Sealant is a substance used to block the passage of
fluid
In physics, a fluid is a liquid, gas, or other material that continuously deforms (''flows'') under an applied shear stress, or external force. They have zero shear modulus, or, in simpler terms, are substances which cannot resist any shear ...
s through openings in materials, a type of
mechanical seal
A mechanical seal is a device that helps join systems and mechanisms together by preventing leakage (e.g. in a pumping system), containing pressure, or excluding contamination. The effectiveness of a seal is dependent on adhesion in the case of ...
. In building construction ''sealant'' is sometimes synonymous with ''
caulking'' and also serve the purposes of blocking dust, sound and heat transmission. Sealants may be weak or strong, flexible or rigid, permanent or temporary. Sealants are not
adhesive
Adhesive, also known as glue, cement, mucilage, or paste, is any non-metallic substance applied to one or both surfaces of two separate items that binds them together and resists their separation.
The use of adhesives offers certain advant ...
s but some have adhesive qualities and are called ''adhesive-sealants'' or ''structural sealants''.
History
Sealants were first used in prehistory in the broadest sense as mud, grass and reeds to seal dwellings from the weather such as the daub in
wattle and daub and
thatching
Thatching is the craft of building a roof with dry vegetation such as straw, water reed, sedge (''Cladium mariscus''), rushes, heather, or palm branches, layering the vegetation so as to shed water away from the inner roof. Since the bulk of ...
. Natural sealants and adhesive-sealants included plant
resins such as pine pitch and
birch pitch
Birch tar or birch pitch is a substance (liquid when heated) derived from the dry distillation of the bark of the birch tree.
Compounds
It is composed of phenols such as guaiacol, cresol, xylenol, and creosol.
Ancient and modern uses
Birc ...
,
bitumen
Asphalt, also known as bitumen (, ), is a sticky, black, highly viscous liquid or semi-solid form of petroleum. It may be found in natural deposits or may be a refined product, and is classed as a pitch. Before the 20th century, the term a ...
,
wax,
tar,
natural gum, clay (mud) mortar,
lime mortar,
lead, blood and egg. In the 17th century glazing
putty
Putty is a material with high plasticity, similar in texture to clay or dough, typically used in domestic construction and repair as a sealant or filler. Although some types of putty (typically those using linseed oil) slowly polymerise and be ...
was first used to seal window glass made with linseed oil and chalk, later other
drying oils were also used to make oil-based putties which were often referred to as ''caulks''. In the 1920s
polymers such as
acrylic polymer
An acrylate polymer (also known as acrylic or polyacrylate) is any of a group of polymers prepared from acrylate monomers. These plastics are noted for their transparency, resistance to breakage, and elasticity.
Acrylate polymer is commonly used ...
s,
butyl polymers and silicone polymers were first developed and used in sealants. By the 1960s synthetic-polymer-based sealants were widely available.
Function
Sealants, despite not having great strength, convey a number of properties. They seal top structures to the substrate, and are particularly effective in
waterproofing processes by keeping moisture out (or in) the components in which they are used. They can provide thermal and acoustical insulation, and may serve as fire barriers. They may have electrical properties, as well. Sealants can also be used for simple smoothing or filling. They are often called upon to perform several of these functions at once.
A caulking sealant has three basic functions: It fills a gap between two or more substrates; it forms a barrier through the physical properties of the sealant itself and by adhesion to the substrate; and it maintains sealing properties for the expected lifetime, service conditions, and environments. The sealant performs these functions by way of correct formulation to achieve specific application and performance properties. Other than adhesives, however, there are few functional alternatives to the sealing process.
Soldering or
welding can perhaps be used as alternatives in certain instances, depending on the substrates and the relative movement that the substrates will see in service. However, the simplicity and reliability offered by organic elastomers usually make them the clear choice for performing these functions.
Types of sealants
A sealant may be viscous material that has little or no flow characteristics and which stay where they are applied; or they can be thin and runny so as to allow it to penetrate the substrate by means of capillary action.
Anaerobic acrylic sealants (generally referred to as impregnants) are the most desirable, as they are required to cure in the absence of air, unlike surface sealants that require air as part of the cure mechanism that changes state to become solid, once applied, and is used to prevent the penetration of air, gas, noise, dust, fire, smoke, or liquid from one location through a barrier into another.
Typically, sealants are used to close small openings that are difficult to shut with other materials, such as
concrete,
drywall, etc. Desirable properties of sealants include insolubility,
corrosion resistance, and
adhesion. Uses of sealants vary widely and sealants are used in many industries, for example,
construction,
automotive and
aerospace industries.
Sealants can be categorized in accordance with varying criteria, e. g. in accordance with the reactivity of the product in the ready-to-use condition or on the basis of its mechanical behavior after installation.
Often the intended use or the chemical basis is used to classify sealants, too. A typical classification system for most commonly used sealants is shown below.

Types of sealants fall between the higher-strength, adhesive-derived sealers and
coatings at one end, and extremely low-strength putties, waxes, and caulks at the other. Putties and caulks serve only one function – i.e., to take up space and fill voids. Sealants maybe based on
Silicone
A silicone or polysiloxane is a polymer made up of siloxane (−R2Si−O−SiR2−, where R = organic group). They are typically colorless oils or rubber-like substances. Silicones are used in sealants, adhesives, lubricants, medicine, cooking ...
- and has a proven long life and is unaffected by UV or extremes of weather or temperature.
See below for other common types of sealants -
Common areas of use
Aerospace sealants
* Firewall Sealants - a two-component, firewall sealant intended for use as a coating, sealant or filleting material in the construction, repair and maintenance of aircraft and is especially useful where fire resistance, exposure to phosphate ester fluids, and/or exposure to extreme temperatures -65°F (-54°C) to 400°F (204°C) are major considerations.
* Fuel Tank Sealants - High-temperature fuel resistant sealant intended for use on integral fuel tanks with excellent resistance to other fluids such as water, alcohols, synthetic oils and petroleum-based hydraulic fluids
* Access Door Sealants - Access door sealant intended for use on integral fuel tanks and pressurized cabins with low adhesion characteristics and excellent resistance to other fluids such as water, alcohols, synthetic oils and petroleum based hydraulic fluids.
* Windshield Sealant - Demonstrated to be a useful sealant in a variety of applications where quick setting is desired, for example, windshield sealants, repair caulks, adhesives, etc.
Comparison with adhesives
The main difference between
adhesive
Adhesive, also known as glue, cement, mucilage, or paste, is any non-metallic substance applied to one or both surfaces of two separate items that binds them together and resists their separation.
The use of adhesives offers certain advant ...
s and sealants is that sealants typically have lower strength and higher elongation than adhesives do. When sealants are used between substrates having different thermal coefficients of expansion or differing elongation under stress, they need to have adequate flexibility and elongation. Sealants generally contain inert filler material and are usually formulated with an
elastomer
An elastomer is a polymer with viscoelasticity (i.e. both viscosity and elasticity) and with weak intermolecular forces, generally low Young's modulus and high failure strain compared with other materials. The term, a portmanteau of ''elastic p ...
to give the required flexibility and elongation. They usually have a paste consistency to allow filling of gaps between substrates. Low shrinkage after application is often required. Many adhesive technologies can be formulated into sealants.
References
{{Reflist
Seals (mechanical)
Materials