Shoshonite
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Shoshonite is a type of
igneous rock Igneous rock ( ), or magmatic rock, is one of the three main rock types, the others being sedimentary and metamorphic. Igneous rocks are formed through the cooling and solidification of magma or lava. The magma can be derived from partial ...
. More specifically, it is a
potassium Potassium is a chemical element; it has Symbol (chemistry), symbol K (from Neo-Latin ) and atomic number19. It is a silvery white metal that is soft enough to easily cut with a knife. Potassium metal reacts rapidly with atmospheric oxygen to ...
-rich variety of
basalt Basalt (; ) is an aphanite, aphanitic (fine-grained) extrusive igneous rock formed from the rapid cooling of low-viscosity lava rich in magnesium and iron (mafic lava) exposed at or very near the planetary surface, surface of a terrestrial ...
ic trachyandesite, composed of
olivine The mineral olivine () is a magnesium iron Silicate minerals, silicate with the chemical formula . It is a type of Nesosilicates, nesosilicate or orthosilicate. The primary component of the Earth's upper mantle (Earth), upper mantle, it is a com ...
,
augite Augite, also known as Augurite, is a common rock-forming pyroxene mineral with formula . The crystals are monoclinic and prismatic. Augite has two prominent cleavages, meeting at angles near 90 degrees. Characteristics Augite is a solid soluti ...
and
plagioclase Plagioclase ( ) is a series of Silicate minerals#Tectosilicates, tectosilicate (framework silicate) minerals within the feldspar group. Rather than referring to a particular mineral with a specific chemical composition, plagioclase is a continu ...
phenocryst image:montblanc granite phenocrysts.JPG, 300px, Granites often have large feldspar, feldspathic phenocrysts. This granite, from the Switzerland, Swiss side of the Mont Blanc massif, has large white phenocrysts of plagioclase (that have trapezoid sh ...
s in a groundmass with calcic plagioclase and
sanidine Sanidine is the high temperature form of potassium feldspar with a general formula K(AlSi3O8). Sanidine is found most typically in felsic volcanic rocks such as obsidian, rhyolite and trachyte. Sanidine crystallizes in the monoclinic crystal sys ...
and some dark-colored
volcanic glass Volcanic glass is the amorphous (uncrystallized) product of rapidly cooling magma. Like all types of glass, it is a state of matter intermediate between the closely packed, highly ordered array of a crystal and the highly disordered array of liqu ...
. Shoshonite gives its name to the shoshonite series and grades into absarokite with the loss of plagioclase phenocrysts and into banakite with an increase in sanidine. Shoshonite was named by Iddings in 1895 for the Shoshone River in
Wyoming Wyoming ( ) is a landlocked U.S. state, state in the Mountain states, Mountain West subregion of the Western United States, Western United States. It borders Montana to the north and northwest, South Dakota and Nebraska to the east, Idaho t ...
. Textural and mineralogical features of potash-rich rocks of the absarokite-shoshonite-banakite series strongly suggest that most of the large crystals and aggregates are not true phenocrysts as previously thought but are xenocrysts and microxenoliths, suggesting a hybrid origin involving assimilation of
gabbro Gabbro ( ) is a phaneritic (coarse-grained and magnesium- and iron-rich), mafic intrusive igneous rock formed from the slow cooling magma into a holocrystalline mass deep beneath the Earth's surface. Slow-cooling, coarse-grained gabbro is ch ...
by high-temperature syenitic
magma Magma () is the molten or semi-molten natural material from which all igneous rocks are formed. Magma (sometimes colloquially but incorrectly referred to as ''lava'') is found beneath the surface of the Earth, and evidence of magmatism has also ...
.


Chemical characteristics

Igneous Igneous rock ( ), or magmatic rock, is one of the three main rock types, the others being sedimentary and metamorphic. Igneous rocks are formed through the cooling and solidification of magma or lava. The magma can be derived from partial ...
rocks with shoshonitic chemical characteristics must be:Morrison, Gregg, 1980, ''Characteristics and tectonic settings of shoshonite rock association,'' Lithos, 13, 97-108 #Near-saturated in silica; #Low iron enrichment; #High total alkalies (Na2O + K2O > 5%); #High K2O/Na2O; #Steep positive slope for K2O versus SiO2 at low SiO2; #Enrichment in P, Rb, Sr, Ba, Pb, light rare earth elements; #Low TiO2; #High but variable Al2O3; #High Fe2O3/FeO.


Tectonic settings and examples

Shoshonitic rocks tend to be associated with
calc-alkaline The calc-alkaline magma series is one of two main subdivisions of the subalkaline magma series, the other subalkaline magma series being the tholeiitic series. A magma series is a series of compositions that describes the evolution of a mafic ...
island-arc
subduction Subduction is a geological process in which the oceanic lithosphere and some continental lithosphere is recycled into the Earth's mantle at the convergent boundaries between tectonic plates. Where one tectonic plate converges with a second p ...
volcanism Volcanism, vulcanism, volcanicity, or volcanic activity is the phenomenon where solids, liquids, gases, and their mixtures erupt to the surface of a solid-surface astronomical body such as a planet or a moon. It is caused by the presence of a he ...
, but the K-rich shoshonites are generally younger and above deeper, steeper parts or the
Benioff zone Benioff is a surname. Notable people with the surname include: * David Benioff (born 1970), American writer, screenwriter and television producer * Hugo Benioff (1899–1968), American seismologist and academic **Wadati–Benioff zone *Marc Benioff ...
.
Volcanic rock Volcanic rocks (often shortened to volcanics in scientific contexts) are rocks formed from lava erupted from a volcano. Like all rock types, the concept of volcanic rock is artificial, and in nature volcanic rocks grade into hypabyssal and me ...
s of the absarokite-shoshonite-banakite series described from Yellowstone Park by Iddings and the similar ciminite-toscanite series described from western
Italy Italy, officially the Italian Republic, is a country in Southern Europe, Southern and Western Europe, Western Europe. It consists of Italian Peninsula, a peninsula that extends into the Mediterranean Sea, with the Alps on its northern land b ...
by Washington are associated with
leucite Leucite (from the Greek word ''leukos'' meaning white) is a rock-forming mineral of the feldspathoid group, silica-undersaturated and composed of potassium and aluminium tectosilicate KAlSi2O6. Crystals have the form of cubic icositetrahedra b ...
-bearing rocks, potassium-rich
trachyte Trachyte () is an extrusive igneous rock composed mostly of alkali feldspar. It is usually light-colored and aphanite, aphanitic (fine-grained), with minor amounts of mafic minerals, and is formed by the rapid cooling of lava (or shallow intrus ...
s and andesitic rocks. Similar associations are described from several other regions including Indonesia and the
East African Rift The East African Rift (EAR) or East African Rift System (EARS) is an active continental rift zone in East Africa. The EAR began developing around the onset of the Miocene, 22–25 million years ago. It was formerly considered to be part of a l ...
. Joplin, Germaine A., ''The shoshonite association: A review,'' Journal of the Geological Society of Australia, v. 15, #2, 1968, pp 275-294 DOI:10.1080/00167616808728699 In the Aeolian Arc in the southern
Tyrrhenian Sea The Tyrrhenian Sea (, ; or ) , , , , is part of the Mediterranean Sea off the western coast of Italy. It is named for the Tyrrhenians, Tyrrhenian people identified with the Etruscans of Italy. Geography The sea is bounded by the islands of C ...
(between the Eurasian and African
tectonic plates Plate tectonics (, ) is the scientific theory that the Earth's lithosphere comprises a number of large tectonic plates, which have been slowly moving since 3–4 billion years ago. The model builds on the concept of , an idea developed durin ...
), volcanism has changed between
calc-alkaline The calc-alkaline magma series is one of two main subdivisions of the subalkaline magma series, the other subalkaline magma series being the tholeiitic series. A magma series is a series of compositions that describes the evolution of a mafic ...
to high-K calc-alkaline to shoshonitic with the last one million years, possibly due to the progressive steepening of the
Benioff zone Benioff is a surname. Notable people with the surname include: * David Benioff (born 1970), American writer, screenwriter and television producer * Hugo Benioff (1899–1968), American seismologist and academic **Wadati–Benioff zone *Marc Benioff ...
, which is inclined at 50-60°. An example of shoshonite lava in this region is the Capo Secco lava shield near Vulcano. Late
Cretaceous The Cretaceous ( ) is a geological period that lasted from about 143.1 to 66 mya (unit), million years ago (Mya). It is the third and final period of the Mesozoic Era (geology), Era, as well as the longest. At around 77.1 million years, it is the ...
Puerto Rican volcanism is interpreted to have occurred in a similar
tectonic Tectonics ( via Latin ) are the processes that result in the structure and properties of the Earth's crust and its evolution through time. The field of ''planetary tectonics'' extends the concept to other planets and moons. These processes ...
setting. In places, shoshonitic and high-potassium calc-alkaline magmatism is associated with world-class hydrothermal gold and copper-gold mineralization. Examples include:Müller D., Groves D.I. (2019) Potassic igneous rocks and associated gold-copper mineralization (5th ed.). Mineral Resource Reviews. Springer-Verlag Heidelberg, 398 pp :Ladolam gold mine,
Lihir Island Lihir Island (a.k.a. Niolam Island) is the largest island in the Lihir Group, Lihir group of islands, long and wide, in Papua New Guinea's New Ireland Province. It consists of a complex of several overlapping basaltic stratovolcanoes rising 700 ...
,
Papua New Guinea Papua New Guinea, officially the Independent State of Papua New Guinea, is an island country in Oceania that comprises the eastern half of the island of New Guinea and offshore islands in Melanesia, a region of the southwestern Pacific Ocean n ...
; : Bingham copper-gold mine,
Utah Utah is a landlocked state in the Mountain states, Mountain West subregion of the Western United States. It is one of the Four Corners states, sharing a border with Arizona, Colorado, and New Mexico. It also borders Wyoming to the northea ...
; : Grasberg copper-gold mine,
Indonesia Indonesia, officially the Republic of Indonesia, is a country in Southeast Asia and Oceania, between the Indian Ocean, Indian and Pacific Ocean, Pacific oceans. Comprising over List of islands of Indonesia, 17,000 islands, including Sumatra, ...
; : Oyu Tolgoi copper-gold mine,
Mongolia Mongolia is a landlocked country in East Asia, bordered by Russia to the north and China to the south and southeast. It covers an area of , with a population of 3.5 million, making it the world's List of countries and dependencies by po ...
.


References

{{Rock type Volcanic rocks