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The piezoresistive effect is a change in the
electrical resistivity Electricity is the set of physical phenomena associated with the presence and motion of matter possessing an electric charge. Electricity is related to magnetism, both being part of the phenomenon of electromagnetism, as described by ...
of a
semiconductor A semiconductor is a material with electrical conductivity between that of a conductor and an insulator. Its conductivity can be modified by adding impurities (" doping") to its crystal structure. When two regions with different doping level ...
or
metal A metal () is a material that, when polished or fractured, shows a lustrous appearance, and conducts electrical resistivity and conductivity, electricity and thermal conductivity, heat relatively well. These properties are all associated wit ...
when mechanical strain is applied. In contrast to the
piezoelectric effect Piezoelectricity (, ) is the electric charge that accumulates in certain solid materials—such as crystals, certain ceramics, and biological matter such as bone, DNA, and various proteins—in response to applied stress (mechanics), mechanical s ...
, the piezoresistive effect causes a change only in electrical resistance, not in
electric potential Electric potential (also called the ''electric field potential'', potential drop, the electrostatic potential) is defined as electric potential energy per unit of electric charge. More precisely, electric potential is the amount of work (physic ...
.


History

The change of electrical resistance in metal devices due to an applied mechanical load was first discovered in 1856 by
Lord Kelvin William Thomson, 1st Baron Kelvin (26 June 182417 December 1907), was a British mathematician, Mathematical physics, mathematical physicist and engineer. Born in Belfast, he was the Professor of Natural Philosophy (Glasgow), professor of Natur ...
. With single crystal
silicon Silicon is a chemical element; it has symbol Si and atomic number 14. It is a hard, brittle crystalline solid with a blue-grey metallic lustre, and is a tetravalent metalloid (sometimes considered a non-metal) and semiconductor. It is a membe ...
becoming the material of choice for the design of analog and
digital circuit In theoretical computer science, a circuit is a model of computation in which input values proceed through a sequence of gates, each of which computes a function. Circuits of this kind provide a generalization of Boolean circuits and a mathematica ...
s, the large piezoresistive effect in silicon and germanium was first discovered in 1954 (Smith 1954).


Mechanism

In conducting and semi-conducting materials, changes in inter-atomic spacing resulting from strain affect the
bandgap In solid-state physics and solid-state chemistry, a band gap, also called a bandgap or energy gap, is an energy range in a solid where no electronic states exist. In graphs of the electronic band structure of solids, the band gap refers to the ...
s, making it easier (or harder depending on the material and strain) for electrons to be raised into the
conduction band In solid-state physics, the valence band and conduction band are the bands closest to the Fermi level, and thus determine the electrical conductivity of the solid. In nonmetals, the valence band is the highest range of electron energies in ...
. This results in a change in resistivity of the material. Within a certain range of strain this relationship is linear, so that the piezoresistive coefficient : \rho_\sigma = \frac where :∂ρ = Change in resistivity :ρ = Original resistivity :ε = Strain are constant.


Piezoresistivity in metals

Usually the resistance change in metals is mostly due to the change of geometry resulting from applied mechanical stress. However, even though the piezoresistive effect is small in those cases it is often not negligible. In cases where it is, it can be calculated using the simple resistance equation derived from
Ohm's law Ohm's law states that the electric current through a Electrical conductor, conductor between two Node (circuits), points is directly Proportionality (mathematics), proportional to the voltage across the two points. Introducing the constant of ...
; :R = \rho\frac \, where :\ell Conductor length [m] :''A'' Cross-sectional area of the current flow [m2] Some metals display piezoresistivity that is much larger than the resistance change due to geometry. In platinum alloys, for instance, piezoresistivity is more than a factor of two larger, combining with the geometry effects to give a strain gauge sensitivity of up to more than three times as large than due to geometry effects alone. Pure nickel's piezoresistivity is -13 times larger, completely dwarfing and even reversing the sign of the geometry-induced resistance change.


Piezoresistive effect in bulk semiconductors

The piezoresistive effect of semiconductor materials can be several orders of magnitudes larger than the geometrical effect and is present in materials like
germanium Germanium is a chemical element; it has Symbol (chemistry), symbol Ge and atomic number 32. It is lustrous, hard-brittle, grayish-white and similar in appearance to silicon. It is a metalloid or a nonmetal in the carbon group that is chemically ...
, polycrystalline silicon, amorphous silicon, silicon carbide, and single crystal silicon. Hence, semiconductor strain gauges with a very high coefficient of sensitivity can be built. For precision measurements they are more difficult to handle than metal strain gauges, because semiconductor strain gauges are generally sensitive to environmental conditions (especially temperature). For silicon, gauge factors can be two orders of magnitudes larger than those observed in most metals (Smith 1954). The resistance of n-conducting silicon mainly changes due to a shift of the three different conducting valley pairs. The shifting causes a redistribution of the carriers between valleys with different mobilities. This results in varying mobilities dependent on the direction of current flow. A minor effect is due to the effective mass change related to changing shapes of the valleys. In p-conducting silicon the phenomena are more complex and also result in mass changes and hole transfer.


Giant piezoresistance in metal-silicon hybrid structures

A giant piezoresistive effect – where the piezoresistive coefficient exceeds the bulk value – was reported for a microfabricated silicon-aluminium hybrid structure. The effect has been applied to silicon-based sensor technologies.


Giant piezoresistive effect in silicon nanostructures

The longitudinal piezoresistive coefficient of top-down fabricated silicon
nanowires upright=1.2, Crystalline 2×2-atom tin selenide nanowire grown inside a single-wall carbon nanotube (tube diameter ≈1 nm). A nanowire is a nanostructure in the form of a wire with the diameter of the order of a nanometre (10−9 m). Mor ...
was measured to be 60% larger than in bulk silicon. In 2006, giant piezoresistance was reported in bottom-up fabricated silicon
nanowires upright=1.2, Crystalline 2×2-atom tin selenide nanowire grown inside a single-wall carbon nanotube (tube diameter ≈1 nm). A nanowire is a nanostructure in the form of a wire with the diameter of the order of a nanometre (10−9 m). Mor ...
– a >30 increase in the longitudinal piezoresistive coefficient compared to bulk silicon was reported. The suggestion of a giant piezoresistance in nanostructures has since stimulated much effort into a physical understanding of the effect not only in silicon but also in other functional materials.


Piezoresistive silicon devices

The piezoresistive effect of semiconductors has been used for sensor devices employing all kinds of semiconductor materials such as
germanium Germanium is a chemical element; it has Symbol (chemistry), symbol Ge and atomic number 32. It is lustrous, hard-brittle, grayish-white and similar in appearance to silicon. It is a metalloid or a nonmetal in the carbon group that is chemically ...
, polycrystalline silicon, amorphous silicon, and single crystal silicon. Since silicon is today the material of choice for integrated digital and analog circuits the use of piezoresistive silicon devices has been of great interest. It enables the easy integration of stress sensors with Bipolar and CMOS circuits. This has enabled a wide range of products using the piezoresistive effect. Many commercial devices such as pressure sensors and
acceleration In mechanics, acceleration is the Rate (mathematics), rate of change of the velocity of an object with respect to time. Acceleration is one of several components of kinematics, the study of motion. Accelerations are Euclidean vector, vector ...
sensors employ the piezoresistive effect in
silicon Silicon is a chemical element; it has symbol Si and atomic number 14. It is a hard, brittle crystalline solid with a blue-grey metallic lustre, and is a tetravalent metalloid (sometimes considered a non-metal) and semiconductor. It is a membe ...
. But due to its magnitude the piezoresistive effect in silicon has also attracted the attention of research and development for all other devices using single crystal silicon.
Semiconductor A semiconductor is a material with electrical conductivity between that of a conductor and an insulator. Its conductivity can be modified by adding impurities (" doping") to its crystal structure. When two regions with different doping level ...
Hall sensor In architecture, a hall is a relatively large space enclosed by a roof and walls. In the Iron Age and the Early Middle Ages in northern Europe, a mead hall was where a lord and his retainers ate and also slept. Later in the Middle Ages, the gre ...
s, for example, were capable of achieving their current precision only after employing methods which eliminate signal contributions due to applied mechanical stress.


Piezoresistors

Piezoresistors are resistors made from a piezoresistive material and are usually used for measurement of mechanical stress. They are the simplest form of piezoresistive devices.


Fabrication

Piezoresistors can be fabricated using wide variety of piezoresistive materials. The simplest form of piezoresistive silicon sensors are diffused resistors. Piezoresistors consist of a simple two contact diffused n- or p-wells within a p- or n-substrate. As the typical square resistances of these devices are in the range of several hundred ohms, additional p+ or n+ plus diffusions are a potential method to facilitate ohmic contacts to the device. ''Schematic cross-section of the basic elements of a silicon n-well piezoresistor.''


Physics of operation

For typical stress values in the
MPa MPA or mPa may refer to: Academia Academic degrees * Master of Performing Arts * Master of Professional Accountancy * Master of Public Administration * Master of Public Affairs Schools * Mesa Preparatory Academy * Morgan Park Academy * M ...
range the stress dependent voltage drop along the resistor Vr, can be considered to be linear. A piezoresistor aligned with the x-axis as shown in the figure may be described by :\ V_r = R_0 I + \pi _L \sigma _ + \pi _T (\sigma _ + \sigma _ ) where R_0, ''I'', \pi _T, \pi _L, and \sigma _ denote the stress free resistance, the applied current, the transverse and longitudinal piezoresistive coefficients, and the three tensile stress components, respectively. The piezoresistive coefficients vary significantly with the sensor orientation with respect to the crystallographic axes and with the doping profile. Despite the fairly large stress sensitivity of simple resistors, they are preferably used in more complex configurations eliminating certain cross sensitivities and drawbacks. Piezoresistors have the disadvantage of being highly sensitive to temperature changes while featuring comparatively small relative stress dependent signal amplitude changes.


Other piezoresistive devices

In silicon the piezoresistive effect is used in piezoresistors, transducers, piezo-FETS, solid state
accelerometers An accelerometer is a device that measures the proper acceleration of an object. Proper acceleration is the acceleration (the rate of change of velocity) of the object relative to an observer who is in free fall (that is, relative to an inertia ...
and
bipolar transistors A bipolar junction transistor (BJT) is a type of transistor that uses both electrons and electron holes as charge carriers. In contrast, a unipolar transistor, such as a field-effect transistor (FET), uses only one kind of charge carrier. A ...
. The electrically-conductive packaging material Velostat is used by hobbyists to make pressure sensors due to is piezoresistive properties and low cost.


See also

*
Piezoelectricity Piezoelectricity (, ) is the electric charge that accumulates in certain solid materials—such as crystals, certain ceramics, and biological matter such as bone, DNA, and various proteins—in response to applied mechanical stress. The piezoel ...
*
Electrical resistance The electrical resistance of an object is a measure of its opposition to the flow of electric current. Its reciprocal quantity is , measuring the ease with which an electric current passes. Electrical resistance shares some conceptual paral ...


References

* *S. Middelhoek and S. A. Audet, Silicon Sensors, Delft, The Netherlands: Delft University Press, 1994. *A. L. Window, Strain Gauge Technology, 2nd ed, London, England: Elsevier Applied Science, 1992. * *S. M. Sze, Semiconductor Sensors, New York: Wiley, 1994. {{Authority control Electrical phenomena