Oil Shale In Jordan
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Oil shale in Jordan represents a significant resource. Oil shale deposits in Jordan underlie more than 60% of Jordanian territory. The total resources amounts to 31 billion tonnes of
oil shale Oil shale is an organic-rich Granularity, fine-grained sedimentary rock containing kerogen (a solid mixture of Organic compound, organic chemical compounds) from which liquid hydrocarbons can be produced. In addition to kerogen, general compos ...
. The deposits include a high quality
marinite Marinite is a gray to dark-gray or black oil shale of marine origin in which the chief organic components are lamalginite and bituminite derived from marine phytoplankton, with varied admixtures of bitumen, telalginite and vitrinite. Marinite de ...
oil shale of
Late Cretaceous The Late Cretaceous (100.5–66 Ma) is the more recent of two epochs into which the Cretaceous Period is divided in the geologic time scale. Rock strata from this epoch form the Upper Cretaceous Series. The Cretaceous is named after ''cre ...
to early
Cenozoic The Cenozoic Era ( ; ) is Earth's current geological era, representing the last 66million years of Earth's history. It is characterized by the dominance of mammals, insects, birds and angiosperms (flowering plants). It is the latest of three g ...
age. The most important and investigated deposits are located in west-central
Jordan Jordan, officially the Hashemite Kingdom of Jordan, is a country in the Southern Levant region of West Asia. Jordan is bordered by Syria to the north, Iraq to the east, Saudi Arabia to the south, and Israel and the occupied Palestinian ter ...
, where they occur at the surface and close to developed infrastructure. Although oil shale was utilized in northern Jordan prior to and during
World War I World War I or the First World War (28 July 1914 – 11 November 1918), also known as the Great War, was a World war, global conflict between two coalitions: the Allies of World War I, Allies (or Entente) and the Central Powers. Fighting to ...
, intensive exploration and studies of Jordan's oil shale resource potential started in the 1970s and 1980s, being motivated by higher oil prices, modern technology and better economic potential. As of 2008, no
oil shale industry The oil shale industry is an industry of mining and processing of oil shale—a fine-grained sedimentary rock, containing significant amounts of kerogen (a solid mixture of organic chemical compounds), from which liquid hydrocarbons can be manufa ...
exists in Jordan, but several companies are considering both
shale oil extraction Shale oil extraction is an industrial process for unconventional oil production. This process converts kerogen in oil shale into shale oil by pyrolysis, hydrogenation, or thermal dissolution. The resultant shale oil is used as fuel oil or ...
and oil shale
combustion Combustion, or burning, is a high-temperature exothermic redox chemical reaction between a fuel (the reductant) and an oxidant, usually atmospheric oxygen, that produces oxidized, often gaseous products, in a mixture termed as smoke. Combustion ...
for thermal power generation.


Reserves

Jordan has significant oil shale deposits occurring in 26 known localities. According to the
World Energy Council The World Energy Council is a global forum for thought-leadership and tangible engagement with headquarters in London. Its mission is 'To promote the sustainable supply and use of energy for the greatest benefit of all people'. The idea for the fo ...
, Jordan has 8th largest oil shale resource in the world. Geological surveys indicate that the existing deposits underlie more than 60% of Jordan's territory. The resource has been estimated to consist of 40 to 70 billion tonnes of oil shale, which may be equivalent to more than 5 million tonnes of
shale oil Shale oil is an unconventional oil produced from oil shale rock fragments by pyrolysis, hydrogenation, or thermal dissolution. These processes convert the organic matter within the rock (kerogen) into synthetic oil and gas. The resulting oil c ...
. However, according to a report by World Energy Council in 2010, Jordan had reserves of 34,172 billion tonnes as of the end of 2008. The Jordanian government said in September 2013 that they had reserves of 31 billion tonnes. The Jordanian oil shale is a
marinite Marinite is a gray to dark-gray or black oil shale of marine origin in which the chief organic components are lamalginite and bituminite derived from marine phytoplankton, with varied admixtures of bitumen, telalginite and vitrinite. Marinite de ...
of Late Cretaceous (
Maastrichtian The Maastrichtian ( ) is, in the International Commission on Stratigraphy (ICS) geologic timescale, the latest age (geology), age (uppermost stage (stratigraphy), stage) of the Late Cretaceous epoch (geology), Epoch or Upper Cretaceous series (s ...
) to early Cenozoic era; it lies within the Muwaqqar Formation and is composed predominantly of
chalk Chalk is a soft, white, porous, sedimentary carbonate rock. It is a form of limestone composed of the mineral calcite and originally formed deep under the sea by the compression of microscopic plankton that had settled to the sea floor. Ch ...
and
marl Marl is an earthy material rich in carbonate minerals, Clay minerals, clays, and silt. When Lithification, hardened into rock, this becomes marlstone. It is formed in marine or freshwater environments, often through the activities of algae. M ...
. The rock is typically brown, gray, or black in color and weathers to a distinctive light bluish-gray. It is characterized by its content of light
fine-grained Granularity (also called graininess) is the degree to which a material or system is composed of distinguishable pieces, "granules" or "grains" (metaphorically). It can either refer to the extent to which a larger entity is subdivided, or the ...
phosphatic Phosphates are the naturally occurring form of the element phosphorus. In chemistry, a phosphate is an anion, salt, functional group or ester derived from a phosphoric acid. It most commonly means orthophosphate, a derivative of orthophosphor ...
xenocrysts, some of which is accumulated in
bone bed A bone bed is any Geology, geological stratum or deposition (geology), deposit that contains bones of whatever kind. Inevitably, such deposits are Sedimentary rock, sedimentary in nature. Not a formal term, it tends to be used more to describe esp ...
s. An uncommon feature of Jordanian oil shale is that the included
foraminifera Foraminifera ( ; Latin for "hole bearers"; informally called "forams") are unicellular organism, single-celled organisms, members of a phylum or class (biology), class of Rhizarian protists characterized by streaming granular Ectoplasm (cell bio ...
l shells are filled with
bitumen Bitumen ( , ) is an immensely viscosity, viscous constituent of petroleum. Depending on its exact composition, it can be a sticky, black liquid or an apparently solid mass that behaves as a liquid over very large time scales. In American Engl ...
instead of the usual
calcite Calcite is a Carbonate minerals, carbonate mineral and the most stable Polymorphism (materials science), polymorph of calcium carbonate (CaCO3). It is a very common mineral, particularly as a component of limestone. Calcite defines hardness 3 on ...
. In general, Jordanian oil shales are of high quality, comparable to the western United States oil shale, although their
sulfur Sulfur ( American spelling and the preferred IUPAC name) or sulphur ( Commonwealth spelling) is a chemical element; it has symbol S and atomic number 16. It is abundant, multivalent and nonmetallic. Under normal conditions, sulfur atoms ...
content is usually higher. While the sulfur content of the most of oil shales in Jordan varies from 0.3 to 4.3%, the Jurf ed-Darawish and the Sultani deposits have sulfur content of 8 and 10% respectively. Sulfur is mostly associated with the organic matter with minor occurrence as
pyrite The mineral pyrite ( ), or iron pyrite, also known as fool's gold, is an iron sulfide with the chemical formula Fe S2 (iron (II) disulfide). Pyrite is the most abundant sulfide mineral. Pyrite's metallic luster and pale brass-yellow hue ...
. The moisture content of the oil shale is low (2 to 5.5%). The major mineral components of the Jordanian oil shale are calcite,
quartz Quartz is a hard, crystalline mineral composed of silica (silicon dioxide). The Atom, atoms are linked in a continuous framework of SiO4 silicon–oxygen Tetrahedral molecular geometry, tetrahedra, with each oxygen being shared between two tet ...
,
kaolinite Kaolinite ( ; also called kaolin) is a clay mineral, with the chemical composition Al2 Si2 O5( OH)4. It is a layered silicate mineral, with one tetrahedral sheet of silica () linked through oxygen atoms to one octahedral sheet of alumina () ...
, and
apatite Apatite is a group of phosphate minerals, usually hydroxyapatite, fluorapatite and chlorapatite, with high concentrations of Hydroxide, OH−, Fluoride, F− and Chloride, Cl− ion, respectively, in the crystal. The formula of the admixture of ...
, along with small amounts of dolomite,
feldspar Feldspar ( ; sometimes spelled felspar) is a group of rock-forming aluminium tectosilicate minerals, also containing other cations such as sodium, calcium, potassium, or barium. The most common members of the feldspar group are the ''plagiocl ...
,
pyrite The mineral pyrite ( ), or iron pyrite, also known as fool's gold, is an iron sulfide with the chemical formula Fe S2 (iron (II) disulfide). Pyrite is the most abundant sulfide mineral. Pyrite's metallic luster and pale brass-yellow hue ...
,
illite Illite, also called hydromica or hydromuscovite, is a group of closely related non-expanding clay minerals. Illite is a secondary mineral precipitate, and an example of a phyllosilicate, or layered alumino-silicate. Its structure is a 2:1 sandw ...
,
goethite Goethite (, ) is a mineral of the diaspore group, consisting of iron(III) oxide-hydroxide, specifically the α- polymorph. It is found in soil and other low-temperature environments such as sediment. Goethite has been well known since ancient t ...
, and
gypsum Gypsum is a soft sulfate mineral composed of calcium sulfate Hydrate, dihydrate, with the chemical formula . It is widely mined and is used as a fertilizer and as the main constituent in many forms of plaster, drywall and blackboard or sidewalk ...
. It has also a relatively high metal content. The eight most important deposits are located in west-central Jordan within east of the
Dead Sea The Dead Sea (; or ; ), also known by #Names, other names, is a landlocked salt lake bordered by Jordan to the east, the Israeli-occupied West Bank to the west and Israel to the southwest. It lies in the endorheic basin of the Jordan Rift Valle ...
. These deposits are Juref ed Darawish, Sultani, Wadi Maghar, El Lajjun, Attarat Umm Ghudran, Khan ez Zabib, Siwaga, and Wadi Thamad. The best-explored deposits are El Lajjun, Sultani, and Juref ed Darawish, and to some extent Attarat Umm Ghudran. They are all classified as shallow and most are suitable for
open-cast mining Open-pit mining, also known as open-cast or open-cut mining and in larger contexts mega-mining, is a surface mining technique that extracts rock or minerals from the earth. Open-pit mines are used when deposits of commercially useful ore or ro ...
, albeit some are underlain by phosphate beds. In addition to the west-central deposits, another important deposit may be the Yarmouk deposit occurring near Jordan's northern border, and where the resource was first developed. This deposit would be exploitable by underground mining as it reaches some in thickness. A third oil shale region lies in southern Jordan in the
Ma'an Ma'an () is a city in southern Jordan, southwest of the capital Amman. It serves as the capital of the Ma'an Governorate. Its population was approximately 41,055 in 2015. Civilizations with the name of Ma'an have existed at least since the Nab ...
district.


History

Humans have used oil shale as a fuel since prehistoric times, because it generally burns without any processing. Its occurrence was known in Jordan from ancient times, as evidenced by its use as a building and decorative material from the ancient Greek, Roman,
Byzantine The Byzantine Empire, also known as the Eastern Roman Empire, was the continuation of the Roman Empire centred on Constantinople during late antiquity and the Middle Ages. Having survived the events that caused the fall of the Western Roman E ...
,
Umayyad The Umayyad Caliphate or Umayyad Empire (, ; ) was the second caliphate established after the death of the Islamic prophet Muhammad and was ruled by the Umayyad dynasty. Uthman ibn Affan, the third of the Rashidun caliphs, was also a membe ...
and
Abbasid The Abbasid Caliphate or Abbasid Empire (; ) was the third caliphate to succeed the prophets and messengers in Islam, Islamic prophet Muhammad. It was founded by a dynasty descended from Muhammad's uncle, Abbas ibn Abd al-Muttalib (566–653 C ...
periods. The modern exploitation of Jordanian oil shale began under Ottoman rule prior to and during World War I, when the
German Army The German Army (, 'army') is the land component of the armed forces of Federal Republic of Germany, Germany. The present-day German Army was founded in 1955 as part of the newly formed West German together with the German Navy, ''Marine'' (G ...
produced shale oil from the Yarmouk area. The oil shale was processed to operate the Hejaz Railway. It was mined and processed near the Maqarin station along the Haifa spur of the railroad, which partly follows the
Yarmouk River The Yarmuk River (, ; Greek: Ἱερομύκης, ; or ''Heromicas''; sometimes spelled Yarmouk) is the largest tributary of the Jordan River. It runs in Jordan, Syria and Israel, and drains much of the Hauran plateau. Its main tributaries are ...
valley. In addition to the shale oil production, oil shale was also utilized as a mix with coal to fuel locomotives. The German Geological Mission studied the El Lajjun deposit in 1968. In 1979, the Natural Resources Authority of Jordan commissioned a study from the German Federal Institute of Natural Resources and Geosciences to evaluate the Juref ed Darawish, Sultani, El Lajjun, and El Hisa deposits and in 1980 from Klöckner- Lurgi to evaluate the pre-feasibility of construction of an oil shale retorting complex using Lurgi-Ruhrgas process and a power plant with 300 MW capacity using Lurgi's Circulating Fluidized Bed (CFB) combustion process. In 1980, the Soviet Technopromexport company conducted a pre-feasibility study of the 300–400 direct-burning conventional combustion power plant. In 1986, updated and expanded studies were ordered from Klöckner-Lurgi. In 1985–1986, Chinese oil company
Sinopec China Petroleum and Chemical Corporation, or Sinopec Group, is a Chinese oil and gas enterprise based in Chaoyang District, Beijing. The SASAC administers China Petroleum and Chemical Corporation for the benefit of State Council of the ...
carried out a test for processing El Lajjun oil shale utilizing the Fushun-type retort. Although this process was technically viable, the cooperation with Sinopec was halted due to high operation costs. B.B.C, Lummus/Combustion Eng. and Bechtel Pyropower carried out the CIDA and
USAID The United States Agency for International Development (USAID) is an agency of the United States government that has been responsible for administering civilian United States foreign aid, foreign aid and development assistance. Established in 19 ...
funded study of utilizing Sultani oil shale for direct combustion in CFB power plants. The Krzhizhanovsky Power Engineering Institute (ENIN) conducted processing tests of Jordan oil shale using Galoter technology, finding the technology suitable. In 1999,
Suncor Energy Suncor Energy Inc. () is a Canada, Canadian integrated energy company based in Calgary, Alberta. It specializes in production of synthetic crude from oil sands. In the 2020 Forbes Global 2000, Suncor Energy was ranked as the 48th-largest public ...
signed a memorandum of understanding with the Jordanian government to use the Alberta Taciuk Processing technology to exploit the El Lajjun oil shale deposit. However, the project was never implemented.


Shale oil extraction

In 2006–2007, the government of Jordan signed four memorandums of understanding for above-ground processing of shale oil and one memorandum for ''
in-situ is a Latin phrase meaning 'in place' or 'on site', derived from ' ('in') and ' ( ablative of ''situs'', ). The term typically refers to the examination or occurrence of a process within its original context, without relocation. The term is use ...
'' conversion processing. The memorandum of understanding with Estonian energy company
Eesti Energia Eesti Energia AS is a public limited energy company in Estonia with its headquarters in Tallinn. It is the world's biggest oil shale to energy company. The company was founded in 1939. As of 2014, it operates in Estonia, Latvia, Lithuania, Fi ...
was signed on 5 November 2006. According to the agreement, Eesti Energia was awarded with the exclusive right to study about one third of the resources of the El Lajjun oil shale deposit. Later this right was transferred to cover a block on the Attarat Umm Ghudran oil shale deposit as the shallow aquifer that underlies the El Lajjun deposit provides fresh water to Amman and other municipalities in central Jordan. On 29 April 2008, Eesti Energia present a feasibility study to the Government of Jordan. According to the feasibility study, the company's subsidiary the Jordan Oil Shale Energy Company will establish a shale oil plant with capacity of . The shale oil plant will use an Enefit processing technology. The concession agreement was signed on 11 May 2010 in the presence of Jordanian and Estonian prime ministers Samir Zaid al-Rifai and
Andrus Ansip Andrus Ansip (; born 1 October 1956) is an Estonian politician, a member of the European Parliament, the former European Commissioner for Digital Single Market and Vice President of the European Commission, in office from 2014 until 2019. Previo ...
. On 24 February 2007, a memorandum of understanding was signed with Brazil's
Petrobras Petróleo Brasileiro S.A., better known by and Trade name, trading as the portmanteau Petrobras (), is a Brazilian state-owned enterprise, majority state-owned multinational corporation in the petroleum industry headquartered in Rio de Janeiro. ...
awarding with the exclusive right to study a block at the Attarat Umm Ghudran deposit. The development will be carried out in the cooperation with
Total S.A. TotalEnergies SE is a French multinational integrated energy and petroleum company founded in 1924 and is one of the seven supermajor oil companies. Its businesses cover the entire oil and gas chain, from crude oil and natural gas explorat ...
The company will present a feasibility study at the beginning of 2009 and it will use the
Petrosix Petrosix is the world's largest surface oil shale pyrolysis retort with an diameter vertical shaft kiln, operational since 1992. It is located in São Mateus do Sul, Brazil, and it is owned and operated by the Brazil energy company Petrobras. Petr ...
technology. In June 2006, a memorandum of understanding was signed with
Royal Dutch Shell Shell plc is a British multinational oil and gas company, headquartered in London, England. Shell is a public limited company with a primary listing on the London Stock Exchange (LSE) and secondary listings on Euronext Amsterdam and the New ...
to test its ''in-situ'' conversion processing in the Azraq and Al-Jafr blocks of central Jordan. A formal agreement was concluded in February 2009 by which Shell's subsidiary Jordan Oil Shale Company committed to begin commercial operations within 12–20 years. According to the company a decision to invest in a commercial project is unlikely before the late 2020s. It is expected to start production in 2022. On 9 March 2011, the government of Jordan signed a concession agreement with Karak International Oil, a subsidiary of Jordan Energy and Mining, a project company established for Jordan's oil shale activities. Karak International Oil (KIO) will build a shale oil plant in a area of El Lajjun in
Karak Governorate Karak () is one of the governorates of Jordan, located south-west of Amman, Jordan's capital. Its capital is Al-Karak. It s bordered by Madaba Governorate, Madaba and the Amman Governorate, Capital governorates to the north, Ma'an Governorate to th ...
by 2015. The company plans to use the
Alberta Taciuk Process The Alberta Taciuk process (ATP; known also as the AOSTRA Taciuk process) is an above-ground dry thermal retorting technology for extracting oil from oil sands, oil shale and other organics-bearing materials, including oil contaminated soils, slud ...
ing technology. On 5 November 2006, Saudi Arabian International Corporation for Oil Shale Investment (INCOSIN) signed a memorandum of understanding for evaluation of El Lajjun deposit and Attarat Umm Ghudran resources. The concession agreement was approved by the Jordanian government on 3 March 2013. The company cooperates with Russian Atomenergoproekt to utilize the Galoter (UTT-3000) process to build a shale oil plant. It plans to start production in 2019. In March 2009, the government of Jordan approved a memorandum of understanding on oil shale extraction with Russian company
Inter RAO UES Joint Stock Company Inter RAO UES (, short form: Inter RAO), traded as, is a diversified energy holding company headquartered in Moscow, Russia. Its business includes power and heat generation, electricity supply, international energy trading, e ...
and Aqaba Petroleum Company. Also the
Abu Dhabi National Energy Company Taqa or TAQA may refer to: * Taqa, Iran, a village in Khuzestan Province, Iran * Taqah, town in Oman * Abu Dhabi National Energy Company (TAQA) *Training, Assessment and Quality Assurance (TAQA) in relation to adult, further and work-based education ...
(TAQA) has shown interest to invest into Jordan's oil shale extraction sector. The memorandum of understanding for exploration in Wadi Al Naadiyeh is ready for signing with the
Fushun Mining Group Fushun Mining Group (, FMG) is a large state-owned coal and oil shale company located in Fushun, Liaoning Province, China. The corporation consists of about 30 companies with about 28,000 employees. The main business includes coal min ...
. In 2014, a memorandum of understanding was signed with Al Qamar for Energy and Infrastructure Company.


Power generation

For dealing with increasing power consumption, Jordan plans to utilize oil shale combustion for the power generation. On 30 April 2008, the Ministry of Energy and Mineral Resources of Jordan, the National Electricity Power Company of Jordan, and Eesti Energia signed an agreement, according to which, Eesti Energia will have the exclusive right to develop the construction of an oil shale-fired power plant with capacity of 460 MW. It is called Attarat Power Plant and is expected to be operational by 2017, revised to 2021. It will be among the largest power stations in Jordan (the largest being
Aqaba Thermal Power Plant The Aqaba Thermal Power Station is the largest power station in Jordan. It has a total generation capacity of 656  MW, which consists of five steam turbines units (5 x 130 MW), and two hydraulic turbines (2 x 3 MW). The power station ...
), and the largest oil shale-fired power plant in the world after
Narva Power Plants The Narva Power Plants () are a power generation complex in and near Narva in Estonia, near the border with Leningrad Oblast, Russia. The complex consists of the world's two largest oil shale-fired thermal power plants, Eesti Power Plant () and ...
in Estonia. Inter RAO is planning to build an oil shale-fired power plant with capacity of 90–150 MW. On 29 September 2013, Jordan and China made a deal to build an oil shale-fired power plant in Karak for $2.5 billion. It will be built by Shandong Electric Power Construction Corporation (SEPCO III), HTJ Group and Al-Lajjun Oil Shale Company. The capacity is 900 MW.


Cement production

In November 2005, a memorandum of understanding was signed with the Jordan Cement Factories Company (JCFC). According to this memorandum, JCFC will utilize El Lajjun oil shale from Karak Governorate for cement production.


References

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