Oxyarsenides or arsenide oxides are chemical compounds formally containing the group AsO, with one

arsenic Arsenic is a chemical element; it has Symbol (chemistry), symbol As and atomic number 33. It is a metalloid and one of the pnictogens, and therefore shares many properties with its group 15 neighbors phosphorus and antimony. Arsenic is not ...

and one

oxygen Oxygen is a chemical element; it has chemical symbol, symbol O and atomic number 8. It is a member of the chalcogen group (periodic table), group in the periodic table, a highly reactivity (chemistry), reactive nonmetal (chemistry), non ...

atom. The arsenic and oxygen are not bound together as in

arsenate The arsenate is an ion with the chemical formula . Bonding in arsenate consists of a central arsenic atom, with oxidation state +5, double bonded to one oxygen atom and single bonded to a further three oxygen atoms. The four oxygen atoms orien ...

s or

arsenite In chemistry, an arsenite is a chemical compound containing an arsenic oxyanion where arsenic has oxidation state +3. Note that in fields that commonly deal with groundwater chemistry, arsenite is used generically to identify soluble AsIII anions ...

s, instead they make a separate presence bound to the cations (metals), and could be considered as a mixed

arsenide In chemistry, an arsenide is a compound of arsenic with a less electronegative element or elements. Many metals form binary compounds containing arsenic, and these are called arsenides. They exist with many Stoichiometry, stoichiometries, and in t ...

oxide An oxide () is a chemical compound containing at least one oxygen atom and one other element in its chemical formula. "Oxide" itself is the dianion (anion bearing a net charge of −2) of oxygen, an O2− ion with oxygen in the oxidation st ...

compound. So a compound with O_mAs_n requires

cation An ion () is an atom or molecule with a net electrical charge. The charge of an electron is considered to be negative by convention and this charge is equal and opposite to the charge of a proton, which is considered to be positive by convent ...

s to balance a negative charge of 2m+3n. The cations will have charges of +2 or +3. The trications are often rare earth elements or

actinide The actinide () or actinoid () series encompasses at least the 14 metallic chemical elements in the 5f series, with atomic numbers from 89 to 102, actinium through nobelium. Number 103, lawrencium, is also generally included despite being part ...

s. They are in the category of

oxypnictide In chemistry, oxypnictides are a class of materials composed of oxygen, a pnictogen (group-V, especially phosphorus and arsenic) and one or more other elements. Although this group of compounds has been recognized since 1995, interest in these com ...

compounds. Some of these compounds are superconductors, but may require doping with fluoride or oxygen deficiency. Yet others undergo

colossal magnetoresistance Colossal magnetoresistance (CMR) is a property of some materials, mostly manganese-based perovskite oxides, that enables them to dramatically change their electrical resistance in the presence of a magnetic field. The magnetoresistance of conventio ...

with a lowered electrical resistance in a magnetic field. Many compounds are layered, containing two metals with the formula XZAsO, with an XAs layer alternating with a ZO layer.

Examples

Related compounds include the

oxynitride The oxynitrides are a group of inorganic compounds containing oxygen and nitrogen not bound to each other, instead combined with other non-metallic or metallic elements. Some of these are oxosalts with oxygen replaced by nitrogen. Some of these co ...

oxyphosphides Oxyphosphides are chemical compounds formally containing the group PO, with one phosphorus and one oxygen atom. The phosphorus and oxygen are not bound together as in phosphates or phosphine oxides, instead they are bound separately to the cations ...

, oxyantimonides and

oxybismuthides Oxybismuthides or bismuthide oxides are chemical compounds formally containing the group BiO, with one bismuth and one oxygen atom. The bismuth and oxygen are not bound together as in bismuthates, instead they make a separate presence bound to the ...

References

{{Arsenides Arsenides Oxides