Sergei Vasilievich Lebedev (russian: Сергей Васильевич Лебедев; 13 July 1874 – 2 May 1934) was a

Russia Russia (, , ), or the Russian Federation, is a transcontinental country spanning Eastern Europe and Northern Asia. It is the largest country in the world, with its internationally recognised territory covering , and encompassing one-eigh ...

Soviet The Soviet Union,. officially the Union of Soviet Socialist Republics. (USSR),. was a transcontinental country that spanned much of Eurasia from 1922 to 1991. A flagship communist state, it was nominally a federal union of fifteen national ...

chemist and the inventor of

polybutadiene synthetic rubber Polybutadiene utadiene rubber BRis a synthetic rubber. Polybutadiene rubber is a polymer formed from the polymerization of the monomer 1,3-butadiene. Polybutadiene has a high resistance to wear and is used especially in the Tire manufacturi ...

, the first commercially viable and mass-produced type of

synthetic rubber A synthetic rubber is an artificial elastomer. They are polymers synthesized from petroleum byproducts. About 32-million metric tons of rubbers are produced annually in the United States, and of that amount two thirds are synthetic. Synthetic rubbe ...

Biography

Lebedev was born in 1874 in

Lublin Lublin is the ninth-largest city in Poland and the second-largest city of historical Lesser Poland. It is the capital and the center of Lublin Voivodeship with a population of 336,339 (December 2021). Lublin is the largest Polish city east of ...

and went to school in

Warsaw Warsaw ( pl, Warszawa, ), officially the Capital City of Warsaw,, abbreviation: ''m.st. Warszawa'' is the capital and largest city of Poland. The metropolis stands on the River Vistula in east-central Poland, and its population is official ...

. In 1900, he graduated from

St. Petersburg University Saint Petersburg State University (SPBU; russian: Санкт-Петербургский государственный университет) is a public research university in Saint Petersburg, Russia. Founded in 1724 by a decree of Peter the ...

and found work at the Petersburg Margarine Factory. Starting in 1902, Lebedev moved from university to university in Russia, starting at the

Saint-Petersburg Institute for Railroad Engineering Emperor Alexander I St. Petersburg State Transport University (PGUPS) (russian: Петербургский государственный университет путей сообщения Императора Александра I, abbreviat ...

. In 1904, he returned to St. Petersburg University to work under Alexey Favorsky ( Stalin Prize, 1941, for contributions to the manufacture of synthetic rubber). In 1905, he married his second wife, the artist

Anna Ostroumova-Lebedeva Anna Petrovna Ostroumova-Lebedeva (russian: Анна Петровна Остроумова-Лебедева, 17 May 1871 — 5 May 1955) was a Russian and Soviet artist most notable for her watercolor painting. She was also one of the pioneers o ...

. In 1915, Lebedev was appointed Professor at the Women's Pedagogical Institute in

St. Petersburg Saint Petersburg ( rus, links=no, Санкт-Петербург, a=Ru-Sankt Peterburg Leningrad Petrograd Piter.ogg, r=Sankt-Peterburg, p=ˈsankt pʲɪtʲɪrˈburk), formerly known as Petrograd (1914–1924) and later Leningrad (1924–1991), i ...

. After 1916, he was a Professor of the Saint Petersburg Academy for Military Medicine. In 1925, he became the leader of the ''Oil Laboratory'' (after 1928, the ''Laboratory of Synthetic Resins'') at St. Petersburg University. He died in

Leningrad Saint Petersburg ( rus, links=no, Санкт-Петербург, a=Ru-Sankt Peterburg Leningrad Petrograd Piter.ogg, r=Sankt-Peterburg, p=ˈsankt pʲɪtʲɪrˈburk), formerly known as Petrograd (1914–1924) and later Leningrad (1924–1991), i ...

and is interred in

Tikhvin Cemetery Tikhvin Cemetery (russian: Тихвинское кладбище) is a historic cemetery in the centre of Saint Petersburg. It is part of the Alexander Nevsky Lavra, and is one of four cemeteries in the complex. Since 1932 it has been part of the ...

Works

Lebedev's main works are devoted to

polymerisation In polymer chemistry, polymerization (American English), or polymerisation (British English), is a process of reacting monomer molecules together in a chemical reaction to form polymer chains or three-dimensional networks. There are many for ...

diene In organic chemistry a diene ( ) (diolefin ( ) or alkadiene) is a covalent compound that contains two double bonds, usually among carbon atoms. They thus contain two alk''ene'' units, with the standard prefix ''di'' of systematic nomenclature ...

hydrocarbon In organic chemistry, a hydrocarbon is an organic compound consisting entirely of hydrogen and carbon. Hydrocarbons are examples of group 14 hydrides. Hydrocarbons are generally colourless and hydrophobic, and their odors are usually weak or ...

s. He was the first to research the polymerisation of

butadiene 1,3-Butadiene () is the organic compound with the formula (CH2=CH)2. It is a colorless gas that is easily condensed to a liquid. It is important industrially as a precursor to synthetic rubber. The molecule can be viewed as the union of two vin ...

(1910–1913). In 1910, Lebedev was the first to get synthetic rubber based on poly-butadiene. His book ''Research in polymerisation of by-ethylene hydrocarbons'' (1913) became the bible for studies of synthetic rubber. After 1914, he studied polymerisation of

ethylene Ethylene ( IUPAC name: ethene) is a hydrocarbon which has the formula or . It is a colourless, flammable gas with a faint "sweet and musky" odour when pure. It is the simplest alkene (a hydrocarbon with carbon-carbon double bonds). Ethylene ...

monomers, leading to modern industrial methods for manufacturing of butyl synthetic rubber and poly-

isobutylene Isobutylene (or 2-methylpropene) is a hydrocarbon with the chemical formula . It is a four-carbon branched alkene (olefin), one of the four isomers of butylene. It is a colorless flammable gas, and is of considerable industrial value. Producti ...

. Between 1926 and 1928, he developed a single-stage method for manufacturing butadiene out of

ethanol Ethanol (abbr. EtOH; also called ethyl alcohol, grain alcohol, drinking alcohol, or simply alcohol) is an organic compound. It is an alcohol with the chemical formula . Its formula can be also written as or (an ethyl group linked to a h ...

. In 1928, he developed an industrial method for producing synthetic rubber based on polymerisation of butadiene using metallic

sodium Sodium is a chemical element with the symbol Na (from Latin ''natrium'') and atomic number 11. It is a soft, silvery-white, highly reactive metal. Sodium is an alkali metal, being in group 1 of the periodic table. Its only stable ...

as a

catalyst Catalysis () is the process of increasing the rate of a chemical reaction by adding a substance known as a catalyst (). Catalysts are not consumed in the reaction and remain unchanged after it. If the reaction is rapid and the catalyst recyc ...

. This method became the base for the Soviet industry of synthetic rubber. The Soviets lacked reliable access to natural

rubber Rubber, also called India rubber, latex, Amazonian rubber, ''caucho'', or ''caoutchouc'', as initially produced, consists of polymers of the organic compound isoprene, with minor impurities of other organic compounds. Thailand, Malaysia, a ...

, making the manufacture of synthetic rubber important. The first three synthetic rubber plants were launched in 1932–33. For butadiene production they used grain or potato ethanol as a feedstock. It caused a number of jokes about "Russian method of making tires from potatoes". By 1940, the Soviet Union had the largest synthetic rubber industry in the world, producing more than 50,000 tons per year. During

World War II World War II or the Second World War, often abbreviated as WWII or WW2, was a world war that lasted from 1939 to 1945. It involved the World War II by country, vast majority of the world's countries—including all of the great power ...

, Lebedev's process of obtaining butadiene from ethyl alcohol was also used by the German rubber industry. Another important contribution of Lebedev's was the study of the

kinetics Kinetics ( grc, κίνησις, , kinesis, ''movement'' or ''to move'') may refer to: Science and medicine * Kinetics (physics), the study of motion and its causes ** Rigid body kinetics, the study of the motion of rigid bodies * Chemical k ...

hydrogenation Hydrogenation is a chemical reaction between molecular hydrogen (H2) and another compound or element, usually in the presence of a catalyst such as nickel, palladium or platinum. The process is commonly employed to reduce or saturate org ...

hydrocarbons and the development of a number of

synthetic motor oils Synthetic oil is a lubricant consisting of chemical compounds that are artificially modified or synthesised. Synthetic lubricants can be manufactured using chemically modified petroleum components rather than whole crude oil, but can also be sy ...

for

aircraft An aircraft is a vehicle that is able to fly by gaining support from the air. It counters the force of gravity by using either static lift or by using the dynamic lift of an airfoil, or in a few cases the downward thrust from jet engines. ...

engines An engine or motor is a machine designed to convert one or more forms of energy into mechanical energy. Available energy sources include potential energy (e.g. energy of the Earth's gravitational field as exploited in hydroelectric power ge ...

Honors

* In 1931, Lebedev was awarded the

Order of Lenin The Order of Lenin (russian: Орден Ленина, Orden Lenina, ), named after the leader of the Russian October Revolution, was established by the Central Executive Committee on April 6, 1930. The order was the highest civilian decoration ...

for his work on synthetic rubber * In 1932, he became a full member of the

Soviet Academy of Sciences The Academy of Sciences of the Soviet Union was the highest scientific institution of the Soviet Union from 1925 to 1991, uniting the country's leading scientists, subordinated directly to the Council of Ministers of the Soviet Union (until 1946 ...

. * In 1945 the National Institute for Synthetic Rubber was named "Lebedev's Institute".

References

External links

*
July 25 – Today In Science History
at www.todayinsci.com
Butadiene: Definition and Much More from Answers.com
at www.answers.com {{DEFAULTSORT:Lebedev, Sergei Vasiljevich 1874 births 1934 deaths Scientists from Lublin Soviet chemists Polymer scientists and engineers Saint Petersburg State University alumni Full Members of the USSR Academy of Sciences Saint Petersburg State University faculty Burials at Tikhvin Cemetery Soviet inventors