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Palagonite is an alteration product from the interaction of water with volcanic glass of chemical composition similar to
basalt Basalt (; ) is an aphanite, aphanitic (fine-grained) extrusive igneous rock formed from the rapid cooling of low-viscosity lava rich in magnesium and iron (mafic lava) exposed at or very near the planetary surface, surface of a terrestrial ...
. Palagonite can also result from the interaction between water and basalt melt. The water flashes to steam on contact with the hot
lava Lava is molten or partially molten rock (magma) that has been expelled from the interior of a terrestrial planet (such as Earth) or a Natural satellite, moon onto its surface. Lava may be erupted at a volcano or through a Fissure vent, fractu ...
and the small fragments of lava react with the steam to form the light-colored palagonite tuff cones common in areas of basaltic eruptions in contact with water. An example is found in the pyroclastic cones of the Galapagos Islands.
Charles Darwin Charles Robert Darwin ( ; 12 February 1809 – 19 April 1882) was an English Natural history#Before 1900, naturalist, geologist, and biologist, widely known for his contributions to evolutionary biology. His proposition that all speci ...
recognized the origin of these cones during his visit to the islands. Palagonite can also be formed by a slower
weathering Weathering is the deterioration of rocks, soils and minerals (as well as wood and artificial materials) through contact with water, atmospheric gases, sunlight, and biological organisms. It occurs '' in situ'' (on-site, with little or no move ...
of lava into palagonite, resulting in a thin, yellow-orange rind on the surface of the rock. The process of conversion of lava to palagonite is called ''palagonitization.'' Palagonite soil is a light yellow-orange dust, comprising a mixture of particles ranging down to sub-micrometer sizes, usually found mixed with larger fragments of lava. The color is indicative of the presence of
iron Iron is a chemical element; it has symbol Fe () and atomic number 26. It is a metal that belongs to the first transition series and group 8 of the periodic table. It is, by mass, the most common element on Earth, forming much of Earth's o ...
in the +3
oxidation state In chemistry, the oxidation state, or oxidation number, is the hypothetical Electrical charge, charge of an atom if all of its Chemical bond, bonds to other atoms are fully Ionic bond, ionic. It describes the degree of oxidation (loss of electrons ...
, embedded in an amorphous
matrix Matrix (: matrices or matrixes) or MATRIX may refer to: Science and mathematics * Matrix (mathematics), a rectangular array of numbers, symbols or expressions * Matrix (logic), part of a formula in prenex normal form * Matrix (biology), the m ...
. Palagonite tuff is a tuff composed of sideromelane fragments and coarser pieces of basaltic rock, embedded in a palagonite matrix. A composite of sideromelane aggregate in palagonite matrix is called ''
hyaloclastite Hyaloclastite is a volcanoclastic accumulation or breccia consisting of glass (from the Greek ''hyalus'') fragments (clasts) formed by quench fragmentation of lava flow surfaces during submarine or subglacial extrusion. It occurs as thin marg ...
''.


On Mars

Based on infrared
spectroscopy Spectroscopy is the field of study that measures and interprets electromagnetic spectra. In narrower contexts, spectroscopy is the precise study of color as generalized from visible light to all bands of the electromagnetic spectrum. Spectro ...
, the fine-grained component of
Mauna Kea Mauna Kea (, ; abbreviation for ''Mauna a Wākea''); is a dormant Shield volcano, shield volcano on the Hawaii (island), island of Hawaii. Its peak is above sea level, making it the List of U.S. states by elevation, highest point in Hawaii a ...
palagonite is the terrestrial material with the best match to the spectral properties of Martian dust, and is believed to be similar in composition and in origin to dusty component of the surface regolith of
Mars Mars is the fourth planet from the Sun. It is also known as the "Red Planet", because of its orange-red appearance. Mars is a desert-like rocky planet with a tenuous carbon dioxide () atmosphere. At the average surface level the atmosph ...
. The palagonitic
tephra Tephra is fragmental material produced by a Volcano, volcanic eruption regardless of composition, fragment size, or emplacement mechanism. Volcanologists also refer to airborne fragments as pyroclasts. Once clasts have fallen to the ground, ...
from a cinder cone in Hawaii has been used to create Martian regolith simulant for researchers. The spectroscopic signature of palagonitic alteration on Mars is used as evidence for the existence of water on Mars.


References


Further reading


Volcan Darwin

J. R. Michalski*, M. D. Kraft, T. G. Sharp, and P. R. Christensen, ''Palagonite-like Alteration Products on the Earth and Mars I: Spectrocopy (0.4-25 microns) of Weathered Basalta and Silicate Alteration Products'' Lunar and Planetary Science XXXVI (2005) PDF
{{basalt Igneous rocks Volcanology Glass in nature Weathering