temperature. * Halochromic materials are commonly used materials that change their color as a result of changing acidity. One suggested application is for paints that can change color to indicate
corrosion Corrosion is a natural process that converts a refined metal into a more chemically stable oxide. It is the gradual deterioration of materials (usually a metal) by chemical or electrochemical reaction with their environment. Corrosion engine ...
in the metal underneath them. * Chromogenic systems change color in response to electrical, optical or thermal changes. These include electrochromic materials, which change their colour or opacity on the application of a voltage (e.g.,
liquid crystal display A liquid-crystal display (LCD) is a flat-panel display or other Electro-optic modulator, electronically modulated optical device that uses the light-modulating properties of liquid crystals combined with polarizers to display information. Liq ...
s), thermochromic materials change in colour depending on their temperature, and photochromic materials, which change colour in response to light—for example, light-sensitive
sunglasses Sunglasses or sun glasses (informally called shades or sunnies; more names Sunglasses#Other names, below) are a form of Eye protection, protective eyewear designed primarily to prevent bright sunlight and high-energy visible light from damagin ...
that darken when exposed to bright sunlight. *
Ferrofluid Ferrofluid is a dark liquid that is attracted to the poles of a magnet. It is a colloidal liquid made of nanoscale ferromagnetic or ferrimagnetic particles suspended inside a carrier fluid (usually an organic solvent or water). Each magnetic ...
s are magnetic fluids (affected by magnets and magnetic fields). * Photomechanical materials change shape under exposure to light. *
Polycaprolactone Polycaprolactone (PCL) is a synthetic, semi-crystalline, biodegradable polyester with a melting point of about 60 °C and a glass transition temperature of about −60 °C. The most common use of polycaprolactone is in the production ...
(polymorph) can be molded by immersion in hot water. *
Self-healing material Self-healing materials are artificial or synthetically created materials, substances that have the built-in ability to automatically repair damages to themselves without any external diagnosis of the problem or human intervention. Generally, mate ...
s have the intrinsic ability to repair damage due to normal usage, thus expanding the material's lifetime. * Dielectric elastomers (DEs) are smart material systems which produce large strains (up to 500%) under the influence of an external electric field. * Magnetocaloric materials are compounds that undergo a reversible change in temperature upon exposure to a changing magnetic field. * Thermoelectric materials are used to build devices that convert temperature differences into electricity and vice versa. * Chemoresponsive materials change size or volume under the influence of external chemical or biological compound.''Chemoresponsive Materials /Stimulation by Chemical and Biological Signals'', Schneider, H.-J.; Ed:, (2015)''The Royal Society of Chemistry,'' Cambridge https://dx.doi.org/10.1039/97817828822420


See also

* Smart polymer * Programmable matter *
Sensors A sensor is often defined as a device that receives and responds to a signal or stimulus. The stimulus is the quantity, property, or condition that is sensed and converted into electrical signal. In the broadest definition, a sensor is a devi ...
*
Actuators An actuator is a component of a machine that produces force, torque, or displacement, when an electrical, pneumatic or hydraulic input is supplied to it in a system (called an actuating system). The effect is usually produced in a controlled way. ...
* Artificial muscles * Thermally induced shape-memory effect (polymers) *
Covalent adaptable network Covalent adaptable networks (CANs) are a type of polymer material that closely resemble thermosetting polymers (thermosets). However, they are distinguished from thermosets by the incorporation of dynamic covalent chemistry into the polymer network ...
s /
Vitrimers Vitrimers are a class of plastics, which are derived from thermosetting polymers (thermosets) and are very similar to them. Vitrimers consist of molecular, covalent networks, which can change their topology by thermally activated bond-exchange rea ...


References


External links


Smart Materials Book Series
Royal Society of Chemistry {{Authority control Artificial materials