Pigeonite is a mineral in the clinopyroxene subgroup of the

pyroxene The pyroxenes (commonly abbreviated Px) are a group of important rock-forming inosilicate minerals found in many igneous and metamorphic rocks. Pyroxenes have the general formula , where X represents ions of calcium (Ca), sodium (Na), iron ( ...

group. It has a general formula of . The

calcium Calcium is a chemical element; it has symbol Ca and atomic number 20. As an alkaline earth metal, calcium is a reactive metal that forms a dark oxide-nitride layer when exposed to air. Its physical and chemical properties are most similar to it ...

cation fraction can vary from 5% to 25%, with iron and magnesium making up the rest of the cations. Pigeonite crystallizes in the

monoclinic In crystallography, the monoclinic crystal system is one of the seven crystal systems. A crystal system is described by three Vector (geometric), vectors. In the monoclinic system, the crystal is described by vectors of unequal lengths, as in t ...

system, as does augite, and a miscibility gap exists between the two minerals. At lower temperatures, pigeonite is unstable relative to augite plus orthopyroxene. The low-temperature limit of pigeonite stability depends upon the Fe/Mg ratio in the mineral and is hotter for more Mg-rich compositions; for a Fe/Mg ratio of about 1, the temperature is about 900 °C. The presence of pigeonite in an

igneous rock Igneous rock ( ), or magmatic rock, is one of the three main rock types, the others being sedimentary and metamorphic. Igneous rocks are formed through the cooling and solidification of magma or lava. The magma can be derived from partial ...

thus provides evidence for the crystallization temperature of the

magma Magma () is the molten or semi-molten natural material from which all igneous rocks are formed. Magma (sometimes colloquially but incorrectly referred to as ''lava'') is found beneath the surface of the Earth, and evidence of magmatism has also ...

, and hence indirectly for the water content of that magma. Pigeonite is found as

phenocryst image:montblanc granite phenocrysts.JPG, 300px, Granites often have large feldspar, feldspathic phenocrysts. This granite, from the Switzerland, Swiss side of the Mont Blanc massif, has large white phenocrysts of plagioclase (that have trapezoid sh ...

s in

volcanic rock Volcanic rocks (often shortened to volcanics in scientific contexts) are rocks formed from lava erupted from a volcano. Like all rock types, the concept of volcanic rock is artificial, and in nature volcanic rocks grade into hypabyssal and me ...

s on Earth and as crystals in

meteorite A meteorite is a rock (geology), rock that originated in outer space and has fallen to the surface of a planet or Natural satellite, moon. When the original object enters the atmosphere, various factors such as friction, pressure, and chemical ...

s from

Mars Mars is the fourth planet from the Sun. It is also known as the "Red Planet", because of its orange-red appearance. Mars is a desert-like rocky planet with a tenuous carbon dioxide () atmosphere. At the average surface level the atmosph ...

and the

Moon The Moon is Earth's only natural satellite. It Orbit of the Moon, orbits around Earth at Lunar distance, an average distance of (; about 30 times Earth diameter, Earth's diameter). The Moon rotation, rotates, with a rotation period (lunar ...

. In slowly cooled intrusive

s, pigeonite is rarely preserved. Slow cooling gives the calcium the necessary time to separate itself from the structure to form exsolution lamellae of calcic clinopyroxene, leaving no pigeonite present. Textural evidence of its breakdown to orthopyroxene plus augite may be present, as shown in the accompanying microscopic image. Pigeonite is named for its type locality on

Lake Superior Lake Superior is the largest freshwater lake in the world by surface areaThe Caspian Sea is the largest lake, but is saline, not freshwater. Lake Michigan–Huron has a larger combined surface area than Superior, but is normally considered tw ...

's shores at Pigeon Point, Minnesota, United States. It was first described in 1900.

References

{{Authority control Pyroxene group Calcium minerals Magnesium minerals Iron(II) minerals Monoclinic minerals Minerals in space group 14