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Rheniite is a very rare
rhenium Rhenium is a chemical element with the symbol Re and atomic number 75. It is a silvery-gray, heavy, third-row transition metal in group 7 of the periodic table. With an estimated average concentration of 1 part per billion (ppb), rhenium is on ...
sulfide Sulfide (British English also sulphide) is an inorganic anion of sulfur with the chemical formula S2− or a compound containing one or more S2− ions. Solutions of sulfide salts are corrosive. ''Sulfide'' also refers to chemical compounds l ...
mineral with the chemical formula ( ). It forms metallic, silver grey platey crystals in the
triclinic 180px, Triclinic (a ≠ b ≠ c and α ≠ β ≠ γ ) In crystallography, the triclinic (or anorthic) crystal system is one of the 7 crystal systems. A crystal system is described by three basis vectors. In the triclinic system, the crystal i ...
- pinacoidal class. It has a
specific gravity Relative density, or specific gravity, is the ratio of the density (mass of a unit volume) of a substance to the density of a given reference material. Specific gravity for liquids is nearly always measured with respect to water (molecule), wa ...
of 7.5. It was discovered at the Kudriavy Volcano,
Iturup Island , other_names = russian: Итуру́п; ja, 択捉島 , location = Sea of Okhotsk , coordinates = , archipelago = Kuril Islands , total_islands = , major_islands = , area_km2 = 3139 , length_km = 200 , width_km = 27 , coastline = , highest_moun ...
in the Kurile Islands,
Russia Russia (, , ), or the Russian Federation, is a transcontinental country spanning Eastern Europe and Northern Asia. It is the largest country in the world, with its internationally recognised territory covering , and encompassing one-eigh ...
and approved in 2004. It is found in active hot
fumarole A fumarole (or fumerole) is a vent in the surface of the Earth or other rocky planet from which hot volcanic gases and vapors are emitted, without any accompanying liquids or solids. Fumaroles are characteristic of the late stages of volcan ...
s on the
volcano A volcano is a rupture in the crust of a planetary-mass object, such as Earth, that allows hot lava, volcanic ash, and gases to escape from a magma chamber below the surface. On Earth, volcanoes are most often found where tectonic plates ...
. Rheniite is one of the first minerals of the element rhenium to be found. The other known approved rhenium mineral is the sulfide mineral tarkianite. Almost all commercially mined rhenium is retrieved as a by-product of
molybdenum Molybdenum is a chemical element with the symbol Mo and atomic number 42 which is located in period 5 and group 6. The name is from Neo-Latin ''molybdaenum'', which is based on Ancient Greek ', meaning lead, since its ores were confused with le ...
mining as rhenium occurs in amounts up to 0.2% in the mineral
molybdenite Molybdenite is a mineral of molybdenum disulfide, Mo S2. Similar in appearance and feel to graphite, molybdenite has a lubricating effect that is a consequence of its layered structure. The atomic structure consists of a sheet of molybdenum at ...
. A discredited rhenium sulfide known as ''zappinite'' does not appear to be valid. Rheniite has also been reported in the Pagoni Rachi Mo–Cu–Te–Ag–Au deposit in northeastern
Greece Greece,, or , romanized: ', officially the Hellenic Republic, is a country in Southeast Europe. It is situated on the southern tip of the Balkans, and is located at the crossroads of Europe, Asia, and Africa. Greece shares land borders wit ...
where it occurs with molybdenite in
quartz Quartz is a hard, crystalline mineral composed of silica ( silicon dioxide). The atoms are linked in a continuous framework of SiO4 silicon-oxygen tetrahedra, with each oxygen being shared between two tetrahedra, giving an overall chemical ...
veins Veins are blood vessels in humans and most other animals that carry blood towards the heart. Most veins carry deoxygenated blood from the tissues back to the heart; exceptions are the pulmonary and umbilical veins, both of which carry oxygenated ...
associated with an
epithermal Hydrothermal circulation in its most general sense is the circulation of hot water (Ancient Greek ὕδωρ, ''water'',Liddell, H.G. & Scott, R. (1940). ''A Greek-English Lexicon. revised and augmented throughout by Sir Henry Stuart Jones. with th ...
system in a
dacite Dacite () is a volcanic rock formed by rapid solidification of lava that is high in silica and low in alkali metal oxides. It has a fine-grained ( aphanitic) to porphyritic texture and is intermediate in composition between andesite and rhy ...
porphyry.Voudouris, Panagiotis C., et al., 2009, ''Rhenium-rich molybdenite and rheniite in the Pagoni Rachi Mo-Cu-Te-Ag-Au prospect, Northern Greece: implications for the Re geochemistry of porphyry-style Cu-Mo and Mo mineralization,'' Canadian Mineralogist 47, 1013-1036


References


Mineral galleries
Sulfide minerals Rhenium minerals Triclinic minerals Minerals in space group 2 Minerals described in 2005 {{Sulfide-mineral-stub