Samarium(III) Oxalate
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Samarium(III) oxalate is an
inorganic compound An inorganic compound is typically a chemical compound that lacks carbon–hydrogen bonds⁠that is, a compound that is not an organic compound. The study of inorganic compounds is a subfield of chemistry known as ''inorganic chemistry''. Inorgan ...
, a salt of
samarium Samarium is a chemical element; it has symbol Sm and atomic number 62. It is a moderately hard silvery metal that slowly oxidizes in air. Being a typical member of the lanthanide series, samarium usually has the oxidation state +3. Compounds of s ...
and
oxalic acid Oxalic acid is an organic acid with the systematic name ethanedioic acid and chemical formula , also written as or or . It is the simplest dicarboxylic acid. It is a white crystalline solid that forms a colorless solution in water. Its name i ...
with the formula Sm2(C2O4)3. The compound does not dissolve in water, forms a crystalline hydrate with yellow crystals.


Synthesis

Precipitation In meteorology, precipitation is any product of the condensation of atmospheric water vapor that falls from clouds due to gravitational pull. The main forms of precipitation include drizzle, rain, rain and snow mixed ("sleet" in Commonwe ...
of soluble samarium salts with oxalic acid: ::\mathsf Also a reaction of samarium nitrate and oxalic acid in an aqueous solution: ::\mathsf


Physical properties

Samarium(III) oxalate forms a crystalline hydrate of the composition Sm2(C2O4)3 • 10H2O with yellow crystals.


Chemical properties

Decomposes on heating: ::\mathsf Crystalline hydrate Sm2(C2O4)3 • 10H2O decomposes stepwise.


References

{{Oxalates Oxalates Samarium(III) compounds