Plutonium(III) fluoride or plutonium trifluoride is the

chemical compound A chemical compound is a chemical substance composed of many identical molecules (or molecular entities) containing atoms from more than one chemical element held together by chemical bonds. A molecule consisting of atoms of only one element ...

composed of

plutonium Plutonium is a chemical element; it has symbol Pu and atomic number 94. It is a silvery-gray actinide metal that tarnishes when exposed to air, and forms a dull coating when oxidized. The element normally exhibits six allotropes and four ...

and

fluorine Fluorine is a chemical element; it has Chemical symbol, symbol F and atomic number 9. It is the lightest halogen and exists at Standard temperature and pressure, standard conditions as pale yellow Diatomic molecule, diatomic gas. Fluorine is extre ...

with the

formula In science, a formula is a concise way of expressing information symbolically, as in a mathematical formula or a ''chemical formula''. The informal use of the term ''formula'' in science refers to the general construct of a relationship betwe ...

PuF₃. This salt forms violet crystals. Plutonium(III) fluoride has the LaF₃ structure where the coordination around the plutonium atoms is complex and usually described as tri-capped

trigonal In crystallography, the hexagonal crystal family is one of the six crystal family, crystal families, which includes two crystal systems (hexagonal and trigonal) and two lattice systems (hexagonal and rhombohedral). While commonly confused, the tr ...

prismatic.Wells A.F. (1984) ''Structural Inorganic Chemistry'' 5th edition Oxford Science Publications .

Reactions

A plutonium(III) fluoride

precipitation In meteorology, precipitation is any product of the condensation of atmospheric water vapor that falls from clouds due to gravitational pull. The main forms of precipitation include drizzle, rain, rain and snow mixed ("sleet" in Commonwe ...

method has been investigated as an alternative to the typical plutonium peroxide method of recovering plutonium from solution, such as that from a

nuclear reprocessing Nuclear reprocessing is the chemical separation of fission products and actinides from spent nuclear fuel. Originally, reprocessing was used solely to extract plutonium for producing nuclear weapons. With commercialization of nuclear power, the ...

plant. A 1957 study by the

Los Alamos National Laboratory Los Alamos National Laboratory (often shortened as Los Alamos and LANL) is one of the sixteen research and development Laboratory, laboratories of the United States Department of Energy National Laboratories, United States Department of Energy ...

reported a less effective recovery than the traditional method, while a more recent study sponsored by the

United States The United States of America (USA), also known as the United States (U.S.) or America, is a country primarily located in North America. It is a federal republic of 50 U.S. state, states and a federal capital district, Washington, D.C. The 48 ...

Office of Scientific and Technical Information The Office of Scientific and Technical Information (OSTI) is a component of the Office of Science within the U.S. Department of Energy (DOE). The '' Energy Policy Act'' PL 109–58, Section 982, called out the responsibility of OSTI: "The Secre ...

found it to be one of the more effective methods. Plutonium(III) fluoride can be used for manufacture of the plutonium-gallium alloy instead of more difficult to handle metallic plutonium.

References

{{Actinide halides Plutonium(III) compounds Fluorides Actinide halides