R. Nietzki
   HOME

TheInfoList



OR:

Rudolf Hugo Nietzki (9 March 1847 – 28 September 1917) was a German chemist who specialized in industrial dyes derived from
coal tar Coal tar is a thick dark liquid which is a by-product of the production of coke and coal gas from coal. It is a type of creosote. It has both medical and industrial uses. Medicinally it is a topical medication applied to skin to treat psoria ...
. While a professor at the
University of Basel The University of Basel (Latin: ''Universitas Basiliensis''; German: ''Universität Basel'') is a public research university in Basel, Switzerland. Founded on 4 April 1460, it is Switzerland's oldest university and among the world's oldest univ ...
in Switzerland he initiated the university's association with to the local chemical industry.


Life

Rudolf Hugo Nietzki was born on 9 March 1847 in Heilsberg, East Prussia (now
Lidzbark Warmiński Lidzbark Warmiński (; , ), often shortened to Lidzbark, is a historical town located within the Warmian-Masurian Voivodeship, in northern Poland. It is the capital of Lidzbark County. Lidzbark Warmiński was once the capital of Warmia and fo ...
, Poland) to a Protestant family. His father was Carl Johann Emil Nietzki, a priest, rector and writer. He attended the
Königsberg Königsberg (; ; ; ; ; ; , ) is the historic Germany, German and Prussian name of the city now called Kaliningrad, Russia. The city was founded in 1255 on the site of the small Old Prussians, Old Prussian settlement ''Twangste'' by the Teuton ...
gymnasium (secondary school), which he left before graduating, then began training as a pharmacist. He studied pharmacy in Zinten (now Kornevo, Kaliningrad, Russia) and Kreuzburg, Silesia (now
Kluczbork Kluczbork (, ) is a town in south-western Poland with 23,554 inhabitants (2019), situated in the Opole Voivodeship. It is the capital of Kluczbork County and an important railroad junction. In Kluczbork the major rail line from Katowice splits i ...
, Poland). In 1865 he qualified as an assistant. He worked as a pharmacist in Hirschberg, Silesia, where he met
Paul Ehrlich Paul Ehrlich (; 14 March 1854 – 20 August 1915) was a Nobel Prize-winning German physician and scientist who worked in the fields of hematology, immunology and antimicrobial chemotherapy. Among his foremost achievements were finding a cure fo ...
, who later invented chemotherapy. Nietzki attended the
University of Berlin The Humboldt University of Berlin (, abbreviated HU Berlin) is a public research university in the central borough of Mitte in Berlin, Germany. The university was established by Frederick William III on the initiative of Wilhelm von Humbol ...
from 1867 to 1870, where he studied pharmacy. He served as a military pharmacist during the
Franco-Prussian War The Franco-Prussian War or Franco-German War, often referred to in France as the War of 1870, was a conflict between the Second French Empire and the North German Confederation led by the Kingdom of Prussia. Lasting from 19 July 1870 to 28 Janua ...
of 1870–71, then returned to the university. Nietzki sat the ''
Staatsexamen The ("state examination" or "exam by state"; pl.: ''Staatsexamina'') is a German government licensing examination that future physicians, dentists, physical therapists, teachers, research librarians, archivists, pharmacists, food chemists, psyc ...
'' to qualify as a pharmacist in 1871, and served as the private assistant of the chemist
August Wilhelm von Hofmann August Wilhelm von Hofmann (8 April 18185 May 1892) was a German chemist who made considerable contributions to organic chemistry. His research on aniline helped lay the basis of the aniline-dye industry, and his research on coal tar laid the g ...
(1818–92). In 1874 he received his PhD in the
University of Göttingen The University of Göttingen, officially the Georg August University of Göttingen (, commonly referred to as Georgia Augusta), is a Public university, public research university in the city of Göttingen, Lower Saxony, Germany. Founded in 1734 ...
. After graduating Nietzki worked as an analyst in the sulfuric acid and soda factory of Matthes & Weber in
Düsseldorf Düsseldorf is the capital city of North Rhine-Westphalia, the most populous state of Germany. It is the second-largest city in the state after Cologne and the List of cities in Germany with more than 100,000 inhabitants, seventh-largest city ...
. From 1876 he was assistant to Antoine Paul Nicolas Franchimont (1844–1919) at
Leiden University Leiden University (abbreviated as ''LEI''; ) is a Public university, public research university in Leiden, Netherlands. Established in 1575 by William the Silent, William, Prince of Orange as a Protestantism, Protestant institution, it holds the d ...
. In 1879 he began to work for in
Biebrich, Rhineland Palatinate Biebrich is a municipality in the district of Rhein-Lahn, in Rhineland-Palatinate, in western Germany Germany, officially the Federal Republic of Germany, is a country in Central Europe. It lies between the Baltic Sea and the North Sea to ...
. In a letter to
Heinrich Caro Heinrich Caro (February 13, 1834 – September 11, 1910) was a German chemist. Caro was of Sephardic Jewish origin He started his study of chemistry at the Humboldt University of Berlin, Friedrich Wilhelms University and later chemistry and dy ...
that year Nietski wrote of his position with this dye company, "I have my own small but nice laboratory and nothing to do with the manufacturing; moreover I shall have the same position as you have in Ludwigshafen: That of an inventor!" In 1880 Nietzki married Minna Bickerle. He moved to
Basel Basel ( ; ), also known as Basle ( ), ; ; ; . is a city in northwestern Switzerland on the river Rhine (at the transition from the High Rhine, High to the Upper Rhine). Basel is Switzerland's List of cities in Switzerland, third-most-populo ...
, Switzerland, where he worked for Geigy. Nietzki studied for his
habilitation Habilitation is the highest university degree, or the procedure by which it is achieved, in Germany, France, Italy, Poland and some other European and non-English-speaking countries. The candidate fulfills a university's set criteria of excelle ...
under the Swiss chemist
Jules Piccard Jules Piccard, also known as Julius Piccard (20 September 1840, in Lausanne – 11 April 1933, in Lausanne) was a Swiss chemist. He was the father of twins Auguste Piccard (1884–1962) and Jean Felix Piccard (1884–1963), both renowned ballooni ...
(1840–1933) in 1884 at the
University of Basel The University of Basel (Latin: ''Universitas Basiliensis''; German: ''Universität Basel'') is a public research university in Basel, Switzerland. Founded on 4 April 1460, it is Switzerland's oldest university and among the world's oldest univ ...
. He was appointed Associate Professor of Chemistry at Basel in 1887. In 1888 Nietzki wrote a highly regarded textbook on organic dyes. In 1895 he became Professor of Chemistry. Nietzki specialized in industrially useful dyes, and initiated the University of Basel's association with the chemical industry. He worked in his private laboratory, subsidized by the state, in the Kleinbasel ice factory. He was assisted by
Friedrich Fichter Friedrich Fichter (6 July 1869 – 1952) was a professor of inorganic chemistry at the University of Basel. His main field of interest was electrochemistry. He initiated the founding of the scientific journal ''Helvetica Chimica Acta''. Life Fi ...
as inorganic chemist and
Hans Rupe Johan Hermann Wilhelm Rupe (October 9, 1866, in Basel – January 12, 1951) was a professor of organic chemistry at the University of Basel. His main field of interest was terpenes and camphor as well as optical activity. Life Rupe was born on ...
as organic chemist. Nietzki resigned due to illness in 1911. He was made Professor Emeritus by the university. He died on 28 September 1917 in
Neckargemünd Neckargemünd (; ) is a town in Germany, in the district of Rhein-Neckar-Kreis, state of Baden-Württemberg. It lies on the Neckar, 10 km upriver from Heidelberg at the confluence with the river Elsenz. This confluence of the two rivers is ...
, Baden-Württemberg.


Work

Nietzki played a leading role in the development of a new class of synthetic dyes derived from
coal tar Coal tar is a thick dark liquid which is a by-product of the production of coke and coal gas from coal. It is a type of creosote. It has both medical and industrial uses. Medicinally it is a topical medication applied to skin to treat psoria ...
. He made his name through his work on
quinone The quinones are a class of organic compounds that are formally "derived from aromatic compounds benzene.html" ;"title="uch as benzene">uch as benzene or naphthalene] by conversion of an even number of –CH= groups into –C(=O)– groups with ...
derivatives and
azo dye Azo dyes are organic compounds bearing the functional group R−N=N−R′, in which R and R′ are usually aryl and substituted aryl groups. They are a commercially important family of azo compounds, i.e. compounds containing the C−N=N−C l ...
s. In 1876 he analyzed the synthetic dye ''Anilinschwarz'' (
Aniline Aniline (From , meaning ' indigo shrub', and ''-ine'' indicating a derived substance) is an organic compound with the formula . Consisting of a phenyl group () attached to an amino group (), aniline is the simplest aromatic amine. It is an in ...
black). In 1877 he discovered that indamine dyes were formed in the oxidative coupling of p-diamines and monoamines. He synthesized nitranil acid and developed a simple method for the preparation of p-benzoquinone. In 1878 he created "
Biebrich scarlet Biebrich scarlet (C.I. 26905) is a molecule used in Lillie's trichrome. It is an anionic mono-azo dye, which is an important pigmenting agent in the textile and paper industries, used to color wool, silk, cotton, and papers. The dye was created i ...
" the first tetra azo dye. While working at Kalle & Co. Nietzki recognized that
Raphael Meldola Raphael Meldola FRS (19 July 1849 – 16 November 1915) was a British chemist and entomologist. He was Professor of Organic Chemistry in the University of London, 1912–15. Life Born in Islington, London, he was descended from Raphael Me ...
's synthetic dye, Meldola's Blue, was a member of the
oxazine Oxazines are heterocyclic compound, heterocyclic organic compounds containing one oxygen and one nitrogen atom in a cyclohexa-1,4-diene ring (a doubly unsaturated six-membered ring). Isomers exist depending on the relative position of the heteroa ...
class.


Publications

* * *


Notes


Sources

* * * * * {{DEFAULTSORT:Nietzki, Rudolf Hugo 1847 births 1917 deaths 19th-century German chemists 20th-century German chemists People from Lidzbark Warmiński