Panethite, chemical formula , is a rare

phosphate mineral Phosphate minerals are minerals that contain the tetrahedrally coordinated phosphate () anion, sometimes with arsenate () and vanadate () substitutions, along with chloride (Cl−), fluoride (F−), and hydroxide (OH−) anions, that also fit in ...

that was only found in one

meteorite A meteorite is a rock (geology), rock that originated in outer space and has fallen to the surface of a planet or Natural satellite, moon. When the original object enters the atmosphere, various factors such as friction, pressure, and chemical ...

on Earth. It was originally found in the Dayton meteorite in

Ohio Ohio ( ) is a U.S. state, state in the Midwestern United States, Midwestern region of the United States. It borders Lake Erie to the north, Pennsylvania to the east, West Virginia to the southeast, Kentucky to the southwest, Indiana to the ...

. It is classified as H-M symbol (2/m) with space group of ''P''2₁/n. It is amber in color. It was named in the honor of Friedrich Adolf Paneth (1887–1958), a German chemist who made many contributions toward the discovery of the origin of the universe, and especially studies of meteorites.

Structure

Using

X-ray diffraction X-ray diffraction is a generic term for phenomena associated with changes in the direction of X-ray beams due to interactions with the electrons around atoms. It occurs due to elastic scattering, when there is no change in the energy of the waves. ...

, the

unit cell In geometry, biology, mineralogy and solid state physics, a unit cell is a repeating unit formed by the vectors spanning the points of a lattice. Despite its suggestive name, the unit cell (unlike a unit vector In mathematics, a unit vector i ...

and the space group parameters were determined. The strongest lines of the X-ray were 5.10(6), 3.236(5), 3.007(10), 2.749, 2.710(7) (American Mineralogist, 509). But the error of the cell lengths were relatively high due to twinning and some disorder in the grains examined. Panethite has a

monoclinic In crystallography, the monoclinic crystal system is one of the seven crystal systems. A crystal system is described by three Vector (geometric), vectors. In the monoclinic system, the crystal is described by vectors of unequal lengths, as in t ...

crystal system In crystallography, a crystal system is a set of point groups (a group of geometric symmetries with at least one fixed point). A lattice system is a set of Bravais lattices (an infinite array of discrete points). Space groups (symmetry groups ...

with a0=10.18 ±0.01Å, b0=14.90 ±0.02Å, c0=25.87 ±0.03Å and β =91.1˚, and its space group P2₁/n. Within the error that accompanied the microprobe analysis, the X-ray density was found to be 2.99g/ml.

Properties

Both brianite and panethite were clear and transparent with no crystal faces; and neither present any discernible cleavage. Panethite is a biaxial negative, pale amber in its color and the estimated 2V was approximated to be 51˚. The refractive indices are α=1.567, β=1.576, γ = 1.579 all ±0.001 (Fuchs, 1967). Even though panethite lacks the lamellar structure that brianite shows, panethite shows simple twinning. The higher refractive indices along with the lamellae structure of brianite help us to distinguish these two minerals apart under the microscope. The

specific gravity Relative density, also called specific gravity, is a dimensionless quantity defined as the ratio of the density (mass of a unit volume) of a substance to the density of a given reference material. Specific gravity for solids and liquids is nea ...

of panethite was between 2.90 and 3.0. Both minerals were insoluble in water. Panethite and brianite are the minerals known to have the greatest amount of sodium content in meteorites (Fuchs, 1967). Panethite was named after the then director of the

Max Planck Institute for Chemistry The Max Planck Institute for Chemistry (Otto Hahn Institute; ) is a non-university research institute under the auspices of the Max Planck Society (German: Max-Planck-Gesellschaft) in Mainz, Germany. It was created as the Kaiser Wilhelm Instit ...

Mainz Mainz (; #Names and etymology, see below) is the capital and largest city of the German state of Rhineland-Palatinate, and with around 223,000 inhabitants, it is List of cities in Germany by population, Germany's 35th-largest city. It lies in ...

Germany Germany, officially the Federal Republic of Germany, is a country in Central Europe. It lies between the Baltic Sea and the North Sea to the north and the Alps to the south. Its sixteen States of Germany, constituent states have a total popu ...

, Friedrich Adolf Paneth (1887-1958).

References

*Fuchs, Louis H.(1967) On the occurrence of Brianite and Panethite, two new phosphate minerals from the Dayton meteorite. Geochimica et Cosmochimica Acta, 31, 1711-1719. *Fuchs, Louis H. (1968) Panethite. American Mineralogist, 53, 509 {{Meteorites Phosphate minerals Meteorite minerals Monoclinic minerals Minerals in space group 14

Structure

Properties

See also

References