Sabelliite
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Sabelliite is a mineral that was first discovered at the ''Is Murvonis Mine'' in ''Dosmusnovas,
Sardinia Sardinia ( ; ; ) is the Mediterranean islands#By area, second-largest island in the Mediterranean Sea, after Sicily, and one of the Regions of Italy, twenty regions of Italy. It is located west of the Italian Peninsula, north of Tunisia an ...
''. It was discovered growing in an old fluorite mine. It grows as an inter-grown aggregate or as an isolated crystal in a compact quartzitic matrix. It appears as a platy disc-shaped emerald green transparent crystal. The mineral was named after Dr. Cesare Sabelli, researcher at the Consiglio Nazionale delle Ricerche. Sabelliite's ideal chemical formula is ( Cu, Zn)2Zn As,Antimony">Sb)O">Arsenic">As<_a>,Antimony.html" ;"title="Arsenic.html" ;"title="Arsenic">As,Antimony">Sb)O4](OH)3


Occurrence

Sabelliite occurs in quartzitic outcrops as small disc shaped crystals. Formed on foliated aggregates of theisite, which it is most similar to in both physical and chemical properties. Both sabelliite and theisite are believed to be weathering products of
sulphides Sulfide (also sulphide in British English) is an inorganic anion of sulfur with the chemical formula S2− or a compound containing one or more S2− ions. Solutions of sulfide salts are corrosive. ''Sulfide'' also refers to large families of i ...
and sulphosalts.


Physical properties

Sabelliite is a transparent emerald green crystal that grows in platy discs. The crystals appear tabular and cylindrical. The diameter of the crystals rarely exceeds 400 μm, but usually consist of crystals with a diameter of 200μm and a height of 15 μm. Sabelliite streaks light green and has a Mohs hardness of about 4.5. The crystals are brittle with no cleavage. Sabelliite has a calculated density of 4.65 g/cm³.


Optical properties

Sabelliite is a transparent mineral with an adamantine luster, or clear transparent look to it. It appears to not be fluorescent under long- or short- waved ultraviolet radiation. Sabelliite is optically nonpleochroic, uniaxial negative. Nonpleochroic means that the mineral does not appear as a different color when rotated under a microscope, while uniaxial negative means it has a single optic axis, meaning that under a microscope when rotated the light will get refracted and experience extinction.


Chemical structure

No other elements were found to be associated with sabelliite besides the ones listed in the chemical composition. The empirical formula that was derived from calculations is Cu2.19Zn0.96(As0.80Sb0.16Si0.05)Σ1.01O4.31(OH)2.69. The crystal structure refinement shows that the Zn atoms are both octahedrally and tetrahedrally coordinated.


Chemical composition


X-ray crystallography

X-ray crystallography shows that Sabelliite is a trigonal crystal, and that the crystal structure is ''P''. The data was obtained using a Gandolfi camera with a Ni-filtered CuKα radiation. The dimensions that were calculated using the X-ray diffraction are, a = 8.201(1), b = a, c = 7.315(1) Å. Volume is 426.07(9) ų. However, the structure determination may have some "inconsistencies."


See also

*
List of minerals This is a list of minerals which have Wikipedia articles. Minerals are distinguished by various chemical and physical properties. Differences in chemical composition and crystal structure distinguish the various ''species''. Within a mineral speci ...


References

{{Authority control Wikipedia Student Program Arsenate minerals Antimonate minerals Zinc minerals Trigonal minerals