Rubidium fluoride (RbF) is the
fluoride
Fluoride (). According to this source, is a possible pronunciation in British English. is an inorganic, monatomic anion of fluorine, with the chemical formula (also written ), whose salts are typically white or colorless. Fluoride salts ...
salt of
rubidium
Rubidium is the chemical element with the symbol Rb and atomic number 37. It is a very soft, whitish-grey solid in the alkali metal group, similar to potassium and caesium. Rubidium is the first alkali metal in the group to have a density hig ...
. It is a
cubic
Cubic may refer to:
Science and mathematics
* Cube (algebra), "cubic" measurement
* Cube, a three-dimensional solid object bounded by six square faces, facets or sides, with three meeting at each vertex
** Cubic crystal system, a crystal system ...
crystal
A crystal or crystalline solid is a solid material whose constituents (such as atoms, molecules, or ions) are arranged in a highly ordered microscopic structure, forming a crystal lattice that extends in all directions. In addition, macr ...
with
rock-salt
Halite (), commonly known as rock salt, is a type of salt, the mineral (natural) form of sodium chloride ( Na Cl). Halite forms isometric crystals. The mineral is typically colorless or white, but may also be light blue, dark blue, purple, pi ...
structure.
There are several methods for synthesising rubidium fluoride. One involves reacting
rubidium hydroxide
Rubidium hydroxide is the inorganic compound with the formula RbOH. It consists of rubidium cations and an equal number of hydroxide anions. It is a colorless solid that is commercially available as aqueous solutions from a few suppliers. Like ot ...
with
hydrofluoric acid
Hydrofluoric acid is a solution of hydrogen fluoride (HF) in water. Solutions of HF are colourless, acidic and highly corrosive. It is used to make most fluorine-containing compounds; examples include the commonly used pharmaceutical antidepr ...
:
:RbOH + HF → RbF + H
2O
Another method is to neutralize
rubidium carbonate
Rubidium carbonate, Rb2CO3, is a convenient compound of rubidium; it is stable, not particularly reactive, and readily soluble in water, and is the form in which rubidium is usually sold.
Preparation
This salt can be prepared by adding ammonium c ...
with hydrofluoric acid:
:Rb
2CO
3 + 2HF → 2RbF + H
2O + CO
2
Another possible method is to react rubidium hydroxide with
ammonium fluoride
Ammonium fluoride is the inorganic compound with the formula NH4F. It crystallizes as small colourless prisms, having a sharp saline taste, and is highly soluble in water. Like all fluoride salts, it is moderately toxic in both acute and chronic o ...
:
:RbOH + NH
4F → RbF + H
2O + NH
3
The least used method due to expense of rubidium metal is to react it directly with fluorine gas, as rubidium reacts violently with
halogens:
:2Rb + F
2 → 2RbF
References
*
Rubidium compounds
Fluorides
Alkali metal fluorides
Rock salt crystal structure
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