Scolecite is a

tectosilicate Silicate minerals are rock-forming minerals made up of silicate groups. They are the largest and most important class of minerals and make up approximately 90 percent of Earth's crust. In mineralogy, the crystalline forms of silica (silicon dio ...

mineral In geology and mineralogy, a mineral or mineral species is, broadly speaking, a solid substance with a fairly well-defined chemical composition and a specific crystal structure that occurs naturally in pure form.John P. Rafferty, ed. (2011): Mi ...

belonging to the

zeolite Zeolites are a group of several microporous, crystalline aluminosilicate minerals commonly used as commercial adsorbents and catalysts. They mainly consist of silicon, aluminium, oxygen, and have the general formula ･y where is either a meta ...

group; it is a hydrated

calcium Calcium is a chemical element; it has symbol Ca and atomic number 20. As an alkaline earth metal, calcium is a reactive metal that forms a dark oxide-nitride layer when exposed to air. Its physical and chemical properties are most similar to it ...

silicate A silicate is any member of a family of polyatomic anions consisting of silicon and oxygen, usually with the general formula , where . The family includes orthosilicate (), metasilicate (), and pyrosilicate (, ). The name is also used ...

, Ca Al₂ Si₃ O₁₀· 3H₂O. Only minor amounts of

sodium Sodium is a chemical element; it has Symbol (chemistry), symbol Na (from Neo-Latin ) and atomic number 11. It is a soft, silvery-white, highly reactive metal. Sodium is an alkali metal, being in group 1 element, group 1 of the peri ...

and traces of

potassium Potassium is a chemical element; it has Symbol (chemistry), symbol K (from Neo-Latin ) and atomic number19. It is a silvery white metal that is soft enough to easily cut with a knife. Potassium metal reacts rapidly with atmospheric oxygen to ...

substitute for calcium. There is an absence of

barium Barium is a chemical element; it has symbol Ba and atomic number 56. It is the fifth element in group 2 and is a soft, silvery alkaline earth metal. Because of its high chemical reactivity, barium is never found in nature as a free element. Th ...

strontium Strontium is a chemical element; it has symbol Sr and atomic number 38. An alkaline earth metal, it is a soft silver-white yellowish metallic element that is highly chemically reactive. The metal forms a dark oxide layer when it is exposed to ...

iron Iron is a chemical element; it has symbol Fe () and atomic number 26. It is a metal that belongs to the first transition series and group 8 of the periodic table. It is, by mass, the most common element on Earth, forming much of Earth's o ...

and

magnesium Magnesium is a chemical element; it has Symbol (chemistry), symbol Mg and atomic number 12. It is a shiny gray metal having a low density, low melting point and high chemical reactivity. Like the other alkaline earth metals (group 2 ...

.Zeolites of the World (1992) Scolecite is isostructural (having the same structure) with the sodium-calcium zeolite mesolite and the

zeolite natrolite, but it does not form a continuous chemical series with either of them. It was described in 1813, and named from the

Greek Greek may refer to: Anything of, from, or related to Greece, a country in Southern Europe: *Greeks, an ethnic group *Greek language, a branch of the Indo-European language family **Proto-Greek language, the assumed last common ancestor of all kno ...

word, σκώληξ (sko-lecks) = "worm" because of its reaction to the blowpipe

flame A flame () is the visible, gaseous part of a fire. It is caused by a highly exothermic chemical reaction made in a thin zone. When flames are hot enough to have ionized gaseous components of sufficient density, they are then considered plasm ...

Crystal class

It is

monoclinic In crystallography, the monoclinic crystal system is one of the seven crystal systems. A crystal system is described by three Vector (geometric), vectors. In the monoclinic system, the crystal is described by vectors of unequal lengths, as in t ...

m with

space group In mathematics, physics and chemistry, a space group is the symmetry group of a repeating pattern in space, usually in three dimensions. The elements of a space group (its symmetry operations) are the rigid transformations of the pattern that ...

Cc, but crystals are pseudotetragonal. Scolecite, like natrolite and mesolite, usually occurs as acicular (needle-like) and fibrous aggregations. It has nearly the same angles between the crystal faces as does natrolite, but natrolite is

orthorhombic In crystallography, the orthorhombic crystal system is one of the 7 crystal systems. Orthorhombic Lattice (group), lattices result from stretching a cubic crystal system, cubic lattice along two of its orthogonal pairs by two different factors, res ...

and scolecite is

. The etched figures (figures that arise from the action of a solvent on a crystal face, and indicate its true symmetry) and the pyroelectric character of scolecite show that it

crystal A crystal or crystalline solid is a solid material whose constituents (such as atoms, molecules, or ions) are arranged in a highly ordered microscopic structure, forming a crystal lattice that extends in all directions. In addition, macros ...

lizes with a plane of symmetry, but no

axis An axis (: axes) may refer to: Mathematics *A specific line (often a directed line) that plays an important role in some contexts. In particular: ** Coordinate axis of a coordinate system *** ''x''-axis, ''y''-axis, ''z''-axis, common names ...

of symmetry, that is to say it belongs to the hemihedral class of the monoclinic system. Scolecite can therefore be distinguished from natrolite by an optical examination, since the acicular crystals do not extinguish parallel to their length between crossed

nicol prism A Nicol prism is a type of polarizer. It is an optical device made from calcite crystal used to convert ordinary light into plane polarized light. It is made in such a way that it eliminates one of the rays by total internal reflection, i.e. ...

s. Twinning on the ortho-pinacoid is usually evident.

Structure

The structure of the

aluminosilicate Aluminosilicate refers to materials containing anionic Si-O-Al linkages. Commonly, the associate cations are sodium (Na+), potassium (K+) and protons (H+). Such materials occur as minerals, coal combustion products and as synthetic materials, of ...

framework is the same for scolecite, natrolite and mesolite. Scolecite has long ordered chains, rotated 24° round the axis of the chain. One Ca

cation An ion () is an atom or molecule with a net electrical charge. The charge of an electron is considered to be negative by convention and this charge is equal and opposite to the charge of a proton, which is considered to be positive by convent ...

and three H₂O molecules are in four

ion An ion () is an atom or molecule with a net electrical charge. The charge of an electron is considered to be negative by convention and this charge is equal and opposite to the charge of a proton, which is considered to be positive by convent ...

sites in the channels parallel to the c crystal axis. There is no sign of aluminium ions occupying silicon ion sites.

Unit cell

Scolecite is a monoclinic mineral, with the angle β equal to about 109° and four formula units per

unit cell In geometry, biology, mineralogy and solid state physics, a unit cell is a repeating unit formed by the vectors spanning the points of a lattice. Despite its suggestive name, the unit cell (unlike a unit vector In mathematics, a unit vector i ...

(Z = 4). Described in this way, various sources give the following values for the parameters of the unit cell, which has one long side and two short ones: * a = 6.516 to 6.517 Å, b = 18.948 to 18.956 Å, c = 9.761 to 9.765 Å, β = 108.86 to 108.98° * a = 6.52 to 6.53 Å, b = 18.96 to 18.97 Å, c = 9.76 to 9.78 Å, β = 108.9° * a = 6.516 Å, b = 18.948 Å, c = 9.761 Å, β = 108.98° Crystals, however, are pseudotetragonal, and this can be represented by taking a different unit cell, with twice as many formula units (Z = 8) and two long sides and one short one. The axes are redefined, a and b are very nearly equal and the angle β between the new a and c axes is very nearly equal to 90° (a truly tetragonal crystal would have a = b and β = 90° exactly). The sources give the following values: *a=18.488 to 18.508 Å, b=18.891 to 18.96 Å, c=6.527 to 6.548 Å, β = 90.64 to 90.75° *a = 18.508(5) Å, b = 18.981(5) Å, c = 6.527(2) Å β = 90.64° *a = 18.508(5) Å, b = 18.981(5) Å, c = 6.527(2) Å, β = 90:64(1)° *a = 18.51 Å, b = 18.97 Å, c = 6.53 Å, β = 90.6°

Crystal habit

Scolecite commonly occurs as sprays of thin, prismatic needles, frequently flattened on one side, with slanted terminations and striated parallel to the length of the needles. The crystals appear to be pseudo-

or pseudo-

tetragonal In crystallography, the tetragonal crystal system is one of the 7 crystal systems. Tetragonal crystal lattices result from stretching a cubic lattice along one of its lattice vectors, so that the Cube (geometry), cube becomes a rectangular Pri ...

, and may be square in cross section. It also occurs as radiating groups and fibrous masses. Epitaxial intergrowths (intergrowths of two different crystalline substances in a non-random way) with mesolite, Na₂Ca₂Al₆Si₉O₃₀·8H₂O, are common. ( Natrolite, Na₂Al₂Si₃O₁₀·2H₂O, does not directly form epitaxial overgrowths on scolecite). All three minerals may be developed in the same crystal. Scolecite crystals appear to be monoclinic by X-ray analysis.American Minerlaogist (1988) 73:613 Common forms include , , , and .

Physical properties

Scolecite is usually colorless or white, but can also be pink, salmon, red or green. It is transparent to translucent, with a white streak and a luster which is vitreous, or silky for fibrous specimens. It has a

Mohs hardness The Mohs scale ( ) of mineral hardness is a qualitative ordinal scale, from 1 to 10, characterizing scratch resistance of mineral In geology and mineralogy, a mineral or mineral species is, broadly speaking, a solid substance with a fair ...

of 5 to and a

specific gravity Relative density, also called specific gravity, is a dimensionless quantity defined as the ratio of the density (mass of a unit volume) of a substance to the density of a given reference material. Specific gravity for solids and liquids is nea ...

in the range 2.16 to 2.40. (2.24 to 2.31 2.25 to 2.29 2.16 to 2.4 2.25 to 2.31).

Cleavage Cleavage may refer to: Science * Cleavage (crystal), the way in which a crystal or mineral tends to split * Cleavage (embryo), the division of cells in an early embryo * Cleavage (geology), foliation of rock perpendicular to stress, a result of ...

is perfect in two directions parallel to the length of the crystals; the mineral is

brittle A material is brittle if, when subjected to stress, it fractures with little elastic deformation and without significant plastic deformation. Brittle materials absorb relatively little energy prior to fracture, even those of high strength. ...

with an irregular

fracture Fracture is the appearance of a crack or complete separation of an object or material into two or more pieces under the action of stress (mechanics), stress. The fracture of a solid usually occurs due to the development of certain displacemen ...

. Twinning is common on , twin axis 01 as penetration or contact twins producing V-shaped or fishtail terminations. Scolecite is pyroelectric and

piezoelectric Piezoelectricity (, ) is the electric charge that accumulates in certain solid materials—such as crystals, certain ceramics, and biological matter such as bone, DNA, and various proteins—in response to applied stress (mechanics), mechanical s ...

, sometimes

fluorescent Fluorescence is one of two kinds of photoluminescence, the emission of light by a substance that has absorbed light or other electromagnetic radiation. When exposed to ultraviolet radiation, many substances will glow (fluoresce) with color ...

yellow to brown in longwave and shortwave

ultraviolet Ultraviolet radiation, also known as simply UV, is electromagnetic radiation of wavelengths of 10–400 nanometers, shorter than that of visible light, but longer than X-rays. UV radiation is present in sunlight and constitutes about 10% of ...

light. It is soluble in common acids. Not

radioactive Radioactive decay (also known as nuclear decay, radioactivity, radioactive disintegration, or nuclear disintegration) is the process by which an unstable atomic nucleus loses energy by radiation. A material containing unstable nuclei is conside ...

Optical properties

Biaxial (-) with

refractive indices In optics, the refractive index (or refraction index) of an optical medium is the ratio of the apparent speed of light in the air or vacuum to the speed in the medium. The refractive index determines how much the path of light is bent, or refrac ...

: N_x = 1.507 to 1.513, N_y = 1.516 to 1.520, N_z = 1.517 to 1.521.

Pleochroism Pleochroism is an optical phenomenon in which a substance has different colors when observed at different angles, especially with Polarization (waves), polarized light. Etymology The roots of the word are from Greek (). It was first made compou ...

has been reported, X: colorless Y: colorless Z: colorless.

Environment

Scolecite is a common

. It is a mineral of secondary origin, and occurs with other zeolites in the amygdaloidal cavities (cavities filled with secondary minerals) of weathered basalts, also in gneisses and

amphibolite Amphibolite () is a metamorphic rock that contains amphibole, especially hornblende and actinolite, as well as plagioclase feldspar, but with little or no quartz. It is typically dark-colored and dense, with a weakly foliated or schistose ...

s, and in

laccolith A laccolith is a body of intrusive rock with a dome-shaped upper surface and a level base, fed by a conduit from below. A laccolith forms when magma (molten rock) rising through the Earth's crust begins to spread out horizontally, prying apart ...

s and dikes derived from syenitic and

gabbro Gabbro ( ) is a phaneritic (coarse-grained and magnesium- and iron-rich), mafic intrusive igneous rock formed from the slow cooling magma into a holocrystalline mass deep beneath the Earth's surface. Slow-cooling, coarse-grained gabbro is ch ...

ic magmas, and in contact metamorphic zones. It is a

hydrothermal Hydrothermal circulation in its most general sense is the circulation of hot water (Ancient Greek ὕδωρ, ''water'',Liddell, H.G. & Scott, R. (1940). ''A Greek-English Lexicon. revised and augmented throughout by Sir Henry Stuart Jones. with th ...

mineral derived from low temperature alteration of basalts and related rocks, associated with other zeolites,

calcite Calcite is a Carbonate minerals, carbonate mineral and the most stable Polymorphism (materials science), polymorph of calcium carbonate (CaCO3). It is a very common mineral, particularly as a component of limestone. Calcite defines hardness 3 on ...

quartz Quartz is a hard, crystalline mineral composed of silica (silicon dioxide). The Atom, atoms are linked in a continuous framework of SiO4 silicon–oxygen Tetrahedral molecular geometry, tetrahedra, with each oxygen being shared between two tet ...

and

prehnite Prehnite is an inosilicate of calcium and aluminium with the formula: Ca2Al(AlSi3O10)(OH)2 with limited Fe3+ substitutes for aluminium in the structure. Prehnite crystallizes in the orthorhombic crystal system, and most often forms as stalactitic ...

. It can be found on top of the calcium zeolites

heulandite Heulandite is the name of a series of tectosilicate minerals of the zeolite group. Prior to 1997, heulandite was recognized as a mineral species, but a reclassification in 1997 by the International Mineralogical Association changed it to a seri ...

stilbite Stilbite is the name of a series of tectosilicate minerals of the zeolite group. Prior to 1997, stilbite was recognized as a mineral species, but a reclassification in 1997 by the International Mineralogical Association changed it to a series nam ...

and epistilbite. Associated minerals include

apophyllite The name apophyllite refers to a specific group of phyllosilicates, a class of minerals. Originally, the group name referred to a specific mineral, but was redefined in 1978 to stand for a class of minerals of similar chemical makeup that compris ...

, babingtonite,

and other zeolites.

Localities

Scolecite was first described from Kaiserstuhl in

Baden-Württemberg Baden-Württemberg ( ; ), commonly shortened to BW or BaWü, is a states of Germany, German state () in Southwest Germany, east of the Rhine, which forms the southern part of Germany's western border with France. With more than 11.07 million i ...

in 1813. Divergent groups of prismatic crystals are found in the

basalt Basalt (; ) is an aphanite, aphanitic (fine-grained) extrusive igneous rock formed from the rapid cooling of low-viscosity lava rich in magnesium and iron (mafic lava) exposed at or very near the planetary surface, surface of a terrestrial ...

of Berufjörður near Djúpivogur, Suður-Múlasýsla,

Iceland Iceland is a Nordic countries, Nordic island country between the Atlantic Ocean, North Atlantic and Arctic Oceans, on the Mid-Atlantic Ridge between North America and Europe. It is culturally and politically linked with Europe and is the regi ...

and in the

Deccan Traps The Deccan Traps are a large igneous province of west-central India (17–24°N, 73–74°E). They are one of the largest volcanic features on Earth, taking the form of a large shield volcano. They consist of many layers of solidified flood ...

near

Pune Pune ( ; , ISO 15919, ISO: ), previously spelled in English as Poona (List of renamed Indian cities and states#Maharashtra, the official name until 1978), is a city in the state of Maharashtra in the Deccan Plateau, Deccan plateau in Western ...

India India, officially the Republic of India, is a country in South Asia. It is the List of countries and dependencies by area, seventh-largest country by area; the List of countries by population (United Nations), most populous country since ...

; hence the synonym poonahlite for this species. Other occurrences include

Riverside County, California Riverside County is a County (United States), county located in the Southern California, southern portion of the U.S. state of California. As of the 2020 United States Census, 2020 census, its population was 2,418,185, making it the fourth-most ...

;

Skye The Isle of Skye, or simply Skye, is the largest and northernmost of the major islands in the Inner Hebrides of Scotland. The island's peninsulas radiate from a mountainous hub dominated by the Cuillin, the rocky slopes of which provide some o ...

Scotland Scotland is a Countries of the United Kingdom, country that is part of the United Kingdom. It contains nearly one-third of the United Kingdom's land area, consisting of the northern part of the island of Great Britain and more than 790 adjac ...

and Santa Catarina, Brazil. There is no type locality. Most of the world's finest scolecite specimens are found in the Tertiary Deccan Basalt near Nasik, Pune, in the state of Maharashtra, India. The quarries in the Nasik region produce large, colorless sprays of well terminated coarse scolecite crystals that are commonly twinned on to form V-shaped terminations with V-shaped striations on . The scolecite is commonly found alone or on stilbite and is covered with laumontite or colorless, pale green or white fluorapophyllite. It is also found in the region as massive radiating material with powellite, and in cavities in basalt as colorless, flattened crystals in radiating sprays on blocky green apophyllite covered by tiny, thin, colorless apophyllite plates. Scolecite has been reported from many other localities, including Antarctica, Australia, Austria, Brazil, Bulgaria, Canada, Chile, Czechoslovakia, Ethiopia, Faroe Islands, France, Germany, Greenland, Hungary, Iceland, Italy, Japan, Mexico, Mozambique, Nicaragua, Peru, Poland, South Africa, Sweden, Switzerland, Taiwan, United Kingdom, United States and Yugoslavia.

References

External links

Mineral galleries
*Jmol: http://rruff.geo.arizona.edu/AMS/viewJmol.php?id=06889 {{1911, wstitle=Scolecite, volume=24, page=407 Calcium minerals Aluminium minerals Zeolites Monoclinic minerals Minerals in space group 9