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Piezotronics effect is using the piezoelectric potential (piezopotential) created in materials with
piezoelectricity Piezoelectricity (, ) is the electric charge that accumulates in certain solid materials—such as crystals, certain ceramics, and biological matter such as bone, DNA, and various proteins—in response to applied mechanical stress. The piezoel ...
as a “gate” voltage to tune/control the charge carrier transport properties for fabricating new devices. Neil A Downie showed how simple it was to build simple demonstrations on a macro-scale using a sandwich of piezoelectric material and carbon piezoresistive material to make an FET-like amplifying device and put it in a book of science projects for students in 2006. The fundamental principle of piezotronics was introduced by Prof. Zhong Lin Wang at Georgia Institute of Technology in 2007. From 2006, a series of electronic devices have been demonstrated based on this effect, including piezopotential gated
field-effect transistor The field-effect transistor (FET) is a type of transistor that uses an electric field to control the current through a semiconductor. It comes in two types: junction FET (JFET) and metal-oxide-semiconductor FET (MOSFET). FETs have three termi ...
, piezopotential gated
diode A diode is a two-Terminal (electronics), terminal electronic component that conducts electric current primarily in One-way traffic, one direction (asymmetric electrical conductance, conductance). It has low (ideally zero) Electrical resistance ...
, strain
sensors A sensor is often defined as a device that receives and responds to a signal or stimulus. The stimulus is the quantity, property, or condition that is sensed and converted into electrical signal. In the broadest definition, a sensor is a devi ...
, force/flow sensors, hybrid
field-effect transistor The field-effect transistor (FET) is a type of transistor that uses an electric field to control the current through a semiconductor. It comes in two types: junction FET (JFET) and metal-oxide-semiconductor FET (MOSFET). FETs have three termi ...
, piezotronic
logic gate A logic gate is a device that performs a Boolean function, a logical operation performed on one or more binary inputs that produces a single binary output. Depending on the context, the term may refer to an ideal logic gate, one that has, for ...
s, electromechanical
memories Memory is the faculty of the mind by which data or information is Encoding (memory), encoded, stored, and retrieved when needed. It is the retention of information over time for the purpose of influencing future Action (philosophy), action. I ...
,
Wenzhuo Wu and Zhong Lin Wang, “Piezotronic Nanowire-Based Resistive Switches As Programmable Electromechanical Memories”, Nano Letters, 2011, 11, 2779–2785. etc. Piezotronic devices are regarded as a new semiconductor-device category. Piezotronics is likely to have important applications in
sensor A sensor is often defined as a device that receives and responds to a signal or stimulus. The stimulus is the quantity, property, or condition that is sensed and converted into electrical signal. In the broadest definition, a sensor is a devi ...
, human-silicon technology interfacing,
MEMS MEMS (micro-electromechanical systems) is the technology of microscopic devices incorporating both electronic and moving parts. MEMS are made up of components between 1 and 100 micrometres in size (i.e., 0.001 to 0.1 mm), and MEMS devices ...
, nanorobotics and active flexible electronics.


Mechanism

Due to the non-central
symmetry Symmetry () in everyday life refers to a sense of harmonious and beautiful proportion and balance. In mathematics, the term has a more precise definition and is usually used to refer to an object that is Invariant (mathematics), invariant und ...
in materials such as the
wurtzite Wurtzite is a zinc and iron sulfide mineral with the chemical formula , a less frequently encountered Polymorphism (materials science), structural polymorph form of sphalerite. The iron content is variable up to eight percent.Palache, Charles, H ...
structured ZnO,
GaN The word Gan or the initials GAN may refer to: Places * Gan, a component of Hebrew placenames literally meaning "garden" China * Gan River (Jiangxi) * Gan River (Inner Mongolia), * Gan County, in Jiangxi province * Gansu, abbreviated '' ...
and InN, a piezopotential is created in the
crystal A crystal or crystalline solid is a solid material whose constituents (such as atoms, molecules, or ions) are arranged in a highly ordered microscopic structure, forming a crystal lattice that extends in all directions. In addition, macros ...
by applying a stress. Owing to the simultaneous possession of
piezoelectricity Piezoelectricity (, ) is the electric charge that accumulates in certain solid materials—such as crystals, certain ceramics, and biological matter such as bone, DNA, and various proteins—in response to applied mechanical stress. The piezoel ...
and
semiconductor A semiconductor is a material with electrical conductivity between that of a conductor and an insulator. Its conductivity can be modified by adding impurities (" doping") to its crystal structure. When two regions with different doping level ...
properties, the piezopotential created in the crystal has a strong effect on the carrier transport process. Generally, the construction of the basic piezotronic devices can be divided into two categories. Here we use the nanowires as the example. The first kind is that the piezoelectric nanowire was put on a flexible substrate with two ends fixed by the electrodes. In this case, when the substrate is bended, the nanowire will be purely stretched or compressed. Piezopotential will be introduced along its axis. It will modify the
electric field An electric field (sometimes called E-field) is a field (physics), physical field that surrounds electrically charged particles such as electrons. In classical electromagnetism, the electric field of a single charge (or group of charges) descri ...
or the
Schottky barrier A Schottky barrier, named after Walter H. Schottky, is a potential energy barrier for electrons formed at a metal–semiconductor junction. Schottky barriers have rectifier, rectifying characteristics, suitable for use as a diode. One of the p ...
(SB) height at the contact area. The induced positive piezopotential at one end will reduce the SB height, while the negative piezopotential at the other end will increase it. Thus the electric transport properties will be changed. The second kind of the piezotronic device is that one end of the nanowire is fixed with electrode, while the other end is free. In this case, when a force is applied at the free end of the nanowire to bend it, the piezopotential distribution will be perpendicular to the axis of the nanowire. The introduced piezoelectric field is perpendicular to electron transport direction, just like applying a gate voltage in the traditional
field-effect transistor The field-effect transistor (FET) is a type of transistor that uses an electric field to control the current through a semiconductor. It comes in two types: junction FET (JFET) and metal-oxide-semiconductor FET (MOSFET). FETs have three termi ...
. Thus the electron transport properties will also be changed. The materials for piezotronics should be piezoelectric semiconductors,
Zhong Lin Wang “Piezopotential Gated Nanowire Devices: Piezotronics and Piezo-phototronics”, Nano Today, 5 (2010) 540-552.
such as ZnO, GaN and InN. Three-way coupling among
piezoelectricity Piezoelectricity (, ) is the electric charge that accumulates in certain solid materials—such as crystals, certain ceramics, and biological matter such as bone, DNA, and various proteins—in response to applied mechanical stress. The piezoel ...
, photoexcitation and semiconductor is the basis of piezotronics (piezoelectricity-semiconductor coupling), piezophotonics (piezoelectric-photon excitation coupling),
optoelectronics Optoelectronics (or optronics) is the study and application of electronic devices and systems that find, detect and control light, usually considered a sub-field of photonics. In this context, ''light'' often includes invisible forms of radi ...
, and piezophototronics (piezoelectricity-semiconductor-photoexcitation). The core of these coupling relies on the piezopotential created by the piezoelectric materials.


See also

*
Piezoelectricity Piezoelectricity (, ) is the electric charge that accumulates in certain solid materials—such as crystals, certain ceramics, and biological matter such as bone, DNA, and various proteins—in response to applied mechanical stress. The piezoel ...
* Non linear piezoelectric effects in polar semiconductors *
Wurtzite Wurtzite is a zinc and iron sulfide mineral with the chemical formula , a less frequently encountered Polymorphism (materials science), structural polymorph form of sphalerite. The iron content is variable up to eight percent.Palache, Charles, H ...
* - EU project


References

{{Electronic systems Microtechnology Nanoelectronics Semiconductor devices