Potassium chlorite is a

potassium Potassium is a chemical element; it has Symbol (chemistry), symbol K (from Neo-Latin ) and atomic number19. It is a silvery white metal that is soft enough to easily cut with a knife. Potassium metal reacts rapidly with atmospheric oxygen to ...

salt of

chlorous acid Chlorous acid is an inorganic compound with the formula HClO2. It is a weak acid. Chlorine has oxidation state +3 in this acid. The pure substance is unstable, disproportionating to hypochlorous acid (Cl oxidation state +1) and chloric acid (Cl ...

(HClO₂) having a chemical formula KClO₂. It exists as white powder and its anhydrous form easily undergoes decomposition in presence of heat or radiation (especially

gamma rays A gamma ray, also known as gamma radiation (symbol ), is a penetrating form of electromagnetic radiation arising from high energy interactions like the radioactive decay of atomic nuclei or astronomical events like solar flares. It consists o ...

Properties

Potassium chlorite is a colorless hygroscopic crystal that deliquesces in the air. It decomposes upon heating into

potassium chloride Potassium chloride (KCl, or potassium salt) is a metal halide salt composed of potassium and chlorine. It is odorless and has a white or colorless vitreous crystal appearance. The solid dissolves readily in water, and its solutions have a sa ...

and

oxygen Oxygen is a chemical element; it has chemical symbol, symbol O and atomic number 8. It is a member of the chalcogen group (periodic table), group in the periodic table, a highly reactivity (chemistry), reactive nonmetal (chemistry), non ...

, emitting light. : Potassium chlorite forms orthorhombic cmcm crystals and has been reported to decompose within hours at room temperature. It is an oxidizing agent.

Synthesis

Some of the methods of preparation of potassium chlorite are: *Thermal decomposition of

potassium chlorate Potassium chlorate is the inorganic compound with the molecular formula KClO3. In its pure form, it is a white solid. After sodium chlorate, it is the second most common chlorate in industrial use. It is a strong oxidizing agent and its most impor ...

: *Reaction of

chloric acid Chloric acid, H Cl O3, is an oxoacid of chlorine, and the formal precursor of chlorate salts. It is a strong acid ( p''K''a ≈ −2.7) and an oxidizing agent. Properties Chloric acid is thermodynamically unstable with respect to disproportio ...

and

potassium hydroxide Potassium hydroxide is an inorganic compound with the formula K OH, and is commonly called caustic potash. Along with sodium hydroxide (NaOH), KOH is a prototypical strong base. It has many industrial and niche applications, most of which utili ...

References

Potassium compounds Chlorites {{chem-compound-stub