Photochemical Machining
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Photochemical machining (PCM), also known as photochemical milling or photo etching, is a chemical milling process used to fabricate sheet metal components using a photoresist and etchants to corrosively
machine A machine is a physical system that uses power to apply forces and control movement to perform an action. The term is commonly applied to artificial devices, such as those employing engines or motors, but also to natural biological macromol ...
away selected areas. This process emerged in the 1960s as an offshoot of the printed circuit board industry. Photo etching can produce highly complex parts with very fine detail accurately and economically. This process can offer economical alternatives to stamping, punching,
laser A laser is a device that emits light through a process of optical amplification based on the stimulated emission of electromagnetic radiation. The word ''laser'' originated as an acronym for light amplification by stimulated emission of radi ...
or water jet cutting, or wire electrical discharge machining (EDM) for thin gauge precision parts. The tooling is inexpensive and quickly produced. This makes the process useful for
prototyping A prototype is an early sample, model, or release of a product built to test a concept or process. It is a term used in a variety of contexts, including semantics, design, electronics, and software programming. A prototype is generally used to ...
and allows for easy changes in
mass production Mass production, also known as mass production, series production, series manufacture, or continuous production, is the production of substantial amounts of standardized products in a constant flow, including and especially on assembly lines ...
. It maintains dimensional tolerances and does not create burrs or sharp edges. It can make a part in hours after receiving the drawing. PCM can be used on virtually any commercially available metal or alloy, of any hardness. It is limited to materials with a thickness of . Metals include
aluminium Aluminium (or aluminum in North American English) is a chemical element; it has chemical symbol, symbol Al and atomic number 13. It has a density lower than that of other common metals, about one-third that of steel. Aluminium has ...
,
brass Brass is an alloy of copper and zinc, in proportions which can be varied to achieve different colours and mechanical, electrical, acoustic and chemical properties, but copper typically has the larger proportion, generally copper and zinc. I ...
,
copper Copper is a chemical element; it has symbol Cu (from Latin ) and atomic number 29. It is a soft, malleable, and ductile metal with very high thermal and electrical conductivity. A freshly exposed surface of pure copper has a pinkish-orang ...
, inconel,
manganese Manganese is a chemical element; it has Symbol (chemistry), symbol Mn and atomic number 25. It is a hard, brittle, silvery metal, often found in minerals in combination with iron. Manganese was first isolated in the 1770s. It is a transition m ...
,
nickel Nickel is a chemical element; it has symbol Ni and atomic number 28. It is a silvery-white lustrous metal with a slight golden tinge. Nickel is a hard and ductile transition metal. Pure nickel is chemically reactive, but large pieces are slo ...
,
silver Silver is a chemical element; it has Symbol (chemistry), symbol Ag () and atomic number 47. A soft, whitish-gray, lustrous transition metal, it exhibits the highest electrical conductivity, thermal conductivity, and reflectivity of any metal. ...
,
steel Steel is an alloy of iron and carbon that demonstrates improved mechanical properties compared to the pure form of iron. Due to steel's high Young's modulus, elastic modulus, Yield (engineering), yield strength, Fracture, fracture strength a ...
,
stainless steel Stainless steel, also known as inox, corrosion-resistant steel (CRES), or rustless steel, is an iron-based alloy that contains chromium, making it resistant to rust and corrosion. Stainless steel's resistance to corrosion comes from its chromi ...
,
zinc Zinc is a chemical element; it has symbol Zn and atomic number 30. It is a slightly brittle metal at room temperature and has a shiny-greyish appearance when oxidation is removed. It is the first element in group 12 (IIB) of the periodic tabl ...
and
titanium Titanium is a chemical element; it has symbol Ti and atomic number 22. Found in nature only as an oxide, it can be reduced to produce a lustrous transition metal with a silver color, low density, and high strength, resistant to corrosion in ...
. Photochemical machining is a form of photo engraving, and a similar process in microfabrication is called
photolithography Photolithography (also known as optical lithography) is a process used in the manufacturing of integrated circuits. It involves using light to transfer a pattern onto a substrate, typically a silicon wafer. The process begins with a photosensiti ...
.


Process

The process starts by printing the shape of the part onto optically clear and dimensionally stable
photographic film Photographic film is a strip or sheet of transparent film base coated on one side with a gelatin photographic emulsion, emulsion containing microscopically small light-sensitive silver halide crystals. The sizes and other characteristics of the ...
. The " phototool" consists of two sheets of this film showing negative images of the parts (meaning that the area that will become the parts is clear and all of the areas to be etched are black). The two sheets are optically and mechanically registered to form the top and bottom halves of the tool.Degarmo, p. 690. The metal sheets are cut to size, cleaned and then laminated on both sides with a UV-sensitive photoresist. The coated metal is placed between the two sheets of the phototool and a vacuum is drawn to ensure intimate contact between the phototool and the metal plate. The plate is then exposed in UV light that allows the areas of resist that are in the clear sections of the film to be hardened. After exposure, the plate is "developed", washing away the unexposed resist and leaving the areas to be etched unprotected. The etching line is a multi-chambered machine that has driven-wheel conveyors to move the plates and arrays of spray nozzles above and below the plates. The etchant is typically an aqueous solution of acid, frequently
ferric chloride Iron(III) chloride describes the inorganic compounds with the formula (H2O)x. Also called ferric chloride, these compounds are some of the most important and commonplace compounds of iron. They are available both in anhydrous and in hydrated f ...
, that is heated and directed under pressure to both sides of the plate. The etchant reacts with the unprotected metal essentially corroding it away fairly quickly. After neutralizing and rinsing, the remaining resist is removed and the sheet of parts is cleaned and dried.


Applications

Thin gauge (under ) parts in a broad range of alloys are candidates for photo etching. Industrial applications include fine screens and meshes, apertures and masks, battery grids,
fuel cell A fuel cell is an electrochemical cell that converts the chemical energy of a fuel (often hydrogen fuel, hydrogen) and an oxidizing agent (often oxygen) into electricity through a pair of redox reactions. Fuel cells are different from most bat ...
components,
sensor A sensor is often defined as a device that receives and responds to a signal or stimulus. The stimulus is the quantity, property, or condition that is sensed and converted into electrical signal. In the broadest definition, a sensor is a devi ...
s, springs, pressure membranes,
heat sink A heat sink (also commonly spelled heatsink) is a passive heat exchanger that transfers the heat generated by an electronic or a mechanical device to a fluid medium, often air or a liquid coolant, where it is thermal management (electronics), ...
s, flexible heating elements, RF and microwave circuits and components, semiconductor leadframes, motor and transformer laminations, metal gaskets and seals, shields and retainers, electrical contacts, encoders and light choppers, EMI/RFI shields,
jewelry Jewellery (or jewelry in American English) consists of decorative items worn for personal adornment such as brooches, ring (jewellery), rings, necklaces, earrings, pendants, bracelets, and cufflinks. Jewellery may be attached to the body or the ...
and washers.


Economics

Phototooling is quick and inexpensive to produce. Most phototools costs less than $350 and can be produced in two days or less. Unlike "hard" tools, such as stamping and punching dies, phototools are exposed only to light and therefore do not suffer wear. Due to the cost of hard tooling for stamping and fine blanking, significant volume is required to justify the expense. Some parts, such as semiconductor leadframes, are so complex and fragile that, despite volumes in the millions of pieces, they can only be produced by photo etching. In PCM, the unit of labor is the sheet. Therefore, it is most economical to plan the largest sheet size possible consistent with the size and dimensional tolerances of the part. The more parts per sheet the lower the unit labor cost per part. Material thickness affects costs as a function of the length of time to etch through. Most alloys etch at rates between of depth per minute per side. In general, steel, copper or aluminium workpieces with a thicknesses up to , part costs will approximate $0.15–0.20 per square inch. As the geometry of the part becomes more complex, photochemical machining gains greater economic advantage over sequential processes such as CNC punching, laser or water-jet cutting, and electrical discharge machining.


References


Bibliography

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