Pine Oil
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Pine oil is an
essential oil An essential oil is a concentrated hydrophobic liquid containing volatile (easily evaporated at normal temperatures) chemical compounds from plants. Essential oils are also known as volatile oils, ethereal oils, aetheroleum, or simply as the ...
obtained from a variety of species of
pine A pine is any conifer tree or shrub in the genus ''Pinus'' () of the family Pinaceae. ''Pinus'' is the sole genus in the subfamily Pinoideae. ''World Flora Online'' accepts 134 species-rank taxa (119 species and 15 nothospecies) of pines as cu ...
, particularly ''
Pinus sylvestris ''Pinus sylvestris'', the Scots pine (UK), Scotch pine (US), Baltic pine, or European red pine is a species of tree in the pine family Pinaceae that is native plant, native to Eurasia. It can readily be identified by its combination of fairly s ...
''. Typically, parts of the trees that are not used for lumber stumps, etc. are ground and subjected to steam distillation. As of 1995, synthetic pine oil was the "biggest single
turpentine Turpentine (which is also called spirit of turpentine, oil of turpentine, terebenthine, terebenthene, terebinthine and, colloquially, turps) is a fluid obtainable by the distillation of resin harvested from living trees, mainly pines. Principall ...
derivative." Synthetic pine oils accounted for 90% of sales as of 2000.


Composition

Pine oil is a higher boiling fraction from
turpentine Turpentine (which is also called spirit of turpentine, oil of turpentine, terebenthine, terebenthene, terebinthine and, colloquially, turps) is a fluid obtainable by the distillation of resin harvested from living trees, mainly pines. Principall ...
. Both synthetic and natural pine oil consists mainly of
α-terpineol Terpineol is any of four isomeric monoterpene, monoterpenoids. Terpenoids are terpene that are modified by the addition of a functional group, in this case, an Alcohol (chemistry), alcohol. Terpineols have been isolated from a variety of sources ...
, a C10 alcohol (b.p. 214–217 °C).''Merck Index'', 11th Edition, 7416. p. 1182 Other components include
dipentene Limonene () is a colorless liquid aliphatic hydrocarbon classified as a cyclic monoterpene, and is the major component in the essential oil of citrus fruit peels. The (+)-isomer, occurring more commonly in nature as the fragrance of oranges, ...
and
pinene Pinene is a collection of unsaturated bicyclic monoterpenes. Two geometric isomers of pinene are found in nature, α-pinene and β-pinene. Both are chiral. As the name suggests, pinenes are found in pines. Specifically, pinene is the major comp ...
. The detailed composition of natural pine oil depends on many factors, such as the species of the host plant. Synthetic pine oil is obtained by treating
pinene Pinene is a collection of unsaturated bicyclic monoterpenes. Two geometric isomers of pinene are found in nature, α-pinene and β-pinene. Both are chiral. As the name suggests, pinenes are found in pines. Specifically, pinene is the major comp ...
with water in the presence of a catalytic amount of
sulfuric acid Sulfuric acid (American spelling and the preferred IUPAC name) or sulphuric acid (English in the Commonwealth of Nations, Commonwealth spelling), known in antiquity as oil of vitriol, is a mineral acid composed of the elements sulfur, oxygen, ...
. This treatment results in hydration of the alkene and rearrangement of the pinene skeleton, yielding terpineols.


Uses

Industrially, pine oil was once used in froth flotation for the separation of mineral from ores. For example, in
copper extraction Copper extraction is the multi-stage process of obtaining copper from list of copper ores, its ores. The conversion of copper ores consists of a series of physical, chemical, and electrochemical processes. Methods have evolved and vary with coun ...
, pine oil is used to condition copper sulfide ores for froth flotation. It is also used as a
lubricant A lubricant (sometimes shortened to lube) is a substance that helps to reduce friction between surfaces in mutual contact, which ultimately reduces the heat generated when the surfaces move. It may also have the function of transmitting forces, ...
in small and expensive
clockwork Clockwork refers to the inner workings of either mechanical devices called clocks and watches (where it is also called the movement (clockwork), movement) or other mechanisms that work similarly, using a series of gears driven by a spring or wei ...
instruments. In
alternative medicine Alternative medicine refers to practices that aim to achieve the healing effects of conventional medicine, but that typically lack biological plausibility, testability, repeatability, or supporting evidence of effectiveness. Such practices are ...
it is used in aromatherapy and as a scent in
bath Bath may refer to: * Bathing, immersion in a fluid ** Bathtub, a large open container for water, in which a person may wash their body ** Public bathing, a public place where people bathe * Thermae, ancient Roman public bathing facilities Plac ...
oils.


Properties as a disinfectant

Pine oil is used as a cleaning product,
disinfectant A disinfectant is a chemical substance or compound used to inactivate or destroy microorganisms on inert surfaces. Disinfection does not necessarily kill all microorganisms, especially resistant bacterial spores; it is less effective than ...
, sanitizer, microbicide (or microbistat), virucide or
insecticide Insecticides are pesticides used to kill insects. They include ovicides and larvicides used against insect eggs and larvae, respectively. The major use of insecticides is in agriculture, but they are also used in home and garden settings, i ...
. It is an effective herbicide where its action is to modify the waxy cuticle of plants, resulting in desiccation. Pine oil is a disinfectant that is mildly antiseptic. It is effective against ''Brevibacterium ammoniagenes'', the fungi '' Candida albicans'', '' Enterobacter aerogenes'', ''
Escherichia coli ''Escherichia coli'' ( )Wells, J. C. (2000) Longman Pronunciation Dictionary. Harlow ngland Pearson Education Ltd. is a gram-negative, facultative anaerobic, rod-shaped, coliform bacterium of the genus '' Escherichia'' that is commonly fo ...
'',
Gram-negative Gram-negative bacteria are bacteria that, unlike gram-positive bacteria, do not retain the crystal violet stain used in the Gram staining method of bacterial differentiation. Their defining characteristic is that their cell envelope consists ...
enteric bacteria, household germs, Gram-negative household germs such as those causing
salmonellosis Salmonellosis is a symptomatic infection caused by bacteria of the ''Salmonella'' type. It is the most common disease to be known as food poisoning (though the name refers to food-borne illness in general). These are defined as diseases, usuall ...
,
herpes simplex Herpes simplex, often known simply as herpes, is a viral disease, viral infection caused by the herpes simplex virus. Herpes infections are categorized by the area of the body that is infected. The two major types of herpes are Cold sore, ora ...
types 1 and 2, influenza type A, influenza virus type A/Brazil, influenza virus type A2/Japan, intestinal bacteria, '' Klebsiella pneumoniae'', odor-causing bacteria, mold, mildew, ''
Pseudomonas aeruginosa ''Pseudomonas aeruginosa'' is a common Bacterial capsule, encapsulated, Gram-negative bacteria, Gram-negative, Aerobic organism, aerobic–facultative anaerobe, facultatively anaerobic, Bacillus (shape), rod-shaped bacteria, bacterium that can c ...
'', '' Salmonella choleraesuis'', '' Salmonella typhi'', '' Salmonella typhosa'', ''
Serratia marcescens ''Serratia marcescens'' () is a species of bacillus (shape), rod-shaped, Gram-negative bacteria in the family Yersiniaceae. It is a facultative anaerobe and an opportunistic pathogen in humans. It was discovered in 1819 by Bartolomeo Bizio in Pa ...
'', '' Shigella sonnei'', ''
Staphylococcus aureus ''Staphylococcus aureus'' is a Gram-positive spherically shaped bacterium, a member of the Bacillota, and is a usual member of the microbiota of the body, frequently found in the upper respiratory tract and on the skin. It is often posi ...
'', '' Streptococcus faecalis'', ''
Streptococcus pyogenes ''Streptococcus pyogenes'' is a species of Gram-positive, aerotolerant bacteria in the genus '' Streptococcus''. These bacteria are extracellular, and made up of non-motile and non-sporing cocci (round cells) that tend to link in chains. They ...
'', and '' Trichophyton mentagrophytes''.


Safety

With respect to the quality of indoor air, attention is directed to the effects of ambient ozone on pine oil components. Large doses may cause
central nervous system The central nervous system (CNS) is the part of the nervous system consisting primarily of the brain, spinal cord and retina. The CNS is so named because the brain integrates the received information and coordinates and influences the activity o ...
depression.


See also

* List of cleaning products * Dettol antiseptic liquid * Pine-Sol, cleaning product that originally contained pine oil, though it switched to a different active ingredient in 2013 due to the declining availability of pine oil


References


Further reading

* * {{cite book , chapter-url= http://www.fao.org/docrep/v5350e/V5350e10.htm , title= TURPENTINE FROM PINE RESIN , chapter= 8 , work= Non-Wood Forest Products 1, Flavours and fragrances of plant origin , isbn= 978-92-5-103648-8 , publisher=
Food and Agriculture Organization The Food and Agriculture Organization of the United Nations; . (FAO) is a specialized agency of the United Nations that leads international efforts to defeat hunger and improve nutrition and food security. Its Latin motto, , translates ...
, location= Rome , year= 1995 , archive-url=https://web.archive.org/web/20110117124839/http://www.fao.org/docrep/v5350e/V5350e10.htm , archive-date=January 17, 2011 Aromatherapy Disinfectants Essential oils