Porco caldera is a

caldera A caldera ( ) is a large cauldron-like hollow that forms shortly after the emptying of a magma chamber in a volcanic eruption. An eruption that ejects large volumes of magma over a short period of time can cause significant detriment to the str ...

Bolivia Bolivia, officially the Plurinational State of Bolivia, is a landlocked country located in central South America. The country features diverse geography, including vast Amazonian plains, tropical lowlands, mountains, the Gran Chaco Province, w ...

which contains a major deposit of

lead Lead () is a chemical element; it has Chemical symbol, symbol Pb (from Latin ) and atomic number 82. It is a Heavy metal (elements), heavy metal that is density, denser than most common materials. Lead is Mohs scale, soft and Ductility, malleabl ...

silver Silver is a chemical element; it has Symbol (chemistry), symbol Ag () and atomic number 47. A soft, whitish-gray, lustrous transition metal, it exhibits the highest electrical conductivity, thermal conductivity, and reflectivity of any metal. ...

tin Tin is a chemical element; it has symbol Sn () and atomic number 50. A silvery-colored metal, tin is soft enough to be cut with little force, and a bar of tin can be bent by hand with little effort. When bent, a bar of tin makes a sound, the ...

, and

zinc Zinc is a chemical element; it has symbol Zn and atomic number 30. It is a slightly brittle metal at room temperature and has a shiny-greyish appearance when oxidation is removed. It is the first element in group 12 (IIB) of the periodic tabl ...

ore Ore is natural rock or sediment that contains one or more valuable minerals, typically including metals, concentrated above background levels, and that is economically viable to mine and process. The grade of ore refers to the concentration ...

. This caldera was formed by a volcanic eruption 12 million years ago in the Bolivian Cordillera Oriental. Subsequent to the caldera collapse, volcanic intrusions occurred as many as 3 million years after the caldera formation. Ore deposits form veins within the caldera infill. These ores were mined for silver as early as the Inca period; more recently, Porco is the site of zinc mining.

Geography and geomorphology

Porco lies in southwestern Bolivia in the Cordillera Oriental, close to the towns of Agua de Castilla and Porco. The jagged, wind-swept landscape lies at an elevation of . Porco consists of a

with a diameter of . The caldera formed along a

ring fault In geology, a fault is a planar fracture or discontinuity in a volume of rock across which there has been significant displacement as a result of rock-mass movements. Large faults within Earth's crust result from the action of plate tectonic f ...

and was enlarged by subsequent

landslide Landslides, also known as landslips, rockslips or rockslides, are several forms of mass wasting that may include a wide range of ground movements, such as rockfalls, mudflows, shallow or deep-seated slope failures and debris flows. Landslides ...

s of its oversteepened margins into a bowl-shaped depression. The rims of the caldera are particularly conspicuous on its northern side and form a recognizable scarp on the northeastern side. The caldera contains two hills in its southern part, high Cerro Apo Porco and high Huayna Porco. Both of these hills are intrusive

stocks Stocks are feet and hand restraining devices that were used as a form of corporal punishment and public humiliation. The use of stocks is seen as early as Ancient Greece, where they are described as being in use in Solon's law code. The law de ...

; other smaller intrusions are found elsewhere in the caldera and some may be exposed feeder

dikes Dyke or dike may refer to: General uses * Dyke (slang), a slang word meaning "lesbian" * Dike (geology), formations of magma or sediment that cut through and across the layering of adjacent rocks * Dike (mythology), ''Dikē'', the Greek goddess ...

of now eroded

lava dome In volcanology, a lava dome is a circular, mound-shaped protrusion resulting from the slow extrusion of viscous lava from a volcano. Dome-building eruptions are common, particularly in convergent plate boundary settings. Around 6% of eruptions ...

s. The

basement A basement is any Storey, floor of a building that is not above the grade plane. Especially in residential buildings, it often is used as a utility space for a building, where such items as the Furnace (house heating), furnace, water heating, ...

of the caldera is formed by

phyllite Phyllite ( ) is a type of foliation (geology), foliated metamorphic rock formed from slate that is further metamorphosed so that very fine grained white mica achieves a preferred orientation.Stephen Marshak ''Essentials of Geology'', 3rd ed. I ...

rocks of

Ordovician The Ordovician ( ) is a geologic period and System (geology), system, the second of six periods of the Paleozoic Era (geology), Era, and the second of twelve periods of the Phanerozoic Eon (geology), Eon. The Ordovician spans 41.6 million years f ...

age, which in turn are overlaid by the

Cretaceous The Cretaceous ( ) is a geological period that lasted from about 143.1 to 66 mya (unit), million years ago (Mya). It is the third and final period of the Mesozoic Era (geology), Era, as well as the longest. At around 77.1 million years, it is the ...

Toro Toro

formation Formation may refer to: Linguistics * Back-formation, the process of creating a new lexeme by removing or affixes * Word formation, the creation of a new word by adding affixes Mathematics and science * Cave formation or speleothem, a secondary ...

, which consists of

sandstone Sandstone is a Clastic rock#Sedimentary clastic rocks, clastic sedimentary rock composed mainly of grain size, sand-sized (0.0625 to 2 mm) silicate mineral, silicate grains, Cementation (geology), cemented together by another mineral. Sand ...

. Porco is found at the southern margin of the Los Frailes volcanic field, a large

ignimbrite Ignimbrite is a type of volcanic rock, consisting of hardened tuff. Ignimbrites form from the deposits of pyroclastic flows, which are a hot suspension of particles and gases flowing rapidly from a volcano, driven by being denser than the surrou ...

field that extends from Potosi in the east as much as to the

Altiplano The Altiplano (Spanish language, Spanish for "high plain"), Collao (Quechuan languages, Quechua and Aymara language, Aymara: Qullaw, meaning "place of the Qulla people, Qulla") or Andean Plateau, in west-central South America, is the most extens ...

in the west. This ignimbrite field was erupted between 6–9 million years ago from a number of vents and consists of

dacite Dacite () is a volcanic rock formed by rapid solidification of lava that is high in silica and low in alkali metal oxides. It has a fine-grained (aphanitic) to porphyritic texture and is intermediate in composition between andesite and rhyolite. ...

and

rhyolite Rhyolite ( ) is the most silica-rich of volcanic rocks. It is generally glassy or fine-grained (aphanitic) in texture (geology), texture, but may be porphyritic, containing larger mineral crystals (phenocrysts) in an otherwise fine-grained matri ...

ash-flow

tuff Tuff is a type of rock made of volcanic ash ejected from a vent during a volcanic eruption. Following ejection and deposition, the ash is lithified into a solid rock. Rock that contains greater than 75% ash is considered tuff, while rock co ...

s. Porco was at first considered to be part of the Los Frailes field, but in 1964 it was found to be a distinct volcanic system. The Porco tuff is of

dacitic Dacite () is a volcanic rock formed by rapid solidification of lava that is high in silica and low in alkali metal oxides. It has a fine-grained (aphanitic) to porphyritic texture and is intermediate in composition between andesite and rhyolite. ...

composition. It contains abundant crystals and

phenocryst image:montblanc granite phenocrysts.JPG, 300px, Granites often have large feldspar, feldspathic phenocrysts. This granite, from the Switzerland, Swiss side of the Mont Blanc massif, has large white phenocrysts of plagioclase (that have trapezoid sh ...

s of

biotite Biotite is a common group of phyllosilicate minerals within the mica group, with the approximate chemical formula . It is primarily a solid-solution series between the iron- endmember annite, and the magnesium-endmember phlogopite; more al ...

plagioclase Plagioclase ( ) is a series of Silicate minerals#Tectosilicates, tectosilicate (framework silicate) minerals within the feldspar group. Rather than referring to a particular mineral with a specific chemical composition, plagioclase is a continu ...

quartz Quartz is a hard, crystalline mineral composed of silica (silicon dioxide). The Atom, atoms are linked in a continuous framework of SiO4 silicon–oxygen Tetrahedral molecular geometry, tetrahedra, with each oxygen being shared between two tet ...

, and

sanidine Sanidine is the high temperature form of potassium feldspar with a general formula K(AlSi3O8). Sanidine is found most typically in felsic volcanic rocks such as obsidian, rhyolite and trachyte. Sanidine crystallizes in the monoclinic crystal sys ...

. Close to the Apo Porco and Huayna Porco hills, the tuff has been altered to varying degrees, forming propylite and

sericite Sericite is the name given to very fine, ragged grains and Aggregate (geology), aggregates of white (colourless) micas, typically made of muscovite, illite, or paragonite. Sericite is produced by the alteration of orthoclase or plagioclase feldsp ...

. A number of individual veins of ore rock cross-cut the Porco tuff and have names such as Cerro Milagro vein system, Larga vein, Panfilo vein, and San Antonio vein. Ore minerals include

acanthite Acanthite is a form of silver sulfide with the chemical formula Ag2S. It crystallizes in the monoclinic system and is the stable form of silver sulfide below . Argentite is the stable form above that temperature. As argentite cools below that temp ...

arsenopyrite Arsenopyrite ( IMA symbol: Apy) is an iron arsenic sulfide (FeAsS). It is a hard ( Mohs 5.5–6) metallic, opaque, steel grey to silver white mineral with a relatively high specific gravity of 6.1. When dissolved in nitric acid, it releases el ...

cassiterite Cassiterite is a tin oxide mineral, SnO2. It is generally opaque, but it is translucent in thin crystals. Its luster and multiple crystal faces produce a desirable gem. Cassiterite was the chief tin ore throughout ancient history and remains ...

cerussite Cerussite (also known as lead carbonate or white lead ore) is a mineral consisting of lead carbonate with the chemical formula PbCO3, and is an important ore of lead. The name is from the Latin ''cerussa'', white lead. ''Cerussa nativa'' was ...

galena Galena, also called lead glance, is the natural mineral form of lead(II) sulfide (PbS). It is the most important ore of lead and an important source of silver. Galena is one of the most abundant and widely distributed sulfide minerals. It crysta ...

limonite Limonite () is an iron ore consisting of a mixture of hydrated iron(III) oxide-hydroxides in varying composition. The generic formula is frequently written as , although this is not entirely accurate as the ratio of oxide to hydroxide can vary qu ...

, pyragyrite,

pyrite The mineral pyrite ( ), or iron pyrite, also known as fool's gold, is an iron sulfide with the chemical formula Fe S2 (iron (II) disulfide). Pyrite is the most abundant sulfide mineral. Pyrite's metallic luster and pale brass-yellow hue ...

semseyite Semseyite is a rarely occurring sulfosalt mineral and is part of the class of lead antimony sulfides. It crystallizes in the monoclinic system with the chemical composition Pb9Sb8S21. The mineral forms dark gray to black aggregates. Etymology ...

sphalerite Sphalerite is a sulfide mineral with the chemical formula . It is the most important ore of zinc. Sphalerite is found in a variety of deposit types, but it is primarily in Sedimentary exhalative deposits, sedimentary exhalative, Carbonate-hoste ...

stannite Stannite is a mineral, a sulfide of copper, iron, and tin, in the category of thiostannates. Background The chemical formula is Cu2 Fe Sn S4. Zinc commonly occurs with the iron and trace germanium may be present. Stannite is used as an ore of t ...

, and

stephanite Stephanite is a silver antimony sulfosalt mineral with formula: Ag5 Sb S4. It is composed of 68.8% silver, and sometimes is of importance as an ore of this metal. History Under the name Schwarzerz it was mentioned by Georgius Agricola in 1546, a ...

. The climate is cold and dry, with temperatures below occurring in ten months. Precipitation is low, amounting to about .

Eruption history

Twelve million years ago, the Porco Tuff was erupted from the volcano, causing the formation of the Porco caldera. This welded tuff accumulated to thicknesses of more than inside the caldera and extended outside of the caldera, where it crops out in patches outside of its western margin. Material from the pre-caldera basement consisting of Cretaceous sandstone

breccia Breccia ( , ; ) is a rock composed of large angular broken fragments of minerals or Rock (geology), rocks cementation (geology), cemented together by a fine-grained matrix (geology), matrix. The word has its origins in the Italian language ...

was embedded in the tuff on the southern and eastern side of the caldera. Porco is also considered to be the source of the Cebadillas ignimbrite. The Huayna Porco hill formed about the same time as the caldera, 12.1 ± 0.4 million years ago, while Apo Porco is more recent, of 8.6 ± 0.3 million years. The formation of these hills coincided with

hydrothermal Hydrothermal circulation in its most general sense is the circulation of hot water (Ancient Greek ὕδωρ, ''water'',Liddell, H.G. & Scott, R. (1940). ''A Greek-English Lexicon. revised and augmented throughout by Sir Henry Stuart Jones. with th ...

alteration of the Porco tuff contained in the caldera; the 3 million year gap between the Porco tuff and the Apo Porco intrusion suggests that the intrusion was a distinct magmatic event, probably part of the Los Frailes volcanism.

Mining

Silver Silver is a chemical element; it has Symbol (chemistry), symbol Ag () and atomic number 47. A soft, whitish-gray, lustrous transition metal, it exhibits the highest electrical conductivity, thermal conductivity, and reflectivity of any metal. ...

mining at Porco occurred already during

pre-Columbian In the history of the Americas, the pre-Columbian era, also known as the pre-contact era, or as the pre-Cabraline era specifically in Brazil, spans from the initial peopling of the Americas in the Upper Paleolithic to the onset of European col ...

times. For example, the silver in the

Coricancha Coricancha, Curicancha, Koricancha, Qoricancha or Qorikancha (''"The Golden Temple,"'' from Quechua ''quri'' gold; ''kancha'' enclosure) was the most important temple in the Inca Empire, and was described by early Spanish colonialists. It is l ...

temple of

Cuzco Cusco or Cuzco (; or , ) is a city in southeastern Peru, near the Sacred Valley of the Andes mountain range and the Huatanay river. It is the capital of the eponymous province and department. The city was the capital of the Inca Empire unti ...

originated at Porco. In fact, Porco was the major silver source for the

Inca The Inca Empire, officially known as the Realm of the Four Parts (, ), was the largest empire in pre-Columbian America. The administrative, political, and military center of the empire was in the city of Cusco. The History of the Incas, Inca ...

, and consequently their government heavily intervened in the region. Even after the Inca, Porco was a major source of silver for the Spanish. Later additional ores of

, and

were mined at Porco as well, and the mine became Bolivia's largest source of zinc. , of ore reserves existed at Porco, this ore containing 1.5% lead, silver, and 15% zinc.

Gold Gold is a chemical element; it has chemical symbol Au (from Latin ) and atomic number 79. In its pure form, it is a brightness, bright, slightly orange-yellow, dense, soft, malleable, and ductile metal. Chemically, gold is a transition metal ...

also occurs at Porco, but not in quantities that would justify mining it.

References

Sources

* *

External links

* * {{Commons category-inline, Porco (caldera) Calderas of Bolivia Mining in Bolivia Miocene calderas