Seifertite is a
silicate mineral
Silicate minerals are rock-forming minerals made up of silicate groups. They are the largest and most important class of minerals and make up approximately 90 percent of Earth's crust.
In mineralogy, the crystalline forms of silica (silicon dio ...
with the formula SiO
2 and is one of the densest polymorphs of
silica
Silicon dioxide, also known as silica, is an oxide of silicon with the chemical formula , commonly found in nature as quartz. In many parts of the world, silica is the major constituent of sand. Silica is one of the most complex and abundant f ...
. It has only been found in
Martian
Mars, the fourth planet from the Sun, has appeared as a setting in works of fiction since at least the mid-1600s. Trends in the planet's portrayal have largely been influenced by advances in planetary science. It became the most popular celes ...
[ and lunar meteorites, where it is presumably formed from either ]tridymite
Tridymite is a high-temperature polymorphism (materials science), polymorph of silica and usually occurs as minute tabular white or colorless pseudo-hexagonal crystals, or scales, in cavities in felsic volcanic rocks. Its chemical formula is sili ...
or cristobalite
Cristobalite ( ) is a mineral polymorph of silica that is formed at very high temperatures. It has the same chemical formula as quartz, Si O2, but a distinct crystal structure. Both quartz and cristobalite are polymorphs with all the members o ...
– other polymorphs of quartz
Quartz is a hard, crystalline mineral composed of silica (silicon dioxide). The Atom, atoms are linked in a continuous framework of SiO4 silicon–oxygen Tetrahedral molecular geometry, tetrahedra, with each oxygen being shared between two tet ...
– as a result of heating during the atmospheric entry
Atmospheric entry (sometimes listed as Vimpact or Ventry) is the movement of an object from outer space into and through the gases of an atmosphere of a planet, dwarf planet, or natural satellite. Atmospheric entry may be ''uncontrolled entr ...
and impact to the Earth, at an estimated minimal pressure of 35 GPa
Grading in education is the application of standardized measurements to evaluate different levels of student achievement in a course. Grades can be expressed as letters (usually A to F), as a range (for example, 1 to 6), percentages, or as num ...
. It can also be produced in the laboratory by compressing cristobalite in a diamond anvil cell
A diamond anvil cell (DAC) is a high-pressure device used in geology, engineering, and materials science experiments. It permits the compression of a small (sub- millimeter-sized) piece of material to extreme pressures, typically up to around 1 ...
to pressures above 40 GPa. The mineral is named after Friedrich Seifert (born 1941), the founder of the Bayerisches Geoinstitut at University of Bayreuth
The University of Bayreuth (German: Universität Bayreuth) is a public research university located in Bayreuth, Germany. It is one of the youngest German universities. It is broadly organized into seven undergraduate and graduate faculties, with ...
, Germany, and is officially recognized by the International Mineralogical Association
Founded in 1958, the International Mineralogical Association (IMA) is an international group of 40 national societies. The goal is to promote the science of mineralogy and to standardize the nomenclature of the 5000 plus known mineral species. ...
.[
Seifertite forms micrometre-sized crystalline ]lamellae
Lamella (: lamellae) means a small plate or flake in Latin, and in English may refer to:
Biology
* Lamella (mycology), a papery rib beneath a mushroom cap
* Lamella (botany)
* Lamella (surface anatomy), a plate-like structure in an animal
* Lame ...
embedded into a glassy SiO2 matrix. The lamellae are rather difficult to analyze, as they vitrify within seconds under laser or electron beams used for standard Raman spectroscopy
Raman spectroscopy () (named after physicist C. V. Raman) is a Spectroscopy, spectroscopic technique typically used to determine vibrational modes of molecules, although rotational and other low-frequency modes of systems may also be observed. Ra ...
or electron-beam microanalysis, even at much reduced beam intensities. Nevertheless, it was possible to verify that it is mainly composed of SiO2 with minor inclusions of Na2O (0.40 wt.%) and Al2O3 (1.14 wt.%). X-ray diffraction
X-ray diffraction is a generic term for phenomena associated with changes in the direction of X-ray beams due to interactions with the electrons around atoms. It occurs due to elastic scattering, when there is no change in the energy of the waves. ...
reveals that the mineral has scrutinyite ( α-PbO2) type structure with an orthorhombic
In crystallography, the orthorhombic crystal system is one of the 7 crystal systems. Orthorhombic Lattice (group), lattices result from stretching a cubic crystal system, cubic lattice along two of its orthogonal pairs by two different factors, res ...
symmetry and Pbcn or Pb2n space group
In mathematics, physics and chemistry, a space group is the symmetry group of a repeating pattern in space, usually in three dimensions. The elements of a space group (its symmetry operations) are the rigid transformations of the pattern that ...
. Its lattice constants ''a'' = 4.097, ''b'' = 5.0462, ''c'' = 4.4946, ''Z'' = 4 correspond to the density of 4.294 g/cm3, which is among the highest for any forms of silica (for example, the density of quartz is 2.65 g/cm3).[First page preview]
Only stishovite
Stishovite is an extremely hard, dense tetragonal form ( polymorph) of silicon dioxide. It is very rare on the Earth's surface; however, it may be a predominant form of silicon dioxide in the Earth, especially in the lower mantle.
Stishovite w ...
has a comparable density of about 4.287 g/cm3.Stishovite summary
Handbook of mineralogy.
See also
* Coesite
Coesite () is a form (polymorphism (materials science), polymorph) of silicon dioxide (silicon, Sioxide, O2) that is formed when very high pressure (2–3 gigapascals), and moderately high temperature (), are applied to quartz. Coesite was first ...
* Stishovite
Stishovite is an extremely hard, dense tetragonal form ( polymorph) of silicon dioxide. It is very rare on the Earth's surface; however, it may be a predominant form of silicon dioxide in the Earth, especially in the lower mantle.
Stishovite w ...
References
{{Silica minerals
Silicate minerals
Orthorhombic minerals
Minerals in space group 60
Silica polymorphs
Meteorite minerals