Relativistic heat conduction refers to the modelling of
heat conduction
Thermal conduction is the diffusion of thermal energy (heat) within one material or between materials in contact. The higher temperature object has molecules with more kinetic energy; collisions between molecules distributes this kinetic energy u ...
(and similar
diffusion
Diffusion is the net movement of anything (for example, atoms, ions, molecules, energy) generally from a region of higher concentration to a region of lower concentration. Diffusion is driven by a gradient in Gibbs free energy or chemical p ...
processes) in a way compatible with
special relativity
In physics, the special theory of relativity, or special relativity for short, is a scientific theory of the relationship between Spacetime, space and time. In Albert Einstein's 1905 paper, Annus Mirabilis papers#Special relativity,
"On the Ele ...
. In
special (and
general
A general officer is an Officer (armed forces), officer of high rank in the army, armies, and in some nations' air force, air and space forces, marines or naval infantry.
In some usages, the term "general officer" refers to a rank above colone ...
) relativity, the usual
heat equation
In mathematics and physics (more specifically thermodynamics), the heat equation is a parabolic partial differential equation. The theory of the heat equation was first developed by Joseph Fourier in 1822 for the purpose of modeling how a quanti ...
for non-relativistic heat conduction must be modified, as it leads to faster-than-light signal propagation.
Relativistic heat conduction, therefore, encompasses a set of models for heat propagation in continuous media (solids, fluids, gases) that are consistent with relativistic
causality, namely the principle that an effect must be within the
light-cone
In special and general relativity, a light cone (or "null cone") is the path that a flash of light, emanating from a single event (localized to a single point in space and a single moment in time) and traveling in all directions, would take t ...
associated to its cause. Any reasonable relativistic model for heat conduction must also be
stable
A stable is a building in which working animals are kept, especially horses or oxen. The building is usually divided into stalls, and may include storage for equipment and feed.
Styles
There are many different types of stables in use tod ...
, in the sense that differences in temperature propagate both slower than light and are damped over time (this stability property is intimately intertwined with relativistic causality).
Parabolic model (non-relativistic)
Heat conduction in a Newtonian context is modelled by the
Fourier equation, namely a
parabolic partial differential equation
A parabolic partial differential equation is a type of partial differential equation (PDE). Parabolic PDEs are used to describe a wide variety of time-dependent phenomena in, for example, engineering science, quantum mechanics and financial ma ...
of the kind:
where ''θ'' is
temperature
Temperature is a physical quantity that quantitatively expresses the attribute of hotness or coldness. Temperature is measurement, measured with a thermometer. It reflects the average kinetic energy of the vibrating and colliding atoms making ...
, ''t'' is
time
Time is the continuous progression of existence that occurs in an apparently irreversible process, irreversible succession from the past, through the present, and into the future. It is a component quantity of various measurements used to sequ ...
, ''α'' = ''k''/(''ρ'' ''c'') is
thermal diffusivity
In thermodynamics, thermal diffusivity is the thermal conductivity divided by density and specific heat capacity at constant pressure. It is a measure of the rate of heat transfer inside a material and has SI, SI units of m2/s. It is an intensive ...
, ''k'' is
thermal conductivity
The thermal conductivity of a material is a measure of its ability to heat conduction, conduct heat. It is commonly denoted by k, \lambda, or \kappa and is measured in W·m−1·K−1.
Heat transfer occurs at a lower rate in materials of low ...
, ''ρ'' is
density
Density (volumetric mass density or specific mass) is the ratio of a substance's mass to its volume. The symbol most often used for density is ''ρ'' (the lower case Greek letter rho), although the Latin letter ''D'' (or ''d'') can also be u ...
, and ''c'' is
specific heat capacity
In thermodynamics, the specific heat capacity (symbol ) of a substance is the amount of heat that must be added to one unit of mass of the substance in order to cause an increase of one unit in temperature. It is also referred to as massic heat ...
. The
Laplace operator
In mathematics, the Laplace operator or Laplacian is a differential operator given by the divergence of the gradient of a Scalar field, scalar function on Euclidean space. It is usually denoted by the symbols \nabla\cdot\nabla, \nabla^2 (where \ ...
,
, is defined in
Cartesian coordinates
In geometry, a Cartesian coordinate system (, ) in a plane is a coordinate system that specifies each point uniquely by a pair of real numbers called ''coordinates'', which are the signed distances to the point from two fixed perpendicular o ...
as
This Fourier equation can be derived by substituting Fourier’s linear approximation of the
heat flux
In physics and engineering, heat flux or thermal flux, sometimes also referred to as heat flux density, heat-flow density or heat-flow rate intensity, is a flow of energy per unit area per unit time (physics), time. Its SI units are watts per sq ...
vector, ''q'', as a function of
temperature gradient
A temperature gradient is a physical quantity that describes in which direction and at what rate the temperature changes the most rapidly around a particular location. The temperature spatial gradient is a vector quantity with Dimensional analysis, ...
,
into the
first law of thermodynamics
The first law of thermodynamics is a formulation of the law of conservation of energy in the context of thermodynamic processes. For a thermodynamic process affecting a thermodynamic system without transfer of matter, the law distinguishes two ...
where the
del
Del, or nabla, is an operator used in mathematics (particularly in vector calculus) as a vector differential operator, usually represented by the nabla symbol ∇. When applied to a function defined on a one-dimensional domain, it denotes ...
operator, ∇, is defined in 3D as
It can be shown that this definition of the heat flux vector also satisfies the second law of thermodynamics,
where ''s'' is specific
entropy
Entropy is a scientific concept, most commonly associated with states of disorder, randomness, or uncertainty. The term and the concept are used in diverse fields, from classical thermodynamics, where it was first recognized, to the micros ...
and ''σ'' is
entropy production
Entropy production (or generation) is the amount of entropy which is produced during heat process to evaluate the efficiency of the process.
Short history
Entropy is produced in irreversible processes. The importance of avoiding irreversible p ...
. This mathematical model is inconsistent with special relativity: the
Green function associated to the heat equation (also known as
heat kernel
In the mathematical study of heat conduction and diffusion, a heat kernel is the fundamental solution to the heat equation on a specified domain with appropriate boundary conditions. It is also one of the main tools in the study of the spectrum ...
) has support that extends outside the
light-cone
In special and general relativity, a light cone (or "null cone") is the path that a flash of light, emanating from a single event (localized to a single point in space and a single moment in time) and traveling in all directions, would take t ...
, leading to faster-than-light propagation of information. For example, consider a pulse of heat at the origin; then according to Fourier equation, it is felt (i.e. temperature changes) at any distant point, instantaneously. The speed of propagation of heat is faster than the
speed of light
The speed of light in vacuum, commonly denoted , is a universal physical constant exactly equal to ). It is exact because, by international agreement, a metre is defined as the length of the path travelled by light in vacuum during a time i ...
in vacuum, which is inadmissible within the framework of relativity.
Hyperbolic model (relativistic)
The parabolic model for heat conduction discussed above shows that the Fourier equation (and the more general
Fick's law of diffusion
Fick's laws of diffusion describe diffusion and were first posited by Adolf Fick in 1855 on the basis of largely experimental results. They can be used to solve for the Mass diffusivity, diffusion coefficient, . Fick's first law can be used to ...
) is incompatible with the theory of relativity for at least one reason: it admits infinite speed of propagation of the continuum
field (in this case: heat, or temperature gradients). To overcome this contradiction, workers such as
Carlo Cattaneo,
Vernotte, Chester, and others proposed that Fourier equation should be upgraded from the
parabolic to a
hyperbolic
Hyperbolic may refer to:
* of or pertaining to a hyperbola, a type of smooth curve lying in a plane in mathematics
** Hyperbolic geometry, a non-Euclidean geometry
** Hyperbolic functions, analogues of ordinary trigonometric functions, defined u ...
form, where the n, the temperature field
is governed by:
In this equation, ''C'' is called the speed of
second sound (that is related to
excitations and
quasiparticles
In condensed matter physics, a quasiparticle is a concept used to describe a collective behavior of a group of particles that can be treated as if they were a single particle. Formally, quasiparticles and collective excitations are closely relate ...
, like
phonons
A phonon is a collective excitation in a periodic, Elasticity (physics), elastic arrangement of atoms or molecules in condensed matter physics, condensed matter, specifically in solids and some liquids. In the context of optically trapped objects ...
). The equation is known as the "
hyperbolic
Hyperbolic may refer to:
* of or pertaining to a hyperbola, a type of smooth curve lying in a plane in mathematics
** Hyperbolic geometry, a non-Euclidean geometry
** Hyperbolic functions, analogues of ordinary trigonometric functions, defined u ...
heat conduction" (HHC) equation. Mathematically, the above equation is called "telegraph equation", as it is formally equivalent to the
telegrapher's equations, which can be derived from
Maxwell’s equations of electrodynamics.
For the HHC equation to remain compatible with the first law of thermodynamics, it is necessary to modify the definition of heat flux vector, ''q'', to
where
is a
relaxation time, such that
This equation for the heat flux is often referred to as "Maxwell-Cattaneo equation". The most important implication of the hyperbolic equation is that by switching from a parabolic (
dissipative
In thermodynamics, dissipation is the result of an irreversible process that affects a thermodynamic system. In a dissipative process, energy ( internal, bulk flow kinetic, or system potential) transforms from an initial form to a final form, wh ...
) to a hyperbolic (includes a
conservative
Conservatism is a cultural, social, and political philosophy and ideology that seeks to promote and preserve traditional institutions, customs, and values. The central tenets of conservatism may vary in relation to the culture and civiliza ...
term)
partial differential equation
In mathematics, a partial differential equation (PDE) is an equation which involves a multivariable function and one or more of its partial derivatives.
The function is often thought of as an "unknown" that solves the equation, similar to ho ...
, there is the possibility of phenomena such as thermal
resonance
Resonance is a phenomenon that occurs when an object or system is subjected to an external force or vibration whose frequency matches a resonant frequency (or resonance frequency) of the system, defined as a frequency that generates a maximu ...
and thermal
shock waves
In physics, a shock wave (also spelled shockwave), or shock, is a type of propagating disturbance that moves faster than the local speed of sound in the medium. Like an ordinary wave, a shock wave carries energy and can propagate through a me ...
.
Notes
{{Reflist, 30em
Heat conduction
Thermodynamics
Heat conduction
Thermal conduction is the diffusion of thermal energy (heat) within one material or between materials in contact. The higher temperature object has molecules with more kinetic energy; collisions between molecules distributes this kinetic energy u ...
Concepts in physics
Hyperbolic partial differential equations
Diffusion
Transport phenomena