Sea ice
Sea ice arises as seawater freezes. Because ice is less dense than water, it floats on the ocean's surface (as does fresh water ice, which has an even lower density). Sea ice covers about 7% of the Earth's surface and about 12% of the world's o ...
is a complex composite composed primarily of pure ice in various states of
crystallization
Crystallization is the process by which solid forms, where the atoms or molecules are highly organized into a structure known as a crystal. Some ways by which crystals form are precipitating from a solution, freezing, or more rarely de ...
along with air bubbles and included pockets of
brine
Brine is a high-concentration Solution (chemistry), solution of salt (NaCl) in water (H2O). In diverse contexts, ''brine'' may refer to the salt solutions ranging from about 3.5% (a typical concentration of seawater, on the lower end of that of ...
. Understanding its growth processes is important both for
climate
Climate is the long-term weather pattern in an area, typically averaged over 30 years. More rigorously, it is the mean and variability of meteorological variables over a time spanning from months to millions of years. Some of the meteorologica ...
scientists for use in
simulation
A simulation is the imitation of the operation of a real-world process or system over time. Simulations require the use of models; the model represents the key characteristics or behaviors of the selected system or process, whereas the ...
s as well
remote sensing
Remote sensing is the acquisition of information about an object or phenomenon without making physical contact with the object, in contrast to in situ or on-site observation. The term is applied especially to acquiring information about Ear ...
specialists since the composition and microstructural properties of the ice ultimately affect how it interacts with
electromagnetic radiation
In physics, electromagnetic radiation (EMR) consists of waves of the electromagnetic (EM) field, which propagate through space and carry momentum and electromagnetic radiant energy. It includes radio waves, microwaves, infrared, (visible ...
.

Sea ice growth models for predicting the
ice distribution and extent are also valuable for shipping concerns. An ice growth model can be combined with
remote sensing
Remote sensing is the acquisition of information about an object or phenomenon without making physical contact with the object, in contrast to in situ or on-site observation. The term is applied especially to acquiring information about Ear ...
measurements in an
assimilation
Assimilation may refer to:
Culture
*Cultural assimilation, the process whereby a minority group gradually adapts to the customs and attitudes of the prevailing culture and customs
**Language shift, also known as language assimilation, the progre ...
model as a means of generating more accurate
ice charts.
Overview
Several formation mechanisms of sea ice have been identified. At its earliest stages, sea ice
consists of elongated, randomly oriented
crystals
A crystal or crystalline solid is a solid material whose constituents (such as atoms, molecules, or ions) are arranged in a highly ordered microscopic structure, forming a crystal lattice that extends in all directions. In addition, macros ...
. This is called
frazil and mixed with water in
the unconsolidated state is known as
grease ice. If wave and wind conditions are calm, these
crystals will consolidate at the surface and by selective pressure, begin to grow preferentially
in the downward direction, forming
nilas. In more turbulent conditions, the frazil will consolidate
by mechanical action to form
pancake ice, which has a more random structure
[
]
[
]
Another common formation mechanism,
especially in the
Antarctic
The Antarctic ( or , American English also or ; commonly ) is a polar region around Earth's South Pole, opposite the Arctic region around the North Pole. The Antarctic comprises the continent of Antarctica, the Kerguelen Plateau and o ...
where
precipitation
In meteorology, precipitation is any product of the condensation of atmospheric water vapor that falls under gravitational pull from clouds. The main forms of precipitation include drizzle, rain, sleet, snow, ice pellets, graupel and hai ...
over sea ice is high, is from snow deposition: on
thin ice, the snow will weigh down the ice enough to cause flooding. Subsequent freezing will
form ice with a much more granular structure.
[
]
[
]
One of the more interesting processes to occur within consolidated ice packs is changes in
the
saline
Saline may refer to:
* Saline (medicine), a liquid with salt content to match the human body
* Saline water, non-medicinal salt water
* Saline, a historical term (especially US) for a salt works or saltern
Places
* Saline, Calvados, a commune in ...
content. As the ice freezes, most of the
salt
Salt is a mineral composed primarily of sodium chloride (NaCl), a chemical compound belonging to the larger class of salts; salt in the form of a natural crystalline mineral is known as rock salt or halite. Salt is present in vast quanti ...
content gets rejected and forms highly
saline
brine
Brine is a high-concentration Solution (chemistry), solution of salt (NaCl) in water (H2O). In diverse contexts, ''brine'' may refer to the salt solutions ranging from about 3.5% (a typical concentration of seawater, on the lower end of that of ...
inclusions between the
crystals
A crystal or crystalline solid is a solid material whose constituents (such as atoms, molecules, or ions) are arranged in a highly ordered microscopic structure, forming a crystal lattice that extends in all directions. In addition, macros ...
. With decreasing temperatures in the ice sheet, the
size of the brine pockets decreases while the salt content goes up. Since ice is less
dense than
water, increasing
pressure
Pressure (symbol: ''p'' or ''P'') is the force applied perpendicular to the surface of an object per unit area over which that force is distributed. Gauge pressure (also spelled ''gage'' pressure)The preferred spelling varies by country a ...
causes some of the brine to be ejected from both the top and bottom,
producing the characteristic ‘C’-shaped salinity profile of first year ice.
[
]
Brine will also
drain through vertical channels, particularly in the melt season. Thus
multi-year ice will tend
to have both lower salinity and lower density than first-year ice
[
]
Vertical growth
The downward growth of consolidated ice in calm conditions is determined by the rate of
heat transfer
Heat transfer is a discipline of thermal engineering that concerns the generation, use, conversion, and exchange of thermal energy (heat) between physical systems. Heat transfer is classified into various mechanisms, such as thermal conduction ...
, ''Q
*'', at the ice-water interface. If we assume that the ice is in
thermal equilibrium
Two physical systems are in thermal equilibrium if there is no net flow of thermal energy between them when they are connected by a path permeable to heat. Thermal equilibrium obeys the zeroth law of thermodynamics. A system is said to be in ...
both with itself and its surroundings and that the weather conditions are known, then we can determine ''Q
*'' by solving the following equation:
:
for ''T
s'', the surface temperature. The water temperature, ''T
w'', is assumed to be at or near
freezing
Freezing is a phase transition where a liquid turns into a solid when its temperature is lowered below its freezing point. In accordance with the internationally established definition, freezing means the solidification phase change of a liquid o ...
, while the ice thickness, ''h'', is assumed to be known and we can approximate the
thermal conductivity
The thermal conductivity of a material is a measure of its ability to conduct heat. It is commonly denoted by k, \lambda, or \kappa.
Heat transfer occurs at a lower rate in materials of low thermal conductivity than in materials of high thermal ...
, ''k'', as an average over the layers (which have different salinities) or simply use the value for pure ice. The net heat flux is a total over four components:
:
which are latent, sensible, longwave and shortwave fluxes, respectively. For a description of the approximate
parameterization
In mathematics, and more specifically in geometry, parametrization (or parameterization; also parameterisation, parametrisation) is the process of finding parametric equations of a curve, a surface, or, more generally, a manifold or a variety, ...
s, see
determining surface flux under
sea ice thickness. The equation can be solved using a numerical
root-finding algorithm
In mathematics and computing, a root-finding algorithm is an algorithm for finding zeros, also called "roots", of continuous functions. A zero of a function , from the real numbers to real numbers or from the complex numbers to the complex numbe ...
such as
bisection
In geometry, bisection is the division of something into two equal or congruent parts, usually by a line, which is then called a ''bisector''. The most often considered types of bisectors are the ''segment bisector'' (a line that passes through ...
: the functional dependencies on surface temperature are given, with ''e'' being the
equilibrium vapor pressure.
While Cox and Weeks
[
]
assume thermal equilibrium, Tonboe
[
]
uses a more complex thermodynamic model based on
numerical solution
Numerical analysis is the study of algorithms that use numerical approximation (as opposed to symbolic manipulations) for the problems of mathematical analysis (as distinguished from discrete mathematics). It is the study of numerical methods th ...
of the
heat equation. This would be appropriate when the ice is thick or the weather conditions are changing rapidly.
The rate of ice growth can be calculated from heat flux by the following equation:
:
where ''L'' is the
latent heat
Latent heat (also known as latent energy or heat of transformation) is energy released or absorbed, by a body or a thermodynamic system, during a constant-temperature process — usually a first-order phase transition.
Latent heat can be underst ...
of fusion for water and
is the density of ice. The growth rate in turn determines the saline content of the newly frozen ice. Empirical equations for determining the initial brine entrapment in sea ice have been derived by Cox and Weeks
and Nakawo and Sinha
[
]
and take the form:
:
where ''S'' is ice salinity, ''S
0'' is the salinity of the parent water and ''f'' is an empirical function of ice growth rate, e.g.:
:
where ''g'' is in cm/s.
Salt content
Brine entrapped in sea ice will always be at or near freezing since any departure will either cause some of the water in the brine to freeze, or melt some of the surrounding ice. Thus, brine salinity is variable and can be determined based strictly on temperature—see
freezing point depression. References
and
[
]
contain empirical formulas relating sea ice temperature to brine salinity.
The relative brine volume, ''V
b'', is defined as the fraction of brine relative to the total volume. It too is highly variable, however its value is more difficult to determine since changes in temperature may cause some of the brine to be ejected or move within the layers, particularly in new ice. Writing equations relating the salt content of the brine, the total salt content, the brine volume, the density of the brine and the density of the ice and solving for brine volume produces the following relation:
:
where ''S'' is sea ice salinity, ''S
b'' is brine salinity,
is the density of the ice and
is brine density. Compare with this empirical formula from Ulaby et al.:
:
where ''T'' is ice temperature in degrees
Celsius and ''S'' is ice salinity in
parts per thousand.
In new ice, the amount of brine ejected as the ice cools can be determined by assuming that the total volume stays constant and subtracting the volume increase from the brine volume. Note that this is only applicable to newly formed ice: any warming will tend to generate air pockets as the brine volume will increase more slowly than the ice volume decreases, again due to the density difference.
Cox and Weeks
provide the following formula determining the ratio of total ice salinity between temperatures, ''T
1'' and ''T
2'' where ''T
2'' < ''T
1'':
:
where ''c''=0.8 kg m
−3 is a constant.
As the ice goes through constant warming and cooling cycles, it becomes progressively more
porous
Porosity or void fraction is a measure of the void (i.e. "empty") spaces in a material, and is a fraction of the volume of voids over the total volume, between 0 and 1, or as a percentage between 0% and 100%. Strictly speaking, some tests measure ...
through ejection of the brine and drainage through the resulting channels.
The figure above shows a
scatter plot
A scatter plot (also called a scatterplot, scatter graph, scatter chart, scattergram, or scatter diagram) is a type of plot or mathematical diagram using Cartesian coordinates to display values for typically two variables for a set of data. ...
of salinity versus ice thickness for ice cores taken from the
Weddell Sea
The Weddell Sea is part of the Southern Ocean and contains the Weddell Gyre. Its land boundaries are defined by the bay formed from the coasts of Coats Land and the Antarctic Peninsula. The easternmost point is Cape Norvegia at Princess Mar ...
,
Antarctica
Antarctica () is Earth's southernmost and least-populated continent. Situated almost entirely south of the Antarctic Circle and surrounded by the Southern Ocean, it contains the geographic South Pole. Antarctica is the fifth-largest co ...
, with an exponential fit of the form,
, overlaid, where ''h'' is ice thickness and ''a'' and ''b'' are constants.
Horizontal motion
The horizontal motion of sea ice is quite difficult to model because ice is a
non-Newtonian fluid
A non-Newtonian fluid is a fluid that does not follow Newton's law of viscosity, i.e., constant viscosity independent of stress. In non-Newtonian fluids, viscosity can change when under force to either more liquid or more solid. Ketchup, for exa ...
.
Sea ice will deform primarily at
fracture points which in turn will form at the points of greatest
stress and lowest
strength, or where the ratio between the two is a maximum. Ice thickness, salinity and
porosity
Porosity or void fraction is a measure of the void (i.e. "empty") spaces in a material, and is a fraction of the volume of voids over the total volume, between 0 and 1, or as a percentage between 0% and 100%. Strictly speaking, some tests measure ...
will all affect the strength of the ice. The motion of the ice is driven primarily by ocean currents, though to a lesser extent by wind. Note that stresses will not be in the direction of the winds or currents, but rather will be shifted by
coriolis effects—see, for instance,
Ekman spiral
The oceanic, wind driven Ekman spiral is the result of a force balance created by a shear stress force, Coriolis force and the water drag. This force balance gives a resulting current of the water different from the winds. In the ocean, there are ...
.
See also
*
Sea ice
Sea ice arises as seawater freezes. Because ice is less dense than water, it floats on the ocean's surface (as does fresh water ice, which has an even lower density). Sea ice covers about 7% of the Earth's surface and about 12% of the world's o ...
*
Sea ice thickness
*
Sea ice concentration
*
Sea ice emissivity modelling
References
Sea ice
Climatology