Pyroxasulfone
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Pyroxasulfone is a pre-emergence
herbicide Herbicides (, ), also commonly known as weed killers, are substances used to control undesired plants, also known as weeds.EPA. February 201Pesticides Industry. Sales and Usage 2006 and 2007: Market Estimates. Summary in press releasMain page f ...
that inhibits the production of
very long chain fatty acids A very-long-chain fatty acid (VLCFA) is a fatty acid with 22 or more carbons. Their biosynthesis occurs in the endoplasmic reticulum. VLCFA's can represent up to a few percent of the total fatty acid content of a cell. Unlike most fatty acids, V ...
in plants. The structure of the existing herbicide thiobencarb served as the basis for development but pyroxasulfone requires a lower dose (100–25 g/ha) and is more stable resulting in longer efficacy. it had been registered for use in Japan, Australia, USA, Canada, Saudi Arabia and South Africa and was used on crops including maize, soybean, wheat and cotton. In 2015 it was applied to over 6 million hectares of land. Pyroxasulfone is from a novel chemical class but has a similar mode of action to
acetamide Acetamide (systematic name: ethanamide) is an organic compound with the formula CH3CONH2. It is an amide derived from ammonia and acetic acid. It finds some use as a plasticizer and as an industrial solvent. The related compound ''N'',''N''-dime ...
herbicides such as
metolachlor Metolachlor is an organic compound that is widely used as an herbicide. It is a derivative of aniline and is a member of the chloroacetanilide family of herbicides. It is highly effective toward grasses. Agricultural use Metolachlor was develo ...
,
acetochlor Acetochlor is an herbicide developed by Monsanto Company and Zeneca. It is a member of the class of herbicides known as chloroacetanilides. Its mode of action is elongase inhibition, and inhibition of geranylgeranyl pyrophosphate (GGPP) cyclizati ...
and dimethenamid. It is mainly used to control annual grasses but is also effective against broadleaf weeds including lambsquarters (''Chenopodium berlandieri''),
pigweed Pigweed can mean any of a number of weedy plants which may be used as pig fodder: * ''Amaranthus'' species ** ''Amaranthus albus'', white pigweed, tumble pigweed ** '' Amaranthus blitoides'', prostrate pigweed ** '' Amaranthus californicus'', Cali ...
and waterhemp (both ''Amaranthus'' species) and black nightshade (''Solanum nigrum'') Pyroxasulfone is classified by the
Herbicide Resistance Action Committee CropLife International is an international trade association of agrochemical companies founded in 2001. It was previously known as ''Global Crop Protection Federation'' and started out as ''International Group of National Associations of Manufactu ...
as Group K (Aus),
Group 15 , - ! colspan=2 style="text-align:left;" , ↓  Period , - ! 2 , , - ! 3 , , - ! 4 , , - ! 5 , , - ! 6 , , - ! 7 , , - , colspan="2", ---- ''Legend'' A pnictogen ( or ; from "to choke" and -gen, "generator") is any ...
(numeric).


Application

Stubble-cover reduces effectiveness, but a greater water rate offsets the effect. A test saw increased control of
ryegrass ''Lolium'' is a genus of tufted grasses in the bluegrass subfamily (Pooideae). It is often called ryegrass, but this term is sometimes used to refer to grasses in other genera. They are characterized by bunch-like growth habits. ''Lolium'' ...
with more water sprayed. Droplet size did not affect the results, and a similar effect was seen with
trifluralin Trifluralin is a common pre-emergent selective herbicide, a dinitroaniline. With about used in the United States in 2001, and in 2012, it is one of the most widely used herbicides. Trifluralin is also used in Australia, New Zealand, Brazil an ...
, despite large differences in adsorption and solubility. Sakura in Australia is applied at 100 g/Ha (0.09 lbs/ac)
active ingredient An active ingredient is any ingredient that provides biologically active or other direct effect in the diagnosis, cure, mitigation, treatment, or prevention of disease or to affect the structure or any function of the body of humans or animals. ...
. It requires rainfall within 7-10 days of application, and is most effective when applied right before
sowing Sowing is the process of planting seeds. An area that has had seeds planted in it will be described as a sowed or sown area. Plants which are usually sown Among the major field crops, oats, wheat, and rye are sown, grasses and legumes are ...
. If weed seeds are buried deeply, pyroxasulfone may struggle to control them. Sakura may be used on
wheat Wheat is a group of wild and crop domestication, domesticated Poaceae, grasses of the genus ''Triticum'' (). They are Agriculture, cultivated for their cereal grains, which are staple foods around the world. Well-known Taxonomy of wheat, whe ...
(not
durum wheat Durum wheat (), also called pasta wheat or macaroni wheat (''Triticum durum'' or ''Triticum turgidum'' subsp. ''durum''), is a tetraploid species of wheat. It is the second most cultivated species of wheat after common wheat, although it repres ...
),
triticale Triticale (; × ''Triticosecale'') is a hybrid of wheat (''Triticum'') and rye (''Secale'') first bred in laboratories during the late 19th century in Scotland and Germany. Commercially available triticale is almost always a second-generation ...
,
chickpea The chickpea or chick pea (''Cicer arietinum'') is an annual plant, annual legume of the family (biology), family Fabaceae, subfamily Faboideae, cultivated for its edible seeds. Its different types are variously known as gram," Bengal gram, ga ...
s, field peas,
lentil The lentil (''Vicia lens'' or ''Lens culinaris'') is an annual plant, annual legume grown for its Lens (geometry), lens-shaped edible seeds or ''pulses'', also called ''lentils''. It is about tall, and the seeds grow in Legume, pods, usually w ...
s, and
lupin ''Lupinus'', commonly known as lupin, lupine, or regionally bluebonnet, is a genus of plants in the legume family Fabaceae. The genus includes over 199 species, with centres of diversity in North and South America. Smaller centres occur in No ...
s, to control
annual ryegrass Annual ryegrass is a common name for several species of ryegrass ''Lolium'' is a genus of tufted grasses in the bluegrass subfamily (Pooideae). It is often called ryegrass, but this term is sometimes used to refer to grasses in other genera. ...
, paradoxa grass (''Phalaris paradoxa''),
barley grass Barley (), a member of the grass family, is a major cereal grain grown in temperate climates globally. It was one of the first cultivated grains; it was domesticated in the Fertile Crescent around 9000 BC, giving it nonshattering spikelets ...
, silver grass (''Vulpia myuros'') and toad rush, or to suppress great brome and wild oat.


References


Further reading

* *{{cite journal , last1=Tanetani , first1=Yoshitaka , last2=Kaku , first2=Koichiro , last3=Kawai , first3=Kiyoshi , last4=Fujioka , first4=Tomonori , last5=Shimizu , first5=Tsutomu , title=Action mechanism of a novel herbicide, pyroxasulfone , journal=Pesticide Biochemistry and Physiology , date=September 2009 , volume=95 , issue=1 , pages=47–55 , doi=10.1016/j.pestbp.2009.06.003 Herbicides Pyrazoles Oxazoles Sulfones Trifluoromethyl compounds Group 15 herbicides