Quaterpyridine refers to a family of
pyridine
Pyridine is a basic (chemistry), basic heterocyclic compound, heterocyclic organic compound with the chemical formula . It is structurally related to benzene, with one methine group replaced by a nitrogen atom. It is a highly flammable, weakl ...
derivatives with the formula (NC
5H
4-C
5H
3N)
2. These compounds can also be viewed as
bipyridine Bipyridines also known as bipyridyls, dipyridyls, and dipyridines, are a family of chemical compounds with the formula (C5H4N)2, consisting of two pyridyl (C5H4N) rings. Pyridine is an aromatic nitrogen-containing heterocycle. Bipyridines are of si ...
decorated with two pyridyl substituents. Several isomers are known. All are colorless solids. One particular isomer, 2,2':6',2
'':6
'',2
-quaterpyridine, a derivative of
2,2'-bipyridine
The comma is a punctuation mark that appears in several variants in different languages. It has the same shape as an apostrophe or single closing quotation mark () in many typefaces, but it differs from them in being placed on the baseline o ...
has attracted interest because it is a potential
tetradentate ligand
In coordination chemistry, a ligand is an ion or molecule ( functional group) that binds to a central metal atom to form a coordination complex. The bonding with the metal generally involves formal donation of one or more of the ligand's ele ...
in
coordination chemistry
A coordination complex consists of a central atom or ion, which is usually metallic and is called the ''coordination centre'', and a surrounding array of chemical bond, bound molecules or ions, that are in turn known as ''ligands'' or complexing ...
.
[{{cite journal , doi=10.1021/acs.chemrev.6b00377, title=Quaterpyridines as Scaffolds for Functional Metallosupramolecular Materials , year=2016 , last1=Gorczyński , first1=Adam , last2=Harrowfield , first2=Jack M. , last3=Patroniak , first3=Violetta , last4=Stefankiewicz , first4=Artur R. , journal=Chemical Reviews , volume=116 , issue=23 , pages=14620–14674 , pmid=27960268 ]
Related compounds
*
terpyridine
Terpyridine (2,2';6',2"-terpyridine, often abbreviated to Terpy or Tpy) is a heterocyclic compound derived from pyridine. It is a white solid that is soluble in most organic solvents. The compound is mainly used as a ligand in coordination chemis ...
References
Chelating agents
Pyridines
Heterocyclic compounds with 4 rings