Peter Ludwig Israel Pauson
FRSE
Fellowship of the Royal Society of Edinburgh (FRSE) is an award granted to individuals that the Royal Society of Edinburgh, Scotland's national academy of science and Literature, letters, judged to be "eminently distinguished in their subject". ...
FRIC (1925–2013) was a German–Jewish emigrant who settled in Britain and who is remembered for his contributions to chemistry, most notably the
Pauson–Khand reaction
The Pauson–Khand (PK) reaction is a chemical reaction, described as a Woodward–Hoffmann rules, +2+1cycloaddition. In it, an alkyne, an alkene, and carbon monoxide combine into a α,β-cyclopentenone in the presence of a metal carbonyl, m ...
and as joint discoverer of
ferrocene
Ferrocene is an organometallic chemistry, organometallic compound with the formula . The molecule is a Cyclopentadienyl complex, complex consisting of two Cyclopentadienyl anion, cyclopentadienyl rings sandwiching a central iron atom. It is an o ...
.
Life
He was born in
Bamberg
Bamberg (, , ; East Franconian German, East Franconian: ''Bambärch'') is a town in Upper Franconia district in Bavaria, Germany, on the river Regnitz close to its confluence with the river Main (river), Main. Bamberg had 79,000 inhabitants in ...
,
Germany
Germany, officially the Federal Republic of Germany, is a country in Central Europe. It lies between the Baltic Sea and the North Sea to the north and the Alps to the south. Its sixteen States of Germany, constituent states have a total popu ...
on 30 July 1925, the son of Stefan Pauson and his wife, Helene Dorothea Herzfelder.
His parents escaped to England in 1939 with Peter and his two sisters to flee the Nazi persecution of Jews.
In 1942 the family moved to
Glasgow
Glasgow is the Cities of Scotland, most populous city in Scotland, located on the banks of the River Clyde in Strathclyde, west central Scotland. It is the List of cities in the United Kingdom, third-most-populous city in the United Kingdom ...
and he began studying chemistry in the
University of Glasgow
The University of Glasgow (abbreviated as ''Glas.'' in Post-nominal letters, post-nominals; ) is a Public university, public research university in Glasgow, Scotland. Founded by papal bull in , it is the List of oldest universities in continuous ...
under
Thomas Stevens Stevens. After graduating in 1946, he moved to
Sheffield University
The University of Sheffield (informally Sheffield University or TUOS) is a public research university in Sheffield, South Yorkshire, England. Its history traces back to the foundation of Sheffield Medical School in 1828, Firth College in 1879 ...
as a postgraduate, studying under
Robert Downs Haworth and receiving his doctorate in 1949. He then went to
Duquesne University
Duquesne University of the Holy Spirit ( ; also known as Duquesne University or Duquesne) is a Private university, private Catholic higher education, Catholic research university in Pittsburgh, Pennsylvania, United States. Founded by members of ...
in
Pittsburgh
Pittsburgh ( ) is a city in Allegheny County, Pennsylvania, United States, and its county seat. It is the List of municipalities in Pennsylvania#Municipalities, second-most populous city in Pennsylvania (after Philadelphia) and the List of Un ...
, Pennsylvania and pursued research on
tropolone
Tropolone is an organic compound with the chemical formula . It is a pale yellow solid that is soluble in organic solvents. The compound has been of interest to research chemists because of its unusual electronic structure and its role as a liga ...
s and other aromatic non-benzenoid molecules. His discovery of
ferrocene
Ferrocene is an organometallic chemistry, organometallic compound with the formula . The molecule is a Cyclopentadienyl complex, complex consisting of two Cyclopentadienyl anion, cyclopentadienyl rings sandwiching a central iron atom. It is an o ...
with his student,
Thomas J. Kealy, arose from an attempt to dimerize
cyclopentadienylmagnesium bromide using
Iron(III) chloride
Iron(III) chloride describes the inorganic compounds with the formula (H2O)x. Also called ferric chloride, these compounds are some of the most important and commonplace compounds of iron. They are available both in anhydrous and in hydrated f ...
; the orange-yellow solid with formula C
10H
10Fe was described as a "molecular sandwich" in Pauson's note which was published in ''Nature'' in 1951.
From 1951 to 1952 he studied at the
University of Chicago
The University of Chicago (UChicago, Chicago, or UChi) is a Private university, private research university in Chicago, Illinois, United States. Its main campus is in the Hyde Park, Chicago, Hyde Park neighborhood on Chicago's South Side, Chic ...
under
Morris Kharasch, then becoming a
DuPont
Dupont, DuPont, Du Pont, duPont, or du Pont may refer to:
People
* Dupont (surname) Dupont, also spelled as DuPont, duPont, Du Pont, or du Pont is a French surname meaning "of the bridge", historically indicating that the holder of the surname re ...
Fellow at
Harvard University
Harvard University is a Private university, private Ivy League research university in Cambridge, Massachusetts, United States. Founded in 1636 and named for its first benefactor, the History of the Puritans in North America, Puritan clergyma ...
. He then gained practical experience at the DuPont Laboratories in
Wilmington. Returning to Britain, he became a lecturer at Sheffield University and in 1959 became Professor of Organic Chemistry at
Strathclyde University
The University of Strathclyde () is a public research university located in Glasgow, Scotland. Founded in 1796 as the Andersonian Institute, it is Glasgow's second-oldest university, having received its royal charter in 1964 as the first techn ...
. In 1964 he was elected a Fellow of the
Royal Society of Edinburgh
The Royal Society of Edinburgh (RSE) is Scotland's national academy of science and letters. It is a registered charity that operates on a wholly independent and non-partisan basis and provides public benefit throughout Scotland. It was establis ...
.
Pauson and his postdoctoral assistant, Ihsan Khand, discovered the reaction now renowned as the
Pauson–Khand reaction
The Pauson–Khand (PK) reaction is a chemical reaction, described as a Woodward–Hoffmann rules, +2+1cycloaddition. In it, an alkyne, an alkene, and carbon monoxide combine into a α,β-cyclopentenone in the presence of a metal carbonyl, m ...
in 1971, though Pauson always referred to it as the "Khand reaction".
In 1994, the University of Strathclyde established the
Merck Pauson Chair in Preparative Chemistry, funded by Merck, marking the contribution of Pauson to chemistry and to the university.
Pauson retired in 1995 and died peacefully at home on 10 December 2013. He was cremated at
Clydebank
Clydebank () is a town in West Dunbartonshire, Scotland. Situated on the north bank of the River Clyde, it borders the village of Old Kilpatrick (with Bowling, West Dunbartonshire, Bowling and Milton, West Dunbartonshire, Milton beyond) to the w ...
Crematorium.
In his obituary, he is described as "''a gentleman of modesty, humility, and compassion … a fine man and a marvellous scientist''".
Family
He married Lai-Ngau Mary (née Wong) (1928 – March 18, 2010),
having met her at a party hosted by
Enrico Fermi
Enrico Fermi (; 29 September 1901 – 28 November 1954) was an Italian and naturalized American physicist, renowned for being the creator of the world's first artificial nuclear reactor, the Chicago Pile-1, and a member of the Manhattan Project ...
when Pauson was at the University of Chicago in the early 1950s.
They went on to have two children, Hilary and Alfred.
Selected publications
*''Organometallic Chemistry'' (1967)
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References
{{DEFAULTSORT:Pauson, Peter Ludwig Israel
1925 births
2013 deaths
Jewish emigrants from Nazi Germany to the United Kingdom
German organic chemists
Alumni of the University of Sheffield
Academics of the University of Sheffield
Academics of the University of Strathclyde
Fellows of the Royal Society of Edinburgh
Duquesne University alumni