Quark matter or QCD matter (
quantum chromodynamic) refers to any of a number of hypothetical
phases of matter whose
degrees of freedom
In many scientific fields, the degrees of freedom of a system is the number of parameters of the system that may vary independently. For example, a point in the plane has two degrees of freedom for translation: its two coordinates; a non-infinite ...
include
quark
A quark () is a type of elementary particle and a fundamental constituent of matter. Quarks combine to form composite particles called hadrons, the most stable of which are protons and neutrons, the components of atomic nucleus, atomic nuclei ...
s and
gluon
A gluon ( ) is a type of Massless particle, massless elementary particle that mediates the strong interaction between quarks, acting as the exchange particle for the interaction. Gluons are massless vector bosons, thereby having a Spin (physi ...
s, of which the prominent example is
quark-gluon plasma. Several series of conferences in 2019, 2020, and 2021 were devoted to this topic.
Quarks are liberated into quark matter at extremely high temperatures and/or densities, and some of them are still only theoretical as they require conditions so extreme that they cannot be produced in any laboratory, especially not at equilibrium conditions. Under these extreme conditions, the familiar structure of
matter
In classical physics and general chemistry, matter is any substance that has mass and takes up space by having volume. All everyday objects that can be touched are ultimately composed of atoms, which are made up of interacting subatomic pa ...
, where the basic constituents are
nuclei (consisting of
nucleon
In physics and chemistry, a nucleon is either a proton or a neutron, considered in its role as a component of an atomic nucleus. The number of nucleons in a nucleus defines the atom's mass number.
Until the 1960s, nucleons were thought to be ele ...
s which are bound states of quarks) and electrons, is disrupted. In quark matter it is more appropriate to treat the quarks themselves as the basic degrees of freedom.
In the
standard model
The Standard Model of particle physics is the Scientific theory, theory describing three of the four known fundamental forces (electromagnetism, electromagnetic, weak interaction, weak and strong interactions – excluding gravity) in the unive ...
of particle physics, the
strong force
In nuclear physics and particle physics, the strong interaction, also called the strong force or strong nuclear force, is one of the four known fundamental interactions. It confines quarks into protons, neutrons, and other hadron particles, an ...
is described by the theory of
QCD
In theoretical physics
Theoretical physics is a branch of physics that employs mathematical models and abstractions of physical objects and systems to rationalize, explain, and predict List of natural phenomena, natural phenomena. This is in ...
. At ordinary temperatures or densities this force just
confines the quarks into composite particles (
hadrons
In particle physics, a hadron is a composite subatomic particle made of two or more quarks held together by the strong nuclear force. Pronounced , the name is derived . They are analogous to molecules, which are held together by the electric ...
) of size around 10
−15 m = 1
femtometer = 1 fm (corresponding to the QCD energy scale Λ
QCD ≈ 200
MeV) and its effects are not noticeable at longer distances.
However, when the temperature reaches the QCD energy scale (
T of order 10
12 kelvin
The kelvin (symbol: K) is the base unit for temperature in the International System of Units (SI). The Kelvin scale is an absolute temperature scale that starts at the lowest possible temperature (absolute zero), taken to be 0 K. By de ...
s) or the density rises to the point where the average inter-quark separation is less than 1 fm (quark
chemical potential
In thermodynamics, the chemical potential of a Chemical specie, species is the energy that can be absorbed or released due to a change of the particle number of the given species, e.g. in a chemical reaction or phase transition. The chemical potent ...
μ around 400 MeV), the hadrons are melted into their constituent quarks, and the strong interaction becomes the dominant feature of the physics. Such phases are called quark matter or QCD matter.
The strength of the color force makes the properties of quark matter unlike gas or plasma, instead leading to a state of matter more reminiscent of a liquid. At high densities, quark matter is a
Fermi liquid
Fermi liquid theory (also known as Landau's Fermi-liquid theory) is a theoretical model of interacting fermions that describes the normal state of the conduction electrons in most metals at sufficiently low temperatures. The theory describes the ...
, but is predicted to exhibit
color superconductivity at high densities and temperatures below 10
12 K.
Occurrence
Natural occurrence
* According to the
Big Bang
The Big Bang is a physical theory that describes how the universe expanded from an initial state of high density and temperature. Various cosmological models based on the Big Bang concept explain a broad range of phenomena, including th ...
theory, in the early universe at high temperatures when the universe was only a few tens of microseconds old, the phase of matter took the form of a hot phase of quark matter called the
quark–gluon plasma
Quark–gluon plasma (QGP or quark soup) is an interacting localized assembly of quarks and gluons at Thermodynamic equilibrium#Local and global equilibrium, thermal (local kinetic) and (close to) chemical (abundance) equilibrium. The word ''plasm ...
(QGP).
*
Compact star
In astronomy, the term compact object (or compact star) refers collectively to white dwarfs, neutron stars, and black holes. It could also include exotic stars if such hypothetical, dense bodies are confirmed to exist. All compact objects have a ...
s (
neutron star
A neutron star is the gravitationally collapsed Stellar core, core of a massive supergiant star. It results from the supernova explosion of a stellar evolution#Massive star, massive star—combined with gravitational collapse—that compresses ...
s). A neutron star is much cooler than 10
12 K, but gravitational collapse has compressed it to such high densities, that it is reasonable to surmise that quark matter may exist in the core. Compact stars composed mostly or entirely of quark matter are called
quark stars or
strange stars.
* QCD matter may exist within the
collapsar of a
gamma-ray burst
In gamma-ray astronomy, gamma-ray bursts (GRBs) are extremely energetic events occurring in distant Galaxy, galaxies which represent the brightest and most powerful class of explosion in the universe. These extreme Electromagnetic radiation, ele ...
, where temperatures as high as 6.7 × 10
13 K may be generated.
At this time no star with properties expected of these objects has been observed, although some evidence has been provided for quark matter in the cores of large neutron stars.
*
Strangelets. These are theoretically postulated (but as yet unobserved) lumps of
strange matter comprising nearly equal amounts of up, down and strange quarks. Strangelets are supposed to be present in the galactic flux of high energy particles and should therefore theoretically be detectable in
cosmic rays
Cosmic rays or astroparticles are high-energy particles or clusters of particles (primarily represented by protons or atomic nuclei) that move through space at nearly the speed of light. They originate from the Sun, from outside of the Solar ...
here on Earth, but no strangelet has been detected with certainty.
*
Cosmic ray
Cosmic rays or astroparticles are high-energy particles or clusters of particles (primarily represented by protons or atomic nuclei) that move through space at nearly the speed of light. They originate from the Sun, from outside of the ...
impacts. Cosmic rays comprise a lot of different particles, including highly accelerated atomic nuclei, particularly that of
iron
Iron is a chemical element; it has symbol Fe () and atomic number 26. It is a metal that belongs to the first transition series and group 8 of the periodic table. It is, by mass, the most common element on Earth, forming much of Earth's o ...
.
Laboratory experiments suggests that the inevitable interaction with heavy
noble gas
The noble gases (historically the inert gases, sometimes referred to as aerogens) are the members of Group (periodic table), group 18 of the periodic table: helium (He), neon (Ne), argon (Ar), krypton (Kr), xenon (Xe), radon (Rn) and, in some ...
nuclei in the
upper atmosphere
Upper atmosphere is a collective term that refers to various layers of the atmosphere of the Earth above the troposphere and corresponding regions of the atmospheres of other planets, and includes:
* The mesosphere, which on Earth lies between th ...
would lead to quark–gluon plasma formation.
* Quark matter with
baryon number
In particle physics, the baryon number (B) is an additive quantum number of a system. It is defined as
B = \frac(n_\text - n_),
where is the number of quarks, and is the number of antiquarks. Baryons (three quarks) have B = +1, mesons (one q ...
over about 300 may be more stable than nuclear matter. This form of baryonic matter could possibly form a
continent of stability.
Laboratory experiments

Even though quark-gluon plasma can only occur under quite extreme conditions of temperature and/or pressure, it is being actively studied at
particle colliders, such as the Large Hadron Collider
LHC at
CERN
The European Organization for Nuclear Research, known as CERN (; ; ), is an intergovernmental organization that operates the largest particle physics laboratory in the world. Established in 1954, it is based in Meyrin, western suburb of Gene ...
and the Relativistic Heavy Ion Collider
RHIC at
Brookhaven National Laboratory
Brookhaven National Laboratory (BNL) is a United States Department of Energy national laboratories, United States Department of Energy national laboratory located in Upton, New York, a hamlet of the Brookhaven, New York, Town of Brookhaven. It w ...
.
In these collisions, the plasma only occurs for a very short time before it spontaneously disintegrates. The plasma's physical characteristics are studied by detecting the debris emanating from the collision region with large particle detectors
Heavy-ion collisions at very high energies can produce small short-lived regions of space whose energy density is comparable to that of the
20-micro-second-old universe. This has been achieved by colliding heavy nuclei such as
lead
Lead () is a chemical element; it has Chemical symbol, symbol Pb (from Latin ) and atomic number 82. It is a Heavy metal (elements), heavy metal that is density, denser than most common materials. Lead is Mohs scale, soft and Ductility, malleabl ...
nuclei at high speeds, and a first time claim of formation of
quark–gluon plasma
Quark–gluon plasma (QGP or quark soup) is an interacting localized assembly of quarks and gluons at Thermodynamic equilibrium#Local and global equilibrium, thermal (local kinetic) and (close to) chemical (abundance) equilibrium. The word ''plasm ...
came from the
SPS accelerator at
CERN
The European Organization for Nuclear Research, known as CERN (; ; ), is an intergovernmental organization that operates the largest particle physics laboratory in the world. Established in 1954, it is based in Meyrin, western suburb of Gene ...
in February 2000.
This work has been continued at more powerful accelerators, such as RHIC in the US, and as of 2010 at the European LHC at CERN located in the border area of Switzerland and France. There is good evidence that the quark–gluon plasma has also been produced at RHIC.
Thermodynamics
The context for understanding the thermodynamics of quark matter is the
standard model
The Standard Model of particle physics is the Scientific theory, theory describing three of the four known fundamental forces (electromagnetism, electromagnetic, weak interaction, weak and strong interactions – excluding gravity) in the unive ...
of particle physics, which contains six different
flavors
Flavour or flavor is either the sensory perception of taste or smell, or a flavoring in food that produces such perception.
Flavour or flavor may also refer to:
Science
* Flavors (programming language), an early object-oriented extension to L ...
of quarks, as well as
lepton
In particle physics, a lepton is an elementary particle of half-integer spin (Spin (physics), spin ) that does not undergo strong interactions. Two main classes of leptons exist: electric charge, charged leptons (also known as the electron-li ...
s like
electron
The electron (, or in nuclear reactions) is a subatomic particle with a negative one elementary charge, elementary electric charge. It is a fundamental particle that comprises the ordinary matter that makes up the universe, along with up qua ...
s and
neutrino
A neutrino ( ; denoted by the Greek letter ) is an elementary particle that interacts via the weak interaction and gravity. The neutrino is so named because it is electrically neutral and because its rest mass is so small ('' -ino'') that i ...
s. These interact via the
strong interaction
In nuclear physics and particle physics, the strong interaction, also called the strong force or strong nuclear force, is one of the four known fundamental interaction, fundamental interactions. It confines Quark, quarks into proton, protons, n ...
,
electromagnetism
In physics, electromagnetism is an interaction that occurs between particles with electric charge via electromagnetic fields. The electromagnetic force is one of the four fundamental forces of nature. It is the dominant force in the interacti ...
, and also the
weak interaction
In nuclear physics and particle physics, the weak interaction, weak force or the weak nuclear force, is one of the four known fundamental interactions, with the others being electromagnetism, the strong interaction, and gravitation. It is th ...
which allows one flavor of quark to turn into another. Electromagnetic interactions occur between particles that carry electrical charge; strong interactions occur between particles that carry
color charge.
The correct thermodynamic treatment of quark matter depends on the physical context. For large quantities that exist for long periods of time (the "thermodynamic limit"), we must take into account the fact that the only conserved charges in the standard model are quark number (equivalent to
baryon
In particle physics, a baryon is a type of composite particle, composite subatomic particle that contains an odd number of valence quarks, conventionally three. proton, Protons and neutron, neutrons are examples of baryons; because baryons are ...
number), electric charge, the eight color charges, and lepton number. Each of these can have an associated chemical potential. However, large volumes of matter must be electrically and color-neutral, which determines the electric and color charge chemical potentials. This leaves a three-dimensional
phase space
The phase space of a physical system is the set of all possible physical states of the system when described by a given parameterization. Each possible state corresponds uniquely to a point in the phase space. For mechanical systems, the p ...
, parameterized by quark chemical potential, lepton chemical potential, and temperature.
In compact stars quark matter would occupy cubic kilometers and exist for millions of years, so the thermodynamic limit is appropriate. However, the neutrinos escape, violating lepton number, so the phase space for quark matter in compact stars only has two dimensions, temperature (''T'') and quark number chemical potential μ. A
strangelet is not in the thermodynamic limit of large volume, so it is like an exotic nucleus: it may carry electric charge.
A heavy-ion collision is in neither the thermodynamic limit of large volumes nor long times. Putting aside questions of whether it is sufficiently equilibrated for thermodynamics to be applicable, there is certainly not enough time for weak interactions to occur, so flavor is conserved, and there are independent chemical potentials for all six quark flavors. The initial conditions (the
impact parameter
In physics, the impact parameter is defined as the perpendicular distance between the path of a projectile and the center of a potential field created by an object that the projectile is approaching (see diagram). It is often referred to in ...
of the collision, the number of up and down quarks in the colliding nuclei, and the fact that they contain no quarks of other flavors) determine the chemical potentials. (Reference for this section:
).
Phase diagram

Based on rigorous theoretical calculations valid at ultrahigh density and a few experimental
ultrarelativistic heavy ion collision experiments, an outline of the
phase diagram of quark matter has been worked out as shown in the figure to the right. It is relevant for the understanding the core of neutron stars, where the only relevant thermodynamic potentials are quark
chemical potential
In thermodynamics, the chemical potential of a Chemical specie, species is the energy that can be absorbed or released due to a change of the particle number of the given species, e.g. in a chemical reaction or phase transition. The chemical potent ...
μ and
temperature
Temperature is a physical quantity that quantitatively expresses the attribute of hotness or coldness. Temperature is measurement, measured with a thermometer. It reflects the average kinetic energy of the vibrating and colliding atoms making ...
T.
For guidance it also shows the typical values of μ and ''T'' in heavy-ion collisions and in the early universe. For readers who are not familiar with the concept of a chemical potential, it is helpful to think of μ as a measure of the imbalance between quarks and antiquarks in the system. Higher μ means a stronger bias favoring quarks over antiquarks. At low temperatures there are no antiquarks, and then higher μ generally means a higher density of quarks.
Ordinary atomic matter as we know it is really a mixed phase, droplets of nuclear matter (nuclei) surrounded by vacuum, which exists at the low-temperature phase boundary between vacuum and nuclear matter, at μ = 310 MeV and ''T'' close to zero. If we increase the quark density (i.e. increase μ) keeping the temperature low, we move into a phase of more and more compressed nuclear matter. Following this path corresponds to burrowing more and more deeply into a
neutron star
A neutron star is the gravitationally collapsed Stellar core, core of a massive supergiant star. It results from the supernova explosion of a stellar evolution#Massive star, massive star—combined with gravitational collapse—that compresses ...
.
Eventually, at an unknown critical value of μ, there is a transition to quark matter. At ultra-high densities we expect to find the
color-flavor-locked (CFL) phase of
color-superconducting quark matter. At intermediate densities we expect some other phases (labelled "non-CFL quark liquid" in the figure) whose nature is presently unknown.
They might be other forms of color-superconducting quark matter, or something different.
Now, imagine starting at the bottom left corner of the phase diagram, in the vacuum where μ = ''T'' = 0. If we heat up the system without introducing any preference for quarks over antiquarks, this corresponds to moving vertically upwards along the ''T'' axis. At first, quarks are still confined and we create a gas of hadrons (
pion
In particle physics, a pion (, ) or pi meson, denoted with the Greek alphabet, Greek letter pi (letter), pi (), is any of three subatomic particles: , , and . Each pion consists of a quark and an antiquark and is therefore a meson. Pions are the ...
s, mostly). Then around ''T'' = 150 MeV there is a crossover to the quark gluon plasma: thermal fluctuations break up the pions, and we find a gas of quarks, antiquarks, and gluons, as well as lighter particles such as photons, electrons, positrons, etc. Following this path corresponds to travelling far back in time (so to say), to the state of the universe shortly after the big bang (where there was a very tiny preference for quarks over antiquarks).
The line that rises up from the nuclear/quark matter transition and then bends back towards the ''T'' axis, with its end marked by a star, is the conjectured boundary between confined and unconfined phases. Until recently it was also believed to be a boundary between phases where chiral symmetry is broken (low temperature and density) and phases where it is unbroken (high temperature and density). It is now known that the CFL phase exhibits chiral symmetry breaking, and other quark matter phases may also break chiral symmetry, so it is not clear whether this is really a chiral transition line. The line ends at the "chiral
critical point", marked by a star in this figure, which is a special temperature and density at which striking physical phenomena, analogous to
critical opalescence, are expected. (Reference for this section:
).
For a complete description of phase diagram it is required that one must have complete understanding of dense, strongly interacting hadronic matter and strongly interacting quark matter from some underlying theory e.g. quantum chromodynamics (QCD). However, because such a description requires the proper understanding of QCD in its non-perturbative regime, which is still far from being completely understood, any theoretical advance remains very challenging.
Theoretical challenges: calculation techniques
The phase structure of quark matter remains mostly conjectural because it is difficult to perform calculations predicting the properties of quark matter. The reason is that QCD, the theory describing the dominant interaction between quarks, is strongly coupled at the densities and temperatures of greatest physical interest, and hence it is very hard to obtain any predictions from it. Here are brief descriptions of some of the standard approaches.
Lattice gauge theory
The only first-principles calculational tool currently available is
lattice QCD
Lattice QCD is a well-established non- perturbative approach to solving the quantum chromodynamics (QCD) theory of quarks and gluons. It is a lattice gauge theory formulated on a grid or lattice of points in space and time. When the size of the ...
, i.e. brute-force computer calculations. Because of a technical obstacle known as the fermion
sign problem, this method can only be used at low density and high temperature (μ < ''T''), and it predicts that the crossover to the quark–gluon plasma will occur around ''T'' = 150 MeV However, it cannot be used to investigate the interesting color-superconducting phase structure at high density and low temperature.
Weak coupling theory
Because QCD is
asymptotically free it becomes weakly coupled at unrealistically high densities, and diagrammatic
methods can be used.
Such methods show that the CFL phase occurs at very high density. At high temperatures, however, diagrammatic methods are still not under full control.
Models
To obtain a rough idea of what phases might occur, one can use a model that has some of the same properties as QCD, but is easier to manipulate. Many physicists use
Nambu–Jona-Lasinio models, which contain no gluons, and replace the strong interaction with a
four-fermion interaction. Mean-field methods are commonly used to analyse the phases. Another approach is the
bag model, in which the effects of confinement are simulated by an additive energy density that penalizes unconfined quark matter.
Effective theories
Many physicists simply give up on a microscopic approach, and make informed guesses of the expected phases (perhaps based on NJL model results). For each phase, they then write down an effective theory for the low-energy excitations, in terms of a small number of parameters, and use it to make predictions that could allow those parameters to be fixed by experimental observations.
[
]
Other approaches
There are other methods that are sometimes used to shed light on QCD, but for various reasons have not yet yielded useful results in studying quark matter.
1/N expansion
Treat the number of colors ''N'', which is actually 3, as a large number, and expand in powers of 1/''N''. It turns out that at high density the higher-order corrections are large, and the expansion gives misleading results.
Supersymmetry
Adding scalar quarks (squarks) and fermionic gluons (gluinos) to the theory makes it more tractable, but the thermodynamics of quark matter depends crucially on the fact that only fermions can carry quark number, and on the number of degrees of freedom in general.
Experimental challenges
Experimentally, it is hard to map the phase diagram of quark matter because it has been rather difficult to learn how to tune to high enough temperatures and density in the laboratory experiment using collisions of relativistic heavy ions as experimental tools. However, these collisions ultimately will provide information about the crossover from
hadronic matter to QGP. It has been suggested that the observations of compact stars may also constrain the information about the high-density low-temperature region. Models of the cooling, spin-down, and precession of these stars offer information about the relevant properties of their interior. As observations become more precise, physicists hope to learn more.
One of the natural subjects for future research is the search for the exact location of the chiral critical point. Some ambitious lattice QCD calculations may have found evidence for it, and future calculations will clarify the situation. Heavy-ion collisions might be able to measure its position experimentally, but this will require scanning across a range of values of μ and T.
Evidence
In 2020, evidence was provided that the cores of neutron stars with mass ~2
M⊙ were likely composed of quark matter.
Their result was based on neutron-star
tidal deformability during a
neutron star merger
A neutron star merger is the stellar collision of neutron stars. When two neutron stars fall into mutual orbit, they gradually inspiral, spiral inward due to the loss of energy emitted as gravitational radiation. When they finally meet, their me ...
as measured by
gravitational-wave observatories, leading to an estimate of star radius, combined with calculations of the equation of state relating the pressure and energy density of the star's core. The evidence was strongly suggestive but did not conclusively prove the existence of quark matter.
See also
*
*
*
*
*
*
*
*
*
Sources and further reading
* Aronson, S. and Ludlam, T.
''"Hunting the quark gluon plasma"'' U.S. Dept. of Energy (2005)
* Letessier, Jean:
Hadrons and quark-gluon plasma', Cambridge monographs on particle physics, nuclear physics, and cosmology (Vol. 18), Cambridge University Press (2002)
*
*
References
External links
Virtual Journal on QCD MatterRHIC finds Exotic Antimatter
{{DEFAULTSORT:Qcd Matter
Quantum chromodynamics
Phases of matter
Unsolved problems in physics