Riebeckite is a

sodium Sodium is a chemical element; it has Symbol (chemistry), symbol Na (from Neo-Latin ) and atomic number 11. It is a soft, silvery-white, highly reactive metal. Sodium is an alkali metal, being in group 1 element, group 1 of the peri ...

-rich member of the amphibole group of silicate minerals, chemical formula Na₂(Fe²⁺₃Fe³⁺₂)Si₈O₂₂(OH)₂. It forms a solid solution series with magnesioriebeckite. It crystallizes in the monoclinic system, usually as long prismatic crystals showing a diamond-shaped cross section, but also in fibrous, bladed, acicular, columnar, and radiating forms. Its Mohs hardness is 5.0–6.0, and its specific gravity is 3.0–3.4. Cleavage is perfect, two directions in the shape of a

diamond Diamond is a Allotropes of carbon, solid form of the element carbon with its atoms arranged in a crystal structure called diamond cubic. Diamond is tasteless, odourless, strong, brittle solid, colourless in pure form, a poor conductor of e ...

; fracture is uneven, splintery. It is often translucent to nearly opaque.

Name and discovery

Riebeckite was first described in 1888 for an occurrence on Socotra Island, Aden Governorate, Yemen, and named for German explorer Emil Riebeck (1853–1885). The mineral is also known as crocidolite.

Occurrence

Riebeckite typically forms dark-blue elongated to fibrous crystals in highly alkali

granite Granite ( ) is a coarse-grained (phanerite, phaneritic) intrusive rock, intrusive igneous rock composed mostly of quartz, alkali feldspar, and plagioclase. It forms from magma with a high content of silica and alkali metal oxides that slowly coo ...

s, syenites, rarely in felsic volcanics, granite pegmatites and schist. It occurs in banded iron formations as the asbestiform variety ''crocidolite'' (blue asbestos). It occurs in association with aegirine, nepheline, albite, arfvedsonite in igneous rocks; with tremolite, ferro- actinolite in metamorphic rocks; and with grunerite, magnetite, hematite, stilpnomelane, ankerite, siderite, calcite, chalcedonic

quartz Quartz is a hard, crystalline mineral composed of silica (silicon dioxide). The Atom, atoms are linked in a continuous framework of SiO4 silicon–oxygen Tetrahedral molecular geometry, tetrahedra, with each oxygen being shared between two tet ...

in iron formations.

Riebeckite granite

The riebeckite

known as ''ailsite'', found on the island of Ailsa Craig in western

Scotland Scotland is a Countries of the United Kingdom, country that is part of the United Kingdom. It contains nearly one-third of the United Kingdom's land area, consisting of the northern part of the island of Great Britain and more than 790 adjac ...

, is prized for its use in the manufacture of

curling Curling is a sport in which players slide #Curling stone, stones on a sheet of ice toward a target area that is segmented into four concentric circles. It is related to bowls, boules, and shuffleboard. Two teams, each with four players, take t ...

stones. Riebeckite granite was used for the facing stones of the Canton Viaduct from Moyles Quarry (a.k.a. Canton Viaduct Quarry) now part of Borderland State Park in Massachusetts, US. The commonwealth's name is even taken from an Algonquian word for the Great Blue Hill, which got its color from this form of granite.

Crocidolite (fibrous riebeckite)

The fibrous forms of riebeckite are known as ''crocidolite'' and are one of the six recognised types of asbestos. Often referred to as blue asbestos, it is considered the most hazardous. The association between blue asbestos and mesothelioma was established by J. C. Wagner, C. A. Sleggs, and P. Marchand by 1960. Crocidolite asbestos was mined in

South Africa South Africa, officially the Republic of South Africa (RSA), is the Southern Africa, southernmost country in Africa. Its Provinces of South Africa, nine provinces are bounded to the south by of coastline that stretches along the Atlantic O ...

Bolivia Bolivia, officially the Plurinational State of Bolivia, is a landlocked country located in central South America. The country features diverse geography, including vast Amazonian plains, tropical lowlands, mountains, the Gran Chaco Province, w ...

, and Wittenoom, Western Australia. Bolivian crocidolite was used in approximately 13 billion Kent Micronite cigarette filters, manufactured from March 1952 until at least May 1956 by the Lorillard Tobacco Company (now part of the R. J. Reynolds Tobacco Company). Blue asbestos was also used to similar effect, and hazard, in early gas masks.

References

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