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The Planck relationFrench & Taylor (1978), pp. 24, 55.Cohen-Tannoudji, Diu & Laloë (1973/1977), pp. 10–11. (referred to as Planck's energy–frequency relation,Schwinger (2001), p. 203. the Planck–Einstein relation, Planck equation, and Planck formula, though the latter might also refer to Planck's law) is a fundamental equation in
quantum mechanics Quantum mechanics is the fundamental physical Scientific theory, theory that describes the behavior of matter and of light; its unusual characteristics typically occur at and below the scale of atoms. Reprinted, Addison-Wesley, 1989, It is ...
which states that the
energy Energy () is the physical quantity, quantitative physical property, property that is transferred to a physical body, body or to a physical system, recognizable in the performance of Work (thermodynamics), work and in the form of heat and l ...
of a
photon A photon () is an elementary particle that is a quantum of the electromagnetic field, including electromagnetic radiation such as light and radio waves, and the force carrier for the electromagnetic force. Photons are massless particles that can ...
, known as photon energy, is proportional to its
frequency Frequency is the number of occurrences of a repeating event per unit of time. Frequency is an important parameter used in science and engineering to specify the rate of oscillatory and vibratory phenomena, such as mechanical vibrations, audio ...
: E = h \nu. The constant of proportionality, , is known as the
Planck constant The Planck constant, or Planck's constant, denoted by h, is a fundamental physical constant of foundational importance in quantum mechanics: a photon's energy is equal to its frequency multiplied by the Planck constant, and the wavelength of a ...
. Several equivalent forms of the relation exist, including in terms of
angular frequency In physics, angular frequency (symbol ''ω''), also called angular speed and angular rate, is a scalar measure of the angle rate (the angle per unit time) or the temporal rate of change of the phase argument of a sinusoidal waveform or sine ...
: E = \hbar \omega, where \hbar = h / 2 \pi. Written using the symbol for frequency, the relation is E = h f. The relation accounts for the quantized nature of light and plays a key role in understanding phenomena such as the photoelectric effect and black-body radiation (where the related Planck postulate can be used to derive Planck's law).


Spectral forms

Light can be characterized using several spectral quantities, such as
frequency Frequency is the number of occurrences of a repeating event per unit of time. Frequency is an important parameter used in science and engineering to specify the rate of oscillatory and vibratory phenomena, such as mechanical vibrations, audio ...
,
wavelength In physics and mathematics, wavelength or spatial period of a wave or periodic function is the distance over which the wave's shape repeats. In other words, it is the distance between consecutive corresponding points of the same ''phase (waves ...
,
wavenumber In the physical sciences, the wavenumber (or wave number), also known as repetency, is the spatial frequency of a wave. Ordinary wavenumber is defined as the number of wave cycles divided by length; it is a physical quantity with dimension of ...
\tilde, and their angular equivalents (
angular frequency In physics, angular frequency (symbol ''ω''), also called angular speed and angular rate, is a scalar measure of the angle rate (the angle per unit time) or the temporal rate of change of the phase argument of a sinusoidal waveform or sine ...
, angular wavelength , and angular wavenumber ). These quantities are related through \nu = \frac = c \tilde \nu = \frac = \frac = \frac, so the Planck relation can take the following "standard" forms: E = h \nu = \frac = h c \tilde \nu, as well as the following "angular" forms: E = \hbar \omega = \frac = \hbar c k. The standard forms make use of the
Planck constant The Planck constant, or Planck's constant, denoted by h, is a fundamental physical constant of foundational importance in quantum mechanics: a photon's energy is equal to its frequency multiplied by the Planck constant, and the wavelength of a ...
. The angular forms make use of the
reduced Planck constant The Planck constant, or Planck's constant, denoted by h, is a fundamental physical constant of foundational importance in quantum mechanics: a photon's energy is equal to its frequency multiplied by the Planck constant, and the wavelength of a ...
. Here is the
speed of light The speed of light in vacuum, commonly denoted , is a universal physical constant exactly equal to ). It is exact because, by international agreement, a metre is defined as the length of the path travelled by light in vacuum during a time i ...
.


de Broglie relation

The de Broglie relation,Weinberg (1995), p. 3. also known as de Broglie's momentum–wavelength relation, generalizes the Planck relation to matter waves. Louis de Broglie argued that if particles had a wave nature, the relation would also apply to them, and postulated that particles would have a wavelength equal to . Combining de Broglie's postulate with the Planck–Einstein relation leads to p = h \tilde \nu or p = \hbar k. The de Broglie relation is also often encountered in vector form \mathbf = \hbar \mathbf, where is the momentum vector, and is the angular wave vector.


Bohr's frequency condition

Bohr's frequency condition states that the frequency of a photon absorbed or emitted during an electronic transition is related to the energy difference () between the two
energy level A quantum mechanics, quantum mechanical system or particle that is bound state, bound—that is, confined spatially—can only take on certain discrete values of energy, called energy levels. This contrasts with classical mechanics, classical pa ...
s involved in the transition:van der Waerden (1967), p. 5. \Delta E = h \nu. This is a direct consequence of the Planck–Einstein relation.


See also

* Compton wavelength


References


Cited bibliography

* Cohen-Tannoudji, C., Diu, B., Laloë, F. (1973/1977). ''Quantum Mechanics'', translated from the French by S.R. Hemley, N. Ostrowsky, D. Ostrowsky, second edition, volume 1, Wiley, New York, . * French, A.P., Taylor, E.F. (1978). ''An Introduction to Quantum Physics'', Van Nostrand Reinhold, London, . *Griffiths, D.J. (1995). ''Introduction to Quantum Mechanics'', Prentice Hall, Upper Saddle River NJ, . * Landé, A. (1951). ''Quantum Mechanics'', Sir Isaac Pitman & Sons, London. *Landsberg, P.T. (1978). ''Thermodynamics and Statistical Mechanics'', Oxford University Press, Oxford UK, . * Messiah, A. (1958/1961)
''Quantum Mechanics''
volume 1, translated from the French by G.M. Temmer, North-Holland, Amsterdam. * Schwinger, J. (2001). ''Quantum Mechanics: Symbolism of Atomic Measurements'', edited by B.-G. Englert, Springer, Berlin, . * van der Waerden, B.L. (1967). ''Sources of Quantum Mechanics'', edited with a historical introduction by B.L. van der Waerden, North-Holland Publishing, Amsterdam. * Weinberg, S. (1995). ''The Quantum Theory of Fields'', volume 1, ''Foundations'', Cambridge University Press, Cambridge UK, . * Weinberg, S. (2013). ''Lectures on Quantum Mechanics'', Cambridge University Press, Cambridge UK, . {{DEFAULTSORT:Planck-Einstein relation Foundational quantum physics Max Planck Old quantum theory