Sampson Flow
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Sampson flow is defined as
fluid flow In physics, physical chemistry and engineering, fluid dynamics is a subdiscipline of fluid mechanics that describes the flow of fluids – liquids and gases. It has several subdisciplines, including (the study of air and other gases in motion ...
through an infinitely thin
orifice An orifice is any opening, mouth, hole or vent, as in a pipe, a plate, or a body * Body orifice, any opening in the body of a human or animal *Orifice plate, a restriction used to measure flow or to control pressure or flow, sometimes given specia ...
in the
viscous flow Viscosity is a measure of a fluid's rate-dependent resistance to a change in shape or to movement of its neighboring portions relative to one another. For liquids, it corresponds to the informal concept of ''thickness''; for example, syrup h ...
regime for low
Reynolds number In fluid dynamics, the Reynolds number () is a dimensionless quantity that helps predict fluid flow patterns in different situations by measuring the ratio between Inertia, inertial and viscous forces. At low Reynolds numbers, flows tend to ...
. It is derived from an analytical solution to the Navier-Stokes equations. The below equation can be used to calculate the total volumetric flowrate through such an orifice: :Q_S=\Delta P d^3 / 24 \mu Here, Q_S is the volumetric flowrate in m^3/sec, \Delta P is the pressure difference in Pa, d is the pore diameter in m, and \mu is the fluid's
dynamic viscosity Viscosity is a measure of a fluid's rate-dependent resistance to a change in shape or to movement of its neighboring portions relative to one another. For liquids, it corresponds to the informal concept of ''thickness''; for example, syrup h ...
in Pa·s. The flow can also be expressed as a molecular flux as: :J_S=P_ \Delta P d/6\pi\mu k_BT Here, J_S is the molecular flux in atoms/m2·sec, P_ is the average of the pressures on either side of the orifice, k_B is the
Boltzmann constant The Boltzmann constant ( or ) is the proportionality factor that relates the average relative thermal energy of particles in a ideal gas, gas with the thermodynamic temperature of the gas. It occurs in the definitions of the kelvin (K) and the ...
, (1.38\times10^ J/K), and T is the absolute temperature in K. Sampson flow is the macroscopic analog of
effusion In physics and chemistry, effusion is the process in which a gas escapes from a container through a hole of diameter considerably smaller than the mean free path of the molecules. Such a hole is often described as a ''pinhole'' and the escape ...
flow, which describes stochastic
diffusion Diffusion is the net movement of anything (for example, atoms, ions, molecules, energy) generally from a region of higher concentration to a region of lower concentration. Diffusion is driven by a gradient in Gibbs free energy or chemical p ...
of molecules through an orifice much smaller than the mean-free-path of the gas molecules. For pore diameters on the order of the mean-free-path of the fluid, flow will occur with contributions from the molecular regime as well as the viscous regime, obeying the dusty gas model according to the following equation: :Q_=Q_S+Q_E Here, Q_ is the total volumetric flowrate and Q_E is the volumetric flowrate according to the law of
effusion In physics and chemistry, effusion is the process in which a gas escapes from a container through a hole of diameter considerably smaller than the mean free path of the molecules. Such a hole is often described as a ''pinhole'' and the escape ...
. As it turns out, for many gasses, we notice equal contributions from molecular and viscous regimes when the pore size is significantly larger than the mean-free-path of the fluid, for nitrogen this occurs at a pore diameter of 393 nm, 6.0× larger than the mean-free-path.


References

{{Reflist Fluid dynamics