Samarium(III) sulfide ( Sm₂ S₃) is a

chemical compound A chemical compound is a chemical substance composed of many identical molecules (or molecular entities) containing atoms from more than one chemical element held together by chemical bonds. A molecule consisting of atoms of only one element ...

of the rare earth element

samarium Samarium is a chemical element; it has symbol Sm and atomic number 62. It is a moderately hard silvery metal that slowly oxidizes in air. Being a typical member of the lanthanide series, samarium usually has the oxidation state +3. Compounds of s ...

, and

sulfur Sulfur ( American spelling and the preferred IUPAC name) or sulphur ( Commonwealth spelling) is a chemical element; it has symbol S and atomic number 16. It is abundant, multivalent and nonmetallic. Under normal conditions, sulfur atoms ...

. In this compound samarium is in the +3

oxidation state In chemistry, the oxidation state, or oxidation number, is the hypothetical Electrical charge, charge of an atom if all of its Chemical bond, bonds to other atoms are fully Ionic bond, ionic. It describes the degree of oxidation (loss of electrons ...

, and sulfur is an anion in the −2 state.

Production

One way to make samarium(III) sulfide is to heat samarium metal with sulfur. Another way to make a thin film is to alternatively soak in

samarium(III) chloride Samarium(III) chloride, also known as samarium trichloride, is an inorganic compound of samarium and chloride. It is a pale yellow salt that rapidly absorbs water to form a hexahydrate, SmCl3.6H2O. The compound has few practical applications but ...

tartaric acid Tartaric acid is a white, crystalline organic acid that occurs naturally in many fruits, most notably in grapes but also in tamarinds, bananas, avocados, and citrus. Its salt (chemistry), salt, potassium bitartrate, commonly known as cream of ta ...

complex, and

sodium thiosulfate Sodium thiosulfate (sodium thiosulphate) is an inorganic compound with the formula . Typically it is available as the white or colorless pentahydrate (x = 5), which is a white solid that dissolves well in water. The compound is a reducing agent an ...

Properties

The low temperature α form crystallises in the

orthorhombic crystal system In crystallography, the orthorhombic crystal system is one of the 7 crystal systems. Orthorhombic lattices result from stretching a cubic lattice along two of its orthogonal pairs by two different factors, resulting in a rectangular prism with ...

. The unit cell has dimensions a=7.376, b=3.9622 c=15.352 Å with volume 448.7 Å₃. There are four of the formula in each unit cell (Sm₈S₁₂). The density comes out to 5.88 kg/liter. There are two kinds of samarium coordination in the solid, one is eight coordinated with sulfur surrounding in a bicapped

trigonal pyramid In chemistry, a trigonal pyramid is a molecular geometry with one atom at the apex and three atoms at the corners of a trigonal base, resembling a tetrahedron (not to be confused with the tetrahedral geometry). When all three atoms at the corner ...

. The other is a sevenfold capped distorted octahedral arrangement. This structure is similar to other light rare-earth element sulfides. Samarium(III) sulfide is a

semiconductor A semiconductor is a material with electrical conductivity between that of a conductor and an insulator. Its conductivity can be modified by adding impurities (" doping") to its crystal structure. When two regions with different doping level ...

with a

band gap In solid-state physics and solid-state chemistry, a band gap, also called a bandgap or energy gap, is an energy range in a solid where no electronic states exist. In graphs of the electronic band structure of solids, the band gap refers to t ...

of 1.7 eV. As a thin film on high area electrodes, it is under investigation as a

super capacitor alt=Supercapacitor, upright=1.5, Schematic illustration of a supercapacitor upright=1.5, A diagram that shows a hierarchical classification of supercapacitors and capacitors of related types A supercapacitor (SC), also called an ultracapacitor, ...

dielectric In electromagnetism, a dielectric (or dielectric medium) is an Insulator (electricity), electrical insulator that can be Polarisability, polarised by an applied electric field. When a dielectric material is placed in an electric field, electric ...

, with specific capacitances of up to 360

Farad The farad (symbol: F) is the unit of electrical capacitance, the ability of a body to store an electrical charge, in the International System of Units, International System of Units (SI), equivalent to 1 coulomb per volt (C/V). It is named afte ...

s per gram.

Related samarium sulfides include the monosulfide SmS and the mixed valent Sm₃S₄ which are also semiconductors. KSm₂CuS₆ is a layered quaternary sulfide.

References

{{Sulfides Sesquisulfides Samarium(III) compounds