
A rotane is a
hydrocarbon consisting of a central
cycloalkane
In organic chemistry, the cycloalkanes (also called naphthenes, but distinct from naphthalene) are the monocyclic saturated hydrocarbons. In other words, a cycloalkane consists only of hydrogen and carbon atoms arranged in a structure containing ...
ring with
cyclopropane
Cyclopropane is the cycloalkane with the molecular formula (CH2)3, consisting of three methylene groups (CH2) linked to each other to form a ring. The small size of the ring creates substantial ring strain in the structure. Cyclopropane itself ...
units
spiro-linked to each corner. The
systematic naming pattern for these molecules is "
'n''otane", where ''n'' is the number of atoms in the central ring.
The simplest such chemical,
otane, consists solely of a branched array of spiro-cyclopropane units, and is thus a branched
triangulane
A triangulane is a hydrocarbon consisting exclusively of a series of spiro-linked cyclopropane rings.
Triangulanes are named according to the rules of systematic nomenclature for spiro compounds. The pattern of their common names is " 'n''riangu ...
.
References
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Hydrocarbons
Cyclopropanes
Spiro compounds
{{Hydrocarbon-stub