Panclastite
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Panclastites are a class of
Sprengel explosive Sprengel explosives are a generic class of materials invented by Hermann Sprengel in the 1870s. They consist of stoichiometric mixtures of strong oxidisers and reactive fuels, mixed just prior to use in order to enhance safety. Either the oxidiser ...
s similar to
oxyliquit An Oxyliquit, also called liquid air explosive or liquid oxygen explosive, is an explosive material which is a mixture of liquid oxygen (LOX) with a suitable fuel, such as carbon (as lampblack), or an organic chemical (e.g. a mixture of soot and n ...
s. They were first suggested in 1881 by
Eugène Turpin François Eugène Turpin (30 September 1848 – 24 January 1927) was a French chemist involved in research of explosive materials. He lived in Colombes. Biography In 1881, Turpin proposed panclastites, a class of Sprengel explosives based on ...
, a French chemist. They are a mixture of liquid
dinitrogen tetroxide Dinitrogen tetroxide, commonly referred to as nitrogen tetroxide (NTO), and occasionally (usually among ex-USSR/Russian rocket engineers) as amyl, is the chemical compound N2O4. It is a useful reagent in chemical synthesis. It forms an equilibrium ...
serving as
oxidizer An oxidizing agent (also known as an oxidant, oxidizer, electron recipient, or electron acceptor) is a substance in a redox chemical reaction that gains or " accepts"/"receives" an electron from a (called the , , or ''electron donor''). In ot ...
with a suitable fuel, e.g.
carbon disulfide Carbon disulfide (also spelled as carbon disulphide) is an inorganic compound with the chemical formula and structure . It is also considered as the anhydride of thiocarbonic acid. It is a colorless, flammable, neurotoxic liquid that is used as ...
, in the 3:2 volume ratio

Other fuel being used is
nitrobenzene Nitrobenzene is an aromatic nitro compound and the simplest of the nitrobenzenes, with the chemical formula C6H5 NO2. It is a water-insoluble pale yellow oil with an almond-like odor. It freezes to give greenish-yellow crystals. It is produced ...
. Possible alternative fuels are e.g. nitrotoluene,
gasoline Gasoline ( North American English) or petrol ( Commonwealth English) is a petrochemical product characterized as a transparent, yellowish, and flammable liquid normally used as a fuel for spark-ignited internal combustion engines. When for ...
,
nitromethane Nitromethane, sometimes shortened to simply "nitro", is an organic compound with the chemical formula . It is the simplest organic nitro compound. It is a polar liquid commonly used as a solvent in a variety of industrial applications such as in ...
, or
halocarbon Halocarbon compounds are chemical compounds in which one or more carbon atoms are linked by covalent bonds with one or more halogen atoms (fluorine, chlorine, bromine or iodine – ) resulting in the formation of organofluorine compounds, or ...
s. Panclastites are shock-sensitive and difficult to handle, requiring their mixing immediately before use; also the dinitrogen tetroxide is highly corrosive and explodes in contact with some chemicals. Despite their
brisance Brisance (; ) is the shattering capability of a high explosive, determined mainly by its detonation pressure. Application Brisance is of practical importance in explosives engineering for determining the effectiveness of an explosion in blasti ...
and
detonation velocity Explosive velocity, also known as detonation velocity or velocity of detonation (VoD), is the velocity at which the shock wave front travels through a detonated explosive. Explosive velocities are always higher than the local speed of sound in t ...
being comparable with
TNT Troponin T (shortened TnT or TropT) is a part of the troponin complex, which are proteins integral to the contraction of skeletal and heart muscles. They are expressed in skeletal and cardiac myocytes. Troponin T binds to tropomyosin and helps ...
, panclastites have virtually no use today. During World War I, due to shortages of other explosives, French used some panclastite-class mixtures, which they called anilites, in small aircraft bombs. The mixing of the chemicals was triggered by airflow spinning a propeller on the nose of the bomb after it was dropped, mixing the previously separated chemicals inside. The resulting mixture was so sensitive the bombs did not need a fuze to explode on impact. In the 1880s, Germans were testing
torpedo A modern torpedo is an underwater ranged weapon launched above or below the water surface, self-propelled towards a target, with an explosive warhead designed to detonate either on contact with or in proximity to the target. Historically, such ...
es with panclastite
warhead A warhead is the section of a device that contains the explosive agent or toxic (biological, chemical, or nuclear) material that is delivered by a missile, rocket (weapon), rocket, torpedo, or bomb. Classification Types of warheads include: *E ...
. Carbon disulfide and nitrogen tetroxide were stored in separate glass compartments, which were broken when the torpedo was launched and the chemicals mixed, and later were detonated by a contact fuse.


References


External links


The Journal of the Society of Chemical Industry. April 29, 1886: NOTE ON SO-CALLED "PANCLASTITE." BY H. SPRENGEL, PH.D., F.R.S.
Explosives Liquid explosives {{explosive-stub