The slave boson method is a technique for dealing with models of
strongly correlated systems, providing a method to second-quantize valence fluctuations within a restrictive manifold of states.
In the 1960s the physicist
John Hubbard introduced an operator, now named the "Hubbard operator"
to describe the creation of an electron within a restrictive manifold of valence configurations. Consider for example, a rare earth or actinide ion in which strong Coulomb interactions restrict the charge fluctuations to two valence states, such as the Ce
4+(4f
0) and Ce
3+ (4f
1) configurations of a mixed-valence
cerium compound. The corresponding quantum states of these two states are the singlet
state and the magnetic
state, where
is the spin. The fermionic Hubbard operators that link these states are then
The algebra of operators is closed by introducing the two bosonic operators
Together, these operators satisfy the graded
Lie algebra
In mathematics, a Lie algebra (pronounced ) is a vector space \mathfrak g together with an operation called the Lie bracket, an alternating bilinear map \mathfrak g \times \mathfrak g \rightarrow \mathfrak g, that satisfies the Jacobi ident ...
where the
and the sign is chosen to be negative, unless both
and
are fermions, in which case it is positive. The Hubbard operators are the generators of the super group SU(2, 1). This non-canonical algebra means that these operators do not satisfy a
Wick's theorem, which prevents a conventional diagrammatic or field theoretic treatment.
In 1983
Piers Coleman introduced the slave boson formulation of the Hubbard operators,
which enabled valence fluctuations to be treated within a field-theoretic approach.
In this approach, the spinless configuration of the ion is represented by a spinless "slave boson"
, whereas the magnetic configuration
is represented by an Abrikosov slave fermion. From these considerations, it is seen that the Hubbard operators can be written as
and
This factorization of the Hubbard operators faithfully preserves the graded Lie algebra. Moreover, the Hubbard operators so written commute with the conserved quantity
In Hubbard's original approach,
, but by generalizing this quantity to larger values, higher irreducible representations of SU(2, 1) are generated.
The slave boson representation can be extended from two component to
component fermions, where the spin index