In
solar thermal collector
A solar thermal collector collects heat by Absorption (optics), absorbing sunlight. The term "solar collector" commonly refers to a device for solar hot water panel, solar hot water heating, but may refer to large power generating installations ...
s, a selective surface or selective
absorber
In Particle physics, high energy physics experiments, an absorber is a block of material used to Absorption (electromagnetic radiation), absorb some of the energy of an incident Subatomic particle, particle in an experiment. Absorbers can be made ...
is a means of increasing its operation temperature and/or efficiency. The selectivity is defined as the
ratio
In mathematics, a ratio () shows how many times one number contains another. For example, if there are eight oranges and six lemons in a bowl of fruit, then the ratio of oranges to lemons is eight to six (that is, 8:6, which is equivalent to the ...
of
solar radiation
Sunlight is the portion of the electromagnetic radiation which is emitted by the Sun (i.e. solar radiation) and received by the Earth, in particular the visible light perceptible to the human eye as well as invisible infrared (typically p ...
absorption
Absorption may refer to:
Chemistry and biology
*Absorption (biology), digestion
**Absorption (small intestine)
*Absorption (chemistry), diffusion of particles of gas or liquid into liquid or solid materials
*Absorption (skin), a route by which su ...
(α
sol) to
thermal infrared radiation emission (ε
therm).
Selective surfaces take advantage of the differing wavelengths of incident solar radiation and the emissive radiation from the absorbing surface:
* Solar radiation covers approximately the wavelengths 350 nm to 4000 nm;
UV-A
Ultraviolet radiation, also known as simply UV, is electromagnetic radiation of wavelengths of 10–400 nanometers, shorter than that of visible light, but longer than X-rays. UV radiation is present in sunlight and constitutes about 10% of the ...
,
visible and
near infrared
Infrared (IR; sometimes called infrared light) is electromagnetic radiation (EMR) with wavelengths longer than that of visible light but shorter than microwaves. The infrared spectral band begins with the waves that are just longer than those o ...
(
NIR, or
IR-A plus
IR-B).
* Thermal
infrared radiation
Infrared (IR; sometimes called infrared light) is electromagnetic radiation (EMR) with wavelengths longer than that of visible light but shorter than microwaves. The infrared spectral band begins with the waves that are just longer than those ...
, from materials with temperatures approximately in the interval -40 to 100 °C, covers approximately the wavelengths 4000 nm to 40,000 nm = 4 um to 40 um; The thermal infrared radiation interval being named or covered by:
MIR
''Mir'' (, ; ) was a space station operated in low Earth orbit from 1986 to 2001, first by the Soviet Union and later by the Russia, Russian Federation. ''Mir'' was the first modular space station and was assembled in orbit from 1986 to ...
,
LWIR
Infrared (IR; sometimes called infrared light) is electromagnetic radiation (EMR) with wavelengths longer than that of visible light but shorter than microwaves. The infrared spectral band begins with the waves that are just longer than those of ...
or
IR-C.
Materials
Normally, a combination of materials is used. One of the first selective surfaces investigated was a semiconductor-metal tandem
– simply
copper
Copper is a chemical element; it has symbol Cu (from Latin ) and atomic number 29. It is a soft, malleable, and ductile metal with very high thermal and electrical conductivity. A freshly exposed surface of pure copper has a pinkish-orang ...
with a layer of black
cupric oxide
Copper(II) oxide or cupric oxide is an inorganic compound with the formula CuO. A black solid, it is one of the two stable oxides of copper, the other being Cu2O or copper(I) oxide (cuprous oxide). As a mineral, it is known as tenorite, or so ...
. Silicon on metal is also another example.
A different design has ceramic–metal composites (
cermet
A cermet is a composite material composed of ceramic and metal materials.
A cermet can combine attractive properties of both a ceramic, such as high temperature resistance and hardness, and those of a metal, such as the ability to undergo pla ...
s) on metal substrates.
Black
Black is a color that results from the absence or complete absorption of visible light. It is an achromatic color, without chroma, like white and grey. It is often used symbolically or figuratively to represent darkness.Eva Heller, ''P ...
chromium
Chromium is a chemical element; it has Symbol (chemistry), symbol Cr and atomic number 24. It is the first element in Group 6 element, group 6. It is a steely-grey, Luster (mineralogy), lustrous, hard, and brittle transition metal.
Chromium ...
("black chrome") and
nickel
Nickel is a chemical element; it has symbol Ni and atomic number 28. It is a silvery-white lustrous metal with a slight golden tinge. Nickel is a hard and ductile transition metal. Pure nickel is chemically reactive, but large pieces are slo ...
-plated anodized aluminum is another selective surface that is very durable, highly resistant to
humidity
Humidity is the concentration of water vapor present in the air. Water vapor, the gaseous state of water, is generally invisible to the human eye. Humidity indicates the likelihood for precipitation (meteorology), precipitation, dew, or fog t ...
or
oxidizing
Redox ( , , reduction–oxidation or oxidation–reduction) is a type of chemical reaction in which the oxidation states of the reactants change. Oxidation is the loss of electrons or an increase in the oxidation state, while reduction is ...
atmospheres and extreme
temperature
Temperature is a physical quantity that quantitatively expresses the attribute of hotness or coldness. Temperature is measurement, measured with a thermometer. It reflects the average kinetic energy of the vibrating and colliding atoms making ...
s, while being able to retain its selective properties, but expensive. One of the more popular designs – a multi-layer broadband solar absorber – consists of a metal substrate coated with multiple layers of metal and dielectric materials. While those have to be vacuum-deposited, they have been widely adopted due to their suitability for vacuum tubes.
Renewable Clean Energy
23 January 2023
Although ordinary black paint has high solar absorption, it also has high thermal emissivity, and thus it is not a selective surface.
Typical values for a selective surface might be 0.90 solar absorption and 0.10 thermal emissivity, but can range from 0.8/0.3 for paints on metal to 0.96/0.05 for commercial surfaces. Thermal emissivities as low as 0.02 have been obtained in laboratories.
Other applications
Selective surfaces are used for other applications than solar thermal collectors, such as low emissivity
Low emissivity (low ''e'' or low thermal emissivity) refers to a surface condition that emits low levels of radiant thermal (heat) energy. All materials absorb, reflect, and emit radiant energy according to Planck's law but here, the primary con ...
surfaces used in window
A window is an opening in a wall, door, roof, or vehicle that allows the exchange of light and may also allow the passage of sound and sometimes air. Modern windows are usually glazed or covered in some other transparent or translucent ma ...
glasses, which reflect thermal radiation and have high transmittance
Electromagnetic radiation can be affected in several ways by the medium in which it propagates. It can be Scattering, scattered, Absorption (electromagnetic radiation), absorbed, and Fresnel equations, reflected and refracted at discontinui ...
factors (being transparent) for visible sunlight.
See also
* Insulated glazing
*Solar cooker
A solar cooker is a device which uses the energy of direct sunlight to heat, cook or pasteurize drink and other food materials. Many solar cookers currently in use are relatively inexpensive, low-tech devices, although some are as powerful or as ...
*Solar power
Solar power, also known as solar electricity, is the conversion of energy from sunlight into electricity, either directly using photovoltaics (PV) or indirectly using concentrated solar power. Solar panels use the photovoltaic effect to c ...
*Trombe wall
A Trombe wall is a massive equator-facing wall that is painted a dark color in order to absorb thermal energy from incident sunlight and covered with a glass on the outside with an insulating air-gap between the wall and the glaze. A Trombe wall is ...
References
{{reflist
External links
Selective Surface for efficient Solar Thermal Conversion
Solar thermal energy
Optical filters