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Permalloy () is a
nickel Nickel is a chemical element; it has symbol Ni and atomic number 28. It is a silvery-white lustrous metal with a slight golden tinge. Nickel is a hard and ductile transition metal. Pure nickel is chemically reactive, but large pieces are slo ...
iron Iron is a chemical element; it has symbol Fe () and atomic number 26. It is a metal that belongs to the first transition series and group 8 of the periodic table. It is, by mass, the most common element on Earth, forming much of Earth's o ...
magnetic
alloy An alloy is a mixture of chemical elements of which in most cases at least one is a metal, metallic element, although it is also sometimes used for mixtures of elements; herein only metallic alloys are described. Metallic alloys often have prop ...
, with about 80% nickel and 20% iron content. Invented in 1914 by physicist Gustav Elmen at Bell Telephone Laboratories, it is notable for its very high magnetic permeability, which makes it useful as a
magnetic core A magnetic core is a piece of magnetism, magnetic material with a high magnetic permeability used to confine and guide magnetic fields in electrical, electromechanical and magnetic devices such as electromagnets, transformers, electric motors, ele ...
material in electrical and electronic equipment, and also in magnetic shielding to block
magnetic field A magnetic field (sometimes called B-field) is a physical field that describes the magnetic influence on moving electric charges, electric currents, and magnetic materials. A moving charge in a magnetic field experiences a force perpendicular ...
s. Commercial permalloy alloys typically have relative permeability of around 100,000, compared to several thousand for ordinary steel. In addition to high permeability, its other magnetic properties are low
coercivity Coercivity, also called the magnetic coercivity, coercive field or coercive force, is a measure of the ability of a ferromagnetic material to withstand an external magnetic field without becoming Magnetization, demagnetized. Coercivity is usual ...
, near zero magnetostriction, and significant
anisotropic Anisotropy () is the structural property of non-uniformity in different directions, as opposed to isotropy. An anisotropic object or pattern has properties that differ according to direction of measurement. For example, many materials exhibit ver ...
magnetoresistance. The low magnetostriction is critical for industrial applications, allowing it to be used in thin films where variable stresses would otherwise cause a ruinously large variation in magnetic properties. Permalloy's electrical resistivity can vary as much as 5% depending on the strength and the direction of an applied
magnetic field A magnetic field (sometimes called B-field) is a physical field that describes the magnetic influence on moving electric charges, electric currents, and magnetic materials. A moving charge in a magnetic field experiences a force perpendicular ...
. Permalloys typically have the
face-centered cubic In crystallography, the cubic (or isometric) crystal system is a crystal system where the unit cell is in the shape of a cube. This is one of the most common and simplest shapes found in crystals and minerals. There are three main varieties o ...
crystal structure with a lattice constant of approximately 0.355 nm in the vicinity of a nickel concentration of 80%. A disadvantage of permalloy is that it is not very ductile or workable, so applications requiring elaborate shapes, such as magnetic shields, are made of other high permeability alloys such as mu metal. Permalloy is used in
transformer In electrical engineering, a transformer is a passive component that transfers electrical energy from one electrical circuit to another circuit, or multiple Electrical network, circuits. A varying current in any coil of the transformer produces ...
laminations and magnetic recording heads.


Development

Permalloy was initially developed in the early 20th century for inductive compensation of
telegraph Telegraphy is the long-distance transmission of messages where the sender uses symbolic codes, known to the recipient, rather than a physical exchange of an object bearing the message. Thus flag semaphore is a method of telegraphy, whereas ...
cables. When the first transatlantic submarine telegraph cables were laid in the 1860s, it was found that the long conductors caused distortion which reduced the maximum signalling speed to only 10–12 words per minute. The right conditions for transmitting signals through cables without distortion were first worked out mathematically in 1885 by Oliver Heaviside.Bragg, L. ''Electricity'' (London: G. Bell & Sons, 1943) pp. 212–213. It was proposed by Carl Emil Krarup in 1902 in Denmark that the cable could be compensated by wrapping it with iron wire, increasing the
inductance Inductance is the tendency of an electrical conductor to oppose a change in the electric current flowing through it. The electric current produces a magnetic field around the conductor. The magnetic field strength depends on the magnitude of the ...
and making it a loaded line to reduce distortion. However, iron did not have high enough permeability to compensate a transatlantic-length cable. After a prolonged search, permalloy was discovered in 1914 by Gustav Elmen of Bell Laboratories, who found it had higher permeability than silicon steel. Later, in 1923, he found its permeability could be greatly enhanced by heat treatment. A wrapping of permalloy tape could reportedly increase the signalling speed of a telegraph cable fourfold. This method of cable compensation declined in the 1930s, but by World War II many other uses for Permalloy were found in the
electronics industry The electronics industry is the industry (economics), industry that produces electronic devices. It emerged in the 20th century and is today one of the largest global industries. Contemporary society uses a vast array of electronic devices that ar ...
.


Other compositions

Other compositions of permalloy are available, designated by a numerical prefix denoting the weight percentage of
nickel Nickel is a chemical element; it has symbol Ni and atomic number 28. It is a silvery-white lustrous metal with a slight golden tinge. Nickel is a hard and ductile transition metal. Pure nickel is chemically reactive, but large pieces are slo ...
in the
alloy An alloy is a mixture of chemical elements of which in most cases at least one is a metal, metallic element, although it is also sometimes used for mixtures of elements; herein only metallic alloys are described. Metallic alloys often have prop ...
, for example "45 permalloy" means an alloy containing 45%
nickel Nickel is a chemical element; it has symbol Ni and atomic number 28. It is a silvery-white lustrous metal with a slight golden tinge. Nickel is a hard and ductile transition metal. Pure nickel is chemically reactive, but large pieces are slo ...
, and 55%
iron Iron is a chemical element; it has symbol Fe () and atomic number 26. It is a metal that belongs to the first transition series and group 8 of the periodic table. It is, by mass, the most common element on Earth, forming much of Earth's o ...
by weight. "Molybdenum permalloy" is an
alloy An alloy is a mixture of chemical elements of which in most cases at least one is a metal, metallic element, although it is also sometimes used for mixtures of elements; herein only metallic alloys are described. Metallic alloys often have prop ...
of 81%
nickel Nickel is a chemical element; it has symbol Ni and atomic number 28. It is a silvery-white lustrous metal with a slight golden tinge. Nickel is a hard and ductile transition metal. Pure nickel is chemically reactive, but large pieces are slo ...
, 17%
iron Iron is a chemical element; it has symbol Fe () and atomic number 26. It is a metal that belongs to the first transition series and group 8 of the periodic table. It is, by mass, the most common element on Earth, forming much of Earth's o ...
and 2%
molybdenum Molybdenum is a chemical element; it has Symbol (chemistry), symbol Mo (from Neo-Latin ''molybdaenum'') and atomic number 42. The name derived from Ancient Greek ', meaning lead, since its ores were confused with lead ores. Molybdenum minerals hav ...
. The latter was invented at
Bell Labs Nokia Bell Labs, commonly referred to as ''Bell Labs'', is an American industrial research and development company owned by Finnish technology company Nokia. With headquarters located in Murray Hill, New Jersey, Murray Hill, New Jersey, the compa ...
in 1940. At the time, when used in long distance copper telegraph lines, it allowed a tenfold increase in maximum line working speed. Supermalloy, at 75% Ni, 20% Fe, and 5% Mo, is also well known for its high performance as a "soft" magnetic material, characterized by high permeability and low
coercivity Coercivity, also called the magnetic coercivity, coercive field or coercive force, is a measure of the ability of a ferromagnetic material to withstand an external magnetic field without becoming Magnetization, demagnetized. Coercivity is usual ...
.


Applications

Due to its high magnetic permeability and low
coercivity Coercivity, also called the magnetic coercivity, coercive field or coercive force, is a measure of the ability of a ferromagnetic material to withstand an external magnetic field without becoming Magnetization, demagnetized. Coercivity is usual ...
, Permalloy is often used in applications that require efficient magnetic field generation and sensing. It exhibits low energy loss, which is beneficial for improving the performance of magnetic sensors,
transformers ''Transformers'' is a media franchise produced by American toy company Hasbro and Japanese toy company Tomy, Takara Tomy. It primarily follows the heroic Autobots and the villainous Decepticons, two Extraterrestrials in fiction, alien robot fac ...
, and inductors. Permalloy is also used in the production of magnetic shielding materials, which help protect electronic equipment from external magnetic interference.


See also

* Loading coil * Mu-metal * Sendust * Supermalloy (a material with even higher magnetic permeability)


Notes


References

* Richard M. Bozorth, ''Ferromagnetism,'' Wiley-IEEE Press (1993 reissue), . * P. Ciureanu and S. Middelhoek, eds., ''Thin Film Resistive Sensors,'' Institute of Physics Publishing (1992), {{ISBN, 0-7503-0173-2. Nickel alloys Magnetic alloys Ferromagnetic materials