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A proton is a stable subatomic particle, symbol , H+, or 1H+ with a positive
electric charge Electric charge is the physical property of matter that causes charged matter to experience a force when placed in an electromagnetic field. Electric charge can be ''positive'' or ''negative'' (commonly carried by protons and electrons respecti ...
of +1 ''e''
elementary charge The elementary charge, usually denoted by is the electric charge carried by a single proton or, equivalently, the magnitude of the negative electric charge carried by a single electron, which has charge −1 . This elementary charge is a funda ...
. Its mass is slightly less than that of a
neutron The neutron is a subatomic particle, symbol or , which has a neutral (not positive or negative) charge, and a mass slightly greater than that of a proton. Protons and neutrons constitute the nuclei of atoms. Since protons and neutrons behav ...
and 1,836 times the mass of an
electron The electron (, or in nuclear reactions) is a subatomic particle with a negative one elementary electric charge. Electrons belong to the first generation of the lepton particle family, and are generally thought to be elementary partic ...
(the
proton–electron mass ratio In physics, the proton-to-electron mass ratio, ''μ'' or ''β'', is the rest mass of the proton (a baryon found in atoms) divided by that of the electron (a lepton found in atoms), a dimensionless quantity, namely: :''μ'' = The number in parenth ...
). Protons and neutrons, each with masses of approximately one
atomic mass unit The dalton or unified atomic mass unit (symbols: Da or u) is a non-SI unit of mass widely used in physics and chemistry. It is defined as of the mass of an unbound neutral atom of carbon-12 in its nuclear and electronic ground state and at r ...
, are jointly referred to as "
nucleon In physics and chemistry, a nucleon is either a proton or a neutron, considered in its role as a component of an atomic nucleus. The number of nucleons in a nucleus defines the atom's mass number (nucleon number). Until the 1960s, nucleons w ...
s" (particles present in atomic nuclei). One or more protons are present in the
nucleus Nucleus ( : nuclei) is a Latin word for the seed inside a fruit. It most often refers to: *Atomic nucleus, the very dense central region of an atom * Cell nucleus, a central organelle of a eukaryotic cell, containing most of the cell's DNA Nucl ...
of every
atom Every atom is composed of a nucleus and one or more electrons bound to the nucleus. The nucleus is made of one or more protons and a number of neutrons. Only the most common variety of hydrogen has no neutrons. Every solid, liquid, gas ...
. They provide the attractive electrostatic central force which binds the atomic electrons. The number of protons in the nucleus is the defining property of an element, and is referred to as the
atomic number The atomic number or nuclear charge number (symbol ''Z'') of a chemical element is the charge number of an atomic nucleus. For ordinary nuclei, this is equal to the proton number (''n''p) or the number of protons found in the nucleus of every ...
(represented by the symbol ''Z''). Since each
element Element or elements may refer to: Science * Chemical element, a pure substance of one type of atom * Heating element, a device that generates heat by electrical resistance * Orbital elements, parameters required to identify a specific orbit of o ...
has a unique number of protons, each element has its own unique atomic number, which determines the number of atomic electrons and consequently the chemical characteristics of the element. The word ''proton'' is
Greek Greek may refer to: Greece Anything of, from, or related to Greece, a country in Southern Europe: *Greeks, an ethnic group. *Greek language, a branch of the Indo-European language family. **Proto-Greek language, the assumed last common ancestor ...
for "first", and this name was given to the hydrogen nucleus by
Ernest Rutherford Ernest Rutherford, 1st Baron Rutherford of Nelson, (30 August 1871 – 19 October 1937) was a New Zealand physicist who came to be known as the father of nuclear physics. ''Encyclopædia Britannica'' considers him to be the greatest ...
in 1920. In previous years, Rutherford had discovered that the
hydrogen Hydrogen is the chemical element with the symbol H and atomic number 1. Hydrogen is the lightest element. At standard conditions hydrogen is a gas of diatomic molecules having the formula . It is colorless, odorless, tasteless, non-toxic ...
nucleus (known to be the lightest nucleus) could be extracted from the nuclei of
nitrogen Nitrogen is the chemical element with the symbol N and atomic number 7. Nitrogen is a nonmetal and the lightest member of group 15 of the periodic table, often called the pnictogens. It is a common element in the universe, estimated at seve ...
by atomic collisions. Protons were therefore a candidate to be a fundamental or
elementary particle In particle physics, an elementary particle or fundamental particle is a subatomic particle that is not composed of other particles. Particles currently thought to be elementary include electrons, the fundamental fermions (quarks, leptons, antiq ...
, and hence a building block of nitrogen and all other heavier atomic nuclei. Although protons were originally considered elementary particles, in the modern
Standard Model The Standard Model of particle physics is the theory describing three of the four known fundamental forces ( electromagnetic, weak and strong interactions - excluding gravity) in the universe and classifying all known elementary particles. I ...
of
particle physics Particle physics or high energy physics is the study of fundamental particles and forces that constitute matter and radiation. The fundamental particles in the universe are classified in the Standard Model as fermions (matter particles) and ...
, protons are now known to be composite particles, containing three
valence quark In particle physics, the quark model is a classification scheme for hadrons in terms of their valence quarks—the quarks and antiquarks which give rise to the quantum numbers of the hadrons. The quark model underlies "flavor SU(3)", or the Ei ...
s, and together with
neutron The neutron is a subatomic particle, symbol or , which has a neutral (not positive or negative) charge, and a mass slightly greater than that of a proton. Protons and neutrons constitute the nuclei of atoms. Since protons and neutrons behav ...
s are now classified as
hadron In particle physics, a hadron (; grc, ἁδρός, hadrós; "stout, thick") is a composite subatomic particle made of two or more quarks held together by the strong interaction. They are analogous to molecules that are held together by the ele ...
s. Protons are composed of two
up quark The up quark or u quark (symbol: u) is the lightest of all quarks, a type of elementary particle, and a significant constituent of matter. It, along with the down quark, forms the neutrons (one up quark, two down quarks) and protons (two up qua ...
s of charge +''e'' and one
down quark The down quark or d quark (symbol: d) is the second-lightest of all quarks, a type of elementary particle, and a major constituent of matter. Together with the up quark, it forms the neutrons (one up quark, two down quarks) and protons (two u ...
of charge −''e''. The
rest mass The invariant mass, rest mass, intrinsic mass, proper mass, or in the case of bound systems simply mass, is the portion of the total mass of an object or system of objects that is independent of the overall motion of the system. More precisely, ...
es of quarks contribute only about 1% of a proton's mass. The remainder of a proton's mass is due to
quantum chromodynamics binding energy Quantum chromodynamics binding energy (QCD binding energy), gluon binding energy or chromodynamic binding energy is the energy binding quarks together into hadrons. It is the energy of the field of the strong force, which is mediated by gluons. Mo ...
, which includes the
kinetic energy In physics, the kinetic energy of an object is the energy that it possesses due to its motion. It is defined as the work needed to accelerate a body of a given mass from rest to its stated velocity. Having gained this energy during its a ...
of the quarks and the energy of the
gluon A gluon ( ) is an elementary particle that acts as the exchange particle (or gauge boson) for the strong force between quarks. It is analogous to the exchange of photons in the electromagnetic force between two charged particles. Gluons bi ...
fields that bind the quarks together. Because protons are not fundamental particles, they possess a measurable size; the
root mean square In mathematics and its applications, the root mean square of a set of numbers x_i (abbreviated as RMS, or rms and denoted in formulas as either x_\mathrm or \mathrm_x) is defined as the square root of the mean square (the arithmetic mean of th ...
charge radius The rms charge radius is a measure of the size of an atomic nucleus, particularly the proton distribution. It can be measured by the scattering of electrons by the nucleus. Relative changes in the mean squared nuclear charge distribution can be ...
of a proton is about 0.84–0.87 fm (or to ). In 2019, two different studies, using different techniques, found this radius to be 0.833 fm, with an uncertainty of ±0.010 fm. Free protons occur occasionally on Earth: thunderstorms can produce protons with energies of up to several tens of
MeV In physics, an electronvolt (symbol eV, also written electron-volt and electron volt) is the measure of an amount of kinetic energy gained by a single electron accelerating from rest through an electric potential difference of one volt in vacuum. ...
. At sufficiently low temperatures and kinetic energies, free protons will bind to
electron The electron (, or in nuclear reactions) is a subatomic particle with a negative one elementary electric charge. Electrons belong to the first generation of the lepton particle family, and are generally thought to be elementary partic ...
s. However, the character of such bound protons does not change, and they remain protons. A fast proton moving through matter will slow by interactions with electrons and nuclei, until it is captured by the
electron cloud In atomic theory and quantum mechanics, an atomic orbital is a function describing the location and wave-like behavior of an electron in an atom. This function can be used to calculate the probability of finding any electron of an atom in a ...
of an atom. The result is a protonated atom, which is a
chemical compound A chemical compound is a chemical substance composed of many identical molecules (or molecular entities) containing atoms from more than one chemical element held together by chemical bonds. A molecule consisting of atoms of only one ele ...
of hydrogen. In a vacuum, when free electrons are present, a sufficiently slow proton may pick up a single free electron, becoming a neutral
hydrogen atom A hydrogen atom is an atom of the chemical element hydrogen. The electrically neutral atom contains a single positively charged proton and a single negatively charged electron bound to the nucleus by the Coulomb force. Atomic hydrogen cons ...
, which is chemically a
free radical A daughter category of ''Ageing'', this category deals only with the biological aspects of ageing. Ageing Ailments of unknown cause Biogerontology Biological processes Causes of death Cellular processes Gerontology Life extension Metabo ...
. Such "free hydrogen atoms" tend to react chemically with many other types of atoms at sufficiently low energies. When free hydrogen atoms react with each other, they form neutral hydrogen molecules (H2), which are the most common molecular component of
molecular clouds A molecular cloud, sometimes called a stellar nursery (if star formation is occurring within), is a type of interstellar cloud, the density and size of which permit absorption nebulae, the formation of molecules (most commonly molecular hydroge ...
in
interstellar space Outer space, commonly shortened to space, is the expanse that exists beyond Earth and its atmosphere and between celestial bodies. Outer space is not completely empty—it is a near-perfect vacuum containing a low density of particles, predo ...
. Free protons are routinely used for accelerators for
proton therapy In medicine, proton therapy, or proton radiotherapy, is a type of particle therapy that uses a beam of protons to irradiate diseased tissue, most often to treat cancer. The chief advantage of proton therapy over other types of external beam r ...
or various particle physics experiments, with the most powerful example being the
Large Hadron Collider The Large Hadron Collider (LHC) is the world's largest and highest-energy particle collider. It was built by the European Organization for Nuclear Research (CERN) between 1998 and 2008 in collaboration with over 10,000 scientists and hundr ...
.


Description

Protons are spin-
fermion In particle physics, a fermion is a particle that follows Fermi–Dirac statistics. Generally, it has a half-odd-integer spin: spin , spin , etc. In addition, these particles obey the Pauli exclusion principle. Fermions include all quarks and ...
s and are composed of three valence quarks, making them
baryon In particle physics, a baryon is a type of composite subatomic particle which contains an odd number of valence quarks (at least 3). Baryons belong to the hadron family of particles; hadrons are composed of quarks. Baryons are also classi ...
s (a sub-type of
hadron In particle physics, a hadron (; grc, ἁδρός, hadrós; "stout, thick") is a composite subatomic particle made of two or more quarks held together by the strong interaction. They are analogous to molecules that are held together by the ele ...
s). The two
up quark The up quark or u quark (symbol: u) is the lightest of all quarks, a type of elementary particle, and a significant constituent of matter. It, along with the down quark, forms the neutrons (one up quark, two down quarks) and protons (two up qua ...
s and one
down quark The down quark or d quark (symbol: d) is the second-lightest of all quarks, a type of elementary particle, and a major constituent of matter. Together with the up quark, it forms the neutrons (one up quark, two down quarks) and protons (two u ...
of a proton are held together by the
strong force The strong interaction or strong force is a fundamental interaction that confines quarks into proton, neutron, and other hadron particles. The strong interaction also binds neutrons and protons to create atomic nuclei, where it is called the ...
, mediated by
gluon A gluon ( ) is an elementary particle that acts as the exchange particle (or gauge boson) for the strong force between quarks. It is analogous to the exchange of photons in the electromagnetic force between two charged particles. Gluons bi ...
s. A modern perspective has a proton composed of the valence quarks (up, up, down), the gluons, and transitory pairs of
sea quark A quark () is a type of elementary particle and a fundamental constituent of matter. Quarks combine to form composite particles called hadrons, the most stable of which are protons and neutrons, the components of atomic nuclei. All commonly ...
s. Protons have a positive charge distribution which decays approximately exponentially, with a root mean square
charge radius The rms charge radius is a measure of the size of an atomic nucleus, particularly the proton distribution. It can be measured by the scattering of electrons by the nucleus. Relative changes in the mean squared nuclear charge distribution can be ...
of about 0.8 fm. Protons and
neutron The neutron is a subatomic particle, symbol or , which has a neutral (not positive or negative) charge, and a mass slightly greater than that of a proton. Protons and neutrons constitute the nuclei of atoms. Since protons and neutrons behav ...
s are both
nucleon In physics and chemistry, a nucleon is either a proton or a neutron, considered in its role as a component of an atomic nucleus. The number of nucleons in a nucleus defines the atom's mass number (nucleon number). Until the 1960s, nucleons w ...
s, which may be bound together by the
nuclear force The nuclear force (or nucleon–nucleon interaction, residual strong force, or, historically, strong nuclear force) is a force that acts between the protons and neutrons of atoms. Neutrons and protons, both nucleons, are affected by the nucl ...
to form
atomic nuclei The atomic nucleus is the small, dense region consisting of protons and neutrons at the center of an atom, discovered in 1911 by Ernest Rutherford based on the 1909 Geiger–Marsden gold foil experiment. After the discovery of the neutron in ...
. The nucleus of the most common
isotope Isotopes are two or more types of atoms that have the same atomic number (number of protons in their nuclei) and position in the periodic table (and hence belong to the same chemical element), and that differ in nucleon numbers ( mass number ...
of the
hydrogen atom A hydrogen atom is an atom of the chemical element hydrogen. The electrically neutral atom contains a single positively charged proton and a single negatively charged electron bound to the nucleus by the Coulomb force. Atomic hydrogen cons ...
(with the
chemical symbol Chemical symbols are the abbreviations used in chemistry for chemical elements, functional groups and chemical compounds. Element symbols for chemical elements normally consist of one or two letters from the Latin alphabet and are written with t ...
"H") is a lone proton. The nuclei of the heavy hydrogen isotopes
deuterium Deuterium (or hydrogen-2, symbol or deuterium, also known as heavy hydrogen) is one of two Stable isotope ratio, stable isotopes of hydrogen (the other being Hydrogen atom, protium, or hydrogen-1). The atomic nucleus, nucleus of a deuterium ato ...
and
tritium Tritium ( or , ) or hydrogen-3 (symbol T or H) is a rare and radioactive isotope of hydrogen with half-life about 12 years. The nucleus of tritium (t, sometimes called a ''triton'') contains one proton and two neutrons, whereas the nucleus ...
contain one proton bound to one and two neutrons, respectively. All other types of atomic nuclei are composed of two or more protons and various numbers of neutrons.


History

The concept of a hydrogen-like particle as a constituent of other atoms was developed over a long period. As early as 1815,
William Prout William Prout FRS (; 15 January 1785 – 9 April 1850) was an English chemist, physician, and natural theologian. He is remembered today mainly for what is called Prout's hypothesis. Biography Prout was born in Horton, Gloucestershire in 1 ...
proposed that all atoms are composed of hydrogen atoms (which he called "protyles"), based on a simplistic interpretation of early values of
atomic weight Relative atomic mass (symbol: ''A''; sometimes abbreviated RAM or r.a.m.), also known by the deprecated synonym atomic weight, is a dimensionless physical quantity defined as the ratio of the average mass of atoms of a chemical element in a give ...
s (see
Prout's hypothesis Prout's hypothesis was an early 19th-century attempt to explain the existence of the various chemical elements through a hypothesis regarding the internal structure of the atom. In 1815 and 1816, the English chemist William Prout published two p ...
), which was disproved when more accurate values were measured. In 1886,
Eugen Goldstein Eugen Goldstein (; 5 September 1850 – 25 December 1930) was a German physicist. He was an early investigator of discharge tubes, the discoverer of anode rays or canal rays, later identified as positive ions in the gas phase including the hy ...
discovered
canal rays An anode ray (also positive ray or canal ray) is a beam of positive ions that is created by certain types of gas-discharge tubes. They were first observed in Crookes tubes during experiments by the German scientist Eugen Goldstein, in 1886. Late ...
(also known as anode rays) and showed that they were positively charged particles (ions) produced from gases. However, since particles from different gases had different values of
charge-to-mass ratio The mass-to-charge ratio (''m''/''Q'') is a physical quantity relating the ''mass'' (quantity of matter) and the ''electric charge'' of a given particle, expressed in units of kilograms per coulomb (kg/C). It is most widely used in the electrod ...
(e/m), they could not be identified with a single particle, unlike the negative
electron The electron (, or in nuclear reactions) is a subatomic particle with a negative one elementary electric charge. Electrons belong to the first generation of the lepton particle family, and are generally thought to be elementary partic ...
s discovered by
J. J. Thomson Sir Joseph John Thomson (18 December 1856 – 30 August 1940) was a British physicist and Nobel Laureate in Physics, credited with the discovery of the electron, the first subatomic particle to be discovered. In 1897, Thomson showed that ...
.
Wilhelm Wien Wilhelm Carl Werner Otto Fritz Franz Wien (; 13 January 1864 – 30 August 1928) was a German physicist who, in 1893, used theories about heat and electromagnetism to deduce Wien's displacement law, which calculates the emission of a blackbody ...
in 1898 identified the hydrogen ion as the particle with the highest charge-to-mass ratio in ionized gases. Following the discovery of the atomic nucleus by
Ernest Rutherford Ernest Rutherford, 1st Baron Rutherford of Nelson, (30 August 1871 – 19 October 1937) was a New Zealand physicist who came to be known as the father of nuclear physics. ''Encyclopædia Britannica'' considers him to be the greatest ...
in 1911,
Antonius van den Broek Antonius Johannes van den Broek (4 May 1870, Zoetermeer – 25 October 1926, Bilthoven) was a Dutch amateur physicist notable for being the first who realized that the number of an element in the periodic table (now called atomic number) correspond ...
proposed that the place of each element in the
periodic table The periodic table, also known as the periodic table of the (chemical) elements, is a rows and columns arrangement of the chemical elements. It is widely used in chemistry, physics, and other sciences, and is generally seen as an icon of ...
(its atomic number) is equal to its nuclear charge. This was confirmed experimentally by
Henry Moseley Henry Gwyn Jeffreys Moseley (; 23 November 1887 – 10 August 1915) was an English physicist, whose contribution to the science of physics was the justification from physical laws of the previous empirical and chemical concept of the atomic num ...
in 1913 using
X-ray spectra X-ray spectroscopy is a general term for several spectroscopic techniques for characterization of materials by using x-ray radiation. Characteristic X-ray spectroscopy When an electron from the inner shell of an atom is excited by the energy o ...
. In 1917 (in experiments reported in 1919 and 1925), Rutherford proved that the hydrogen nucleus is present in other nuclei, a result usually described as the discovery of protons. These experiments began after Rutherford had noticed that, when
alpha particles Alpha particles, also called alpha rays or alpha radiation, consist of two protons and two neutrons bound together into a particle identical to a helium-4 nucleus. They are generally produced in the process of alpha decay, but may also be produce ...
were shot into air (mostly nitrogen), his scintillation detectors showed the signatures of typical hydrogen nuclei as a product. After experimentation Rutherford traced the reaction to the nitrogen in air and found that when alpha particles were introduced into pure nitrogen gas, the effect was larger. In 1919 Rutherford assumed that the alpha particle merely knocked a proton out of nitrogen, turning it into carbon. After observing Blackett's cloud chamber images in 1925, Rutherford realized that the alpha particle was absorbed. After capture of the alpha particle, a hydrogen nucleus is ejected, so that heavy oxygen, not carbon, is the result – i.e., the atomic number ''Z'' of the nucleus is increased rather than reduced. This was the first reported
nuclear reaction In nuclear physics and nuclear chemistry, a nuclear reaction is a process in which two nuclei, or a nucleus and an external subatomic particle, collide to produce one or more new nuclides. Thus, a nuclear reaction must cause a transformatio ...
, . Rutherford at first thought of our modern "p" in this equation as a hydrogen ion, . Depending on one's perspective, either 1919 (when it was seen experimentally as derived from another source than hydrogen) or 1920 (when it was recognized and proposed as an elementary particle) may be regarded as the moment when the proton was 'discovered'. Rutherford knew hydrogen to be the simplest and lightest element and was influenced by
Prout's hypothesis Prout's hypothesis was an early 19th-century attempt to explain the existence of the various chemical elements through a hypothesis regarding the internal structure of the atom. In 1815 and 1816, the English chemist William Prout published two p ...
that hydrogen was the building block of all elements. Discovery that the hydrogen nucleus is present in other nuclei as an elementary particle led Rutherford to give the hydrogen nucleus a special name as a particle, since he suspected that hydrogen, the lightest element, contained only one of these particles. He named this new fundamental building block of the nucleus the ''proton,'' after the neuter singular of the Greek word for "first", . However, Rutherford also had in mind the word ''protyle'' as used by Prout. Rutherford spoke at the
British Association for the Advancement of Science The British Science Association (BSA) is a charity and learned society founded in 1831 to aid in the promotion and development of science. Until 2009 it was known as the British Association for the Advancement of Science (BA). The current Ch ...
at its
Cardiff Cardiff (; cy, Caerdydd ) is the capital city, capital and List of urban areas in the United Kingdom, largest city of Wales. It forms a Principal areas of Wales, principal area, officially known as the City and County of Cardiff ( cy, Dinas a ...
meeting beginning 24 August 1920. At the meeting, he was asked by
Oliver Lodge Sir Oliver Joseph Lodge, (12 June 1851 – 22 August 1940) was a British physicist and writer involved in the development of, and holder of key patents for, radio. He identified electromagnetic radiation independent of Hertz's proof and at his ...
for a new name for the positive hydrogen nucleus to avoid confusion with the neutral hydrogen atom. He initially suggested both ''proton'' and ''prouton'' (after Prout). Rutherford later reported that the meeting had accepted his suggestion that the hydrogen nucleus be named the "proton", following Prout's word "protyle". The first use of the word "proton" in the scientific literature appeared in 1920.


Stability

The free proton (a proton not bound to nucleons or electrons) is a stable particle that has not been observed to break down spontaneously to other particles. Free protons are found naturally in a number of situations in which energies or temperatures are high enough to separate them from electrons, for which they have some affinity. Free protons exist in plasmas in which temperatures are too high to allow them to combine with
electron The electron (, or in nuclear reactions) is a subatomic particle with a negative one elementary electric charge. Electrons belong to the first generation of the lepton particle family, and are generally thought to be elementary partic ...
s. Free protons of high energy and velocity make up 90% of
cosmic ray Cosmic rays are high-energy particles or clusters of particles (primarily represented by protons or atomic nuclei) that move through space at nearly the speed of light. They originate from the Sun, from outside of the Solar System in our ow ...
s, which propagate in vacuum for interstellar distances. Free protons are emitted directly from
atomic nuclei The atomic nucleus is the small, dense region consisting of protons and neutrons at the center of an atom, discovered in 1911 by Ernest Rutherford based on the 1909 Geiger–Marsden gold foil experiment. After the discovery of the neutron in ...
in some rare types of
radioactive decay Radioactive decay (also known as nuclear decay, radioactivity, radioactive disintegration, or nuclear disintegration) is the process by which an unstable atomic nucleus loses energy by radiation. A material containing unstable nuclei is consid ...
. Protons also result (along with electrons and
antineutrino A neutrino ( ; denoted by the Greek letter ) is a fermion (an elementary particle with spin of ) that interacts only via the weak interaction and gravity. The neutrino is so named because it is electrically neutral and because its rest mass i ...
s) from the