Orthorhombic Bulk Black Phosphorus
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In
crystallography Crystallography is the branch of science devoted to the study of molecular and crystalline structure and properties. The word ''crystallography'' is derived from the Ancient Greek word (; "clear ice, rock-crystal"), and (; "to write"). In J ...
, the orthorhombic crystal system is one of the 7
crystal system In crystallography, a crystal system is a set of point groups (a group of geometric symmetries with at least one fixed point). A lattice system is a set of Bravais lattices (an infinite array of discrete points). Space groups (symmetry groups ...
s. Orthorhombic
lattice Lattice may refer to: Arts and design * Latticework, an ornamental criss-crossed framework, an arrangement of crossing laths or other thin strips of material * Lattice (music), an organized grid model of pitch ratios * Lattice (pastry), an or ...
s result from stretching a cubic lattice along two of its orthogonal pairs by two different factors, resulting in a rectangular
prism PRISM is a code name for a program under which the United States National Security Agency (NSA) collects internet communications from various U.S. internet companies. The program is also known by the SIGAD . PRISM collects stored internet ...
with a rectangular base (''a'' by ''b'') and height (''c''), such that ''a'', ''b'', and ''c'' are distinct. All three bases intersect at 90° angles, so the three lattice vectors remain mutually
orthogonal In mathematics, orthogonality (mathematics), orthogonality is the generalization of the geometric notion of ''perpendicularity''. Although many authors use the two terms ''perpendicular'' and ''orthogonal'' interchangeably, the term ''perpendic ...
.


Bravais lattices

There are four orthorhombic Bravais lattices: primitive orthorhombic, base-centered orthorhombic, body-centered orthorhombic, and face-centered orthorhombic. For the base-centered orthorhombic lattice, the primitive cell has the shape of a right rhombic prism;See , row oC, column Primitive, where the cell parameters are given as a1 = a2, α = β = 90° it can be constructed because the two-dimensional centered rectangular base layer can also be described with primitive rhombic axes. Note that the length a of the primitive cell below equals \frac \sqrt of the conventional cell above.


Crystal classes

The ''orthorhombic crystal system'' class names, examples, Schönflies notation, Hermann-Mauguin notation, point groups, International Tables for Crystallography space group number, orbifold notation, type, and space groups are listed in the table below.


In two dimensions

In two dimensions there are two orthorhombic Bravais lattices: primitive rectangular and centered rectangular.


See also

*Crystal structure *Crystal system *List of the 230 crystallographic 3D space groups, Overview of all space groups


References


Further reading

* * {{DEFAULTSORT:Orthorhombic Crystal System Crystal systems