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Polymer solutions are solutions containing dissolved polymers. These may be (e.g. in ), or solid solutions (e.g. a substance which has been plasticized). The introduction into the polymer of small amounts of a solvent ( plasticizer) reduces the temperature of
glass transition The glass–liquid transition, or glass transition, is the gradual and reversible transition in amorphous materials (or in amorphous regions within semicrystalline materials) from a hard and relatively brittle "glassy" state into a viscous or rubb ...
, the
yield temperature Yield may refer to: Measures of output/function Computer science * Yield (multithreading) is an action that occurs in a computer program during multithreading * See generator (computer programming) Physics/chemistry * Yield (chemistry), the a ...
, and the viscosity of a
melt Melt may refer to: Science and technology * Melting, in physics, the process of heating a solid substance to a liquid * Melt (manufacturing), the semi-liquid material used in steelmaking and glassblowing * Melt (geology), magma ** Melt inclusions, ...
. An understanding of the thermodynamics of a polymer solution is critical to prediction of its behavior in manufacturing processes — for example, its shrinkage or expansion in
injection molding Injection moulding (U.S. spelling: injection molding) is a manufacturing process for producing parts by injecting molten material into a mould, or mold. Injection moulding can be performed with a host of materials mainly including metals (for ...
processes, or whether pigments and
solvents A solvent (s) (from the Latin '' solvō'', "loosen, untie, solve") is a substance that dissolves a solute, resulting in a solution. A solvent is usually a liquid but can also be a solid, a gas, or a supercritical fluid. Water is a solvent for p ...
will mix evenly with a polymer in the manufacture of paints and coatings. A recent theory on the viscosity of polymer solutions gives a physical explanation for various well-known empirical relations and numerical values including the Huggins constant, but reveals also novel simple concentration and molar mass dependence.


Applications

Polymer solutions are used in producing
fibers Fiber or fibre (from la, fibra, links=no) is a natural or artificial substance that is significantly longer than it is wide. Fibers are often used in the manufacture of other materials. The strongest engineering materials often incorporate ...
,
films A film also called a movie, motion picture, moving picture, picture, photoplay or (slang) flick is a work of visual art that simulates experiences and otherwise communicates ideas, stories, perceptions, feelings, beauty, or atmosphere ...
,
glue Adhesive, also known as glue, cement, mucilage, or paste, is any non-metallic substance applied to one or both surfaces of two separate items that binds them together and resists their separation. The use of adhesives offers certain advant ...
s,
lacquer Lacquer is a type of hard and usually shiny coating or finish applied to materials such as wood or metal. It is most often made from resin extracted from trees and waxes and has been in use since antiquity. Asian lacquerware, which may be ca ...
s,
paint Paint is any pigmented liquid, liquefiable, or solid mastic composition that, after application to a substrate in a thin layer, converts to a solid film. It is most commonly used to protect, color, or provide texture. Paint can be made in many ...
s, and other items made of
polymer material A polymer (; Greek '' poly-'', "many" + ''-mer'', "part") is a substance or material consisting of very large molecules called macromolecules, composed of many repeating subunits. Due to their broad spectrum of properties, both synthetic an ...
s. Thin layers of polymer solution can be used to produce light-emitting devices. Guar polymer solution gels can be used in
hydraulic fracturing Fracking (also known as hydraulic fracturing, hydrofracturing, or hydrofracking) is a well stimulation technique involving the fracturing of bedrock formations by a pressurized liquid. The process involves the high-pressure injection of "frack ...
("fracking").


See also

* Flory–Huggins solution theory *
Colloid A colloid is a mixture in which one substance consisting of microscopically dispersed insoluble particles is suspended throughout another substance. Some definitions specify that the particles must be dispersed in a liquid, while others extend ...
systems * Gel * Solution polymerization


References


Further reading

* Polymer chemistry * {{Polymer-stub