Powellite is a
calcium
Calcium is a chemical element; it has symbol Ca and atomic number 20. As an alkaline earth metal, calcium is a reactive metal that forms a dark oxide-nitride layer when exposed to air. Its physical and chemical properties are most similar to it ...
molybdate
In chemistry, a molybdate is a compound containing an oxyanion with molybdenum in its highest oxidation state of +6: . Molybdenum can form a very large range of such oxyanions, which can be discrete structures or polymeric extended structures, ...
mineral with formula CaMoO
4. Powellite crystallizes with
tetragonal
In crystallography, the tetragonal crystal system is one of the 7 crystal systems. Tetragonal crystal lattices result from stretching a cubic lattice along one of its lattice vectors, so that the Cube (geometry), cube becomes a rectangular Pri ...
– dipyramidal
crystal structure
In crystallography, crystal structure is a description of ordered arrangement of atoms, ions, or molecules in a crystalline material. Ordered structures occur from intrinsic nature of constituent particles to form symmetric patterns that repeat ...
as transparent adamantine blue, greenish-brown, yellow-to-grey typically anhedral forms. It exhibits distinct
cleavage
Cleavage may refer to:
Science
* Cleavage (crystal), the way in which a crystal or mineral tends to split
* Cleavage (embryo), the division of cells in an early embryo
* Cleavage (geology), foliation of rock perpendicular to stress, a result of ...
, and has a brittle-to-conchoidal fracture. It has a
Mohs hardness
The Mohs scale ( ) of mineral hardness is a qualitative ordinal scale, from 1 to 10, characterizing scratch resistance of mineral
In geology and mineralogy, a mineral or mineral species is, broadly speaking, a solid substance with a fair ...
of 3.5 to 4 and a
specific gravity
Relative density, also called specific gravity, is a dimensionless quantity defined as the ratio of the density (mass of a unit volume) of a substance to the density of a given reference material. Specific gravity for solids and liquids is nea ...
of 4.25. It forms a
solid solution
A solid solution, a term popularly used for metals, is a homogeneous mixture of two compounds in solid state and having a single crystal structure. Many examples can be found in metallurgy, geology, and solid-state chemistry. The word "solutio ...
series with
scheelite
Scheelite is a calcium tungstate mineral with the chemical formula Ca W O4. It is an important ore of tungsten (wolfram). Scheelite is originally named after Swedish chemist Carl Wilhelm Scheele (1742–1786). Well-formed crystals are sought ...
(calcium tungstate, CaWO
4). It has
refractive index
In optics, the refractive index (or refraction index) of an optical medium is the ratio of the apparent speed of light in the air or vacuum to the speed in the medium. The refractive index determines how much the path of light is bent, or refrac ...
values of n
ω=1.974 and n
ε=1.984.
[
Powellite was first described by William Harlow Melville in 1891 for an occurrence in the Peacock Mine, ]Adams County, Idaho
Adams County is a rural county in the state of Idaho. As of the 2020 census, the county had a population of 4,379, making it the sixth-least populous county in Idaho. The county seat and largest city is Council. Established in 1911, the county ...
, and named for American explorer and geologist, John Wesley Powell
John Wesley Powell (March 24, 1834 – September 23, 1902) was an American geologist, U.S. Army soldier, explorer of the American West, professor at Illinois Wesleyan University, and director of major scientific and cultural institutions. He ...
(1834–1902).[
It occurs in ]hydrothermal
Hydrothermal circulation in its most general sense is the circulation of hot water (Ancient Greek ὕδωρ, ''water'',Liddell, H.G. & Scott, R. (1940). ''A Greek-English Lexicon. revised and augmented throughout by Sir Henry Stuart Jones. with th ...
ore
Ore is natural rock or sediment that contains one or more valuable minerals, typically including metals, concentrated above background levels, and that is economically viable to mine and process. The grade of ore refers to the concentration ...
deposits of molybdenum within the near-surface oxidized
Redox ( , , reduction–oxidation or oxidation–reduction) is a type of chemical reaction in which the oxidation states of the reactants change. Oxidation is the loss of electrons or an increase in the oxidation state, while reduction is ...
zones. It also appears as a rare mineral phase in pegmatite
A pegmatite is an igneous rock showing a very coarse texture, with large interlocking crystals usually greater in size than and sometimes greater than . Most pegmatites are composed of quartz, feldspar, and mica, having a similar silicic c ...
, tactite and basalt
Basalt (; ) is an aphanite, aphanitic (fine-grained) extrusive igneous rock formed from the rapid cooling of low-viscosity lava rich in magnesium and iron (mafic lava) exposed at or very near the planetary surface, surface of a terrestrial ...
. Minerals found in association with powellite include molybdenite
Molybdenite is a mineral of molybdenum disulfide, Mo S2. Similar in appearance and feel to graphite, molybdenite has a lubricating effect that is a consequence of its layered structure. The atomic structure consists of a sheet of molybdenum at ...
, ferrimolybdite, stilbite
Stilbite is the name of a series of tectosilicate minerals of the zeolite group. Prior to 1997, stilbite was recognized as a mineral species, but a reclassification in 1997 by the International Mineralogical Association changed it to a series nam ...
, laumontite and apophyllite
The name apophyllite refers to a specific group of phyllosilicates, a class of minerals. Originally, the group name referred to a specific mineral, but was redefined in 1978 to stand for a class of minerals of similar chemical makeup that compris ...
.[
]
References
* Palache, C., H. Berman, and C. Frondel (1951) ''Dana’s System of Mineralogy'', (7th edition), v. II, pp. 1079–1081.
External links
Calcium minerals
Molybdate minerals
Tetragonal minerals
Minerals in space group 88
Luminescent minerals
{{mineral-stub