Random Energy Model
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In the
statistical physics In physics, statistical mechanics is a mathematical framework that applies statistical methods and probability theory to large assemblies of microscopic entities. Sometimes called statistical physics or statistical thermodynamics, its applicati ...
of disordered systems, the random energy model is a
toy model A toy or plaything is an object that is used primarily to provide entertainment. Simple examples include toy blocks, board games, and dolls. Toys are often designed for use by children, although many are designed specifically for adults and ...
of a system with quenched disorder, such as a
spin glass In condensed matter physics, a spin glass is a magnetic state characterized by randomness, besides cooperative behavior in freezing of spins at a temperature called the "freezing temperature," ''T''f. In ferromagnetic solids, component atoms' ...
, having a first-order
phase transition In physics, chemistry, and other related fields like biology, a phase transition (or phase change) is the physical process of transition between one state of a medium and another. Commonly the term is used to refer to changes among the basic Sta ...
. It concerns the statistics of a collection of N spins (''i.e.'' degrees of freedom \boldsymbol\sigma\equiv \_^N that can take one of two possible values \sigma_i=\pm 1) so that the number of possible states for the system is 2^N. The energies of such states are
independent and identically distributed Independent or Independents may refer to: Arts, entertainment, and media Artist groups * Independents (artist group), a group of modernist painters based in Pennsylvania, United States * Independentes (English: Independents), a Portuguese artist ...
Gaussian
random variable A random variable (also called random quantity, aleatory variable, or stochastic variable) is a Mathematics, mathematical formalization of a quantity or object which depends on randomness, random events. The term 'random variable' in its mathema ...
s E_x \sim \mathcal(0,N/2) with zero mean and a variance of N/2. Many properties of this model can be computed exactly. Its simplicity makes this model suitable for pedagogical introduction of concepts like quenched disorder and replica symmetry.


Thermodynamic quantities

Critical energy per particle: h_c = \sqrt. Critical inverse temperature \beta_c = 2\sqrt. Partition function Z(\beta) = \sum_s e^, which at large N becomes 2^N \mathbb E_E ^/math> when \beta < \beta_c, that is, condensation does not occur. When this is true, we say that it has the self-averaging property. Free entropy per particlef(\beta) = \lim_ \frac 1N \ln Z = \begin \ln 2 + \frac 14 \beta^2 \quad & \beta < \beta_c, \\ \beta \sqrt \quad & \beta > \beta_c \end Entropy per particles(h) = \max_\beta(f(\beta) - \beta h) = \begin \ln 2 - h^2 \quad & h \in h_c, +h_c \\ 0 \quad & \text\end


Condensation

When \beta < \beta_c, the Boltzmann distribution of the system is concentrated at energy-per-particle h = -\beta/2, of which there are \sim e^ states. When \beta > \beta_c, the Boltzmann distribution of the system is concentrated at h = -h_c , and since the entropy per particle at that point is zero, the Boltzmann distribution is concentrated on a sub-exponential number of states. This is a phase transition called condensation.


Participation

Define the participation ratio asY = \sum_E p_E^2 = \fracThe participation ratio measures the amount of condensation in the Boltzmann distribution. It can be interpreted as the probability that two randomly sampled states are exactly the same state. Indeed, it is precisely the Simpson index, a commonly used diversity index. For each N, \beta, the participation ratio is a random variable determined by the energy levels. When \beta < \beta_c, the system is not in the condensed phase, and so by asymptotic equipartition, the Boltzmann distribution is asymptotically uniformly distributed over \sim e^ states. The participation ratio is then \sim e^ \times (e^)^2 = e^which decays exponentially to zero. When \beta > \beta_c, the participation ratio satisfies\lim_ \mathbb E = 1 - \fracwhere the expectation is taken over all random energy levels.


Comparison with other disordered systems

The r-spin infinite-range model, in which all r-spin sets interact with a random, independent, identically distributed interaction constant, becomes the random energy model in a suitably defined r\to\infty limit. More precisely, if the Hamiltonian of the model is defined by : H(\boldsymbol\sigma)=\sum_J_ \sigma_ \cdots \sigma_, where the sum runs over all distinct sets of r indices, and, for each such set, \, J_ is an independent Gaussian variable of mean 0 and variance J^2r!/(2 N^), the Random-Energy model is recovered in the r\to\infty limit.


Derivation of thermodynamical quantities

As its name suggests, in the REM each microscopic state has an independent distribution of energy. For a particular realization of the disorder, P(E) = \delta(E - H(\sigma)) where \sigma=(\sigma_i) refers to the individual spin configurations described by the state and H(\sigma) is the energy associated with it. The final extensive variables like the free energy need to be averaged over all realizations of the disorder, just as in the case of the
Edwards–Anderson model In condensed matter physics, a spin glass is a magnetic state characterized by randomness, besides cooperative behavior in freezing of spins at a temperature called the "freezing temperature," ''T''f. In ferromagnetic solids, component atoms' ...
. Averaging P(E) over all possible realizations, we find that the probability that a given configuration of the disordered system has an energy equal to E is given by : (E)= \sqrt\exp\left(-\dfrac\right), where
cdots The ellipsis (, plural ellipses; from , , ), rendered , alternatively described as suspension points/dots, points/periods of ellipsis, or ellipsis points, or colloquialism, colloquially, dot-dot-dot,. According to Toner it is difficult to es ...
/math> denotes the average over all realizations of the disorder. Moreover, the
joint probability distribution A joint or articulation (or articular surface) is the connection made between bones, ossicles, or other hard structures in the body which link an animal's skeletal system into a functional whole.Saladin, Ken. Anatomy & Physiology. 7th ed. McGraw- ...
of the energy values of two different microscopic configurations of the spins, \sigma and \sigma' factorizes: : (E,E') (E), (E') It can be seen that the probability of a given spin configuration only depends on the energy of that state and not on the individual spin configuration. The entropy of the REM is given by : S(E) = N\left log 2 - \left(\frac E \right)^2\right for , E, < NJ\sqrt. However this expression only holds if the entropy per spin, \lim_S(E)/N is finite, i.e., when , E, < -N J \sqrt. Since (1/T)=\partial S/\partial E, this corresponds to T>T_c=1/(2\sqrt). For T, the system remains "frozen" in a small number of configurations of energy E\simeq -N J \sqrt and the entropy per spin vanishes in the thermodynamic limit.


See also

* Random subcube model


References

{{Reflist Statistical mechanics