There are several known

allotropes Allotropy or allotropism () is the property of some chemical elements to exist in two or more different forms, in the same physical state, known as allotropes of the elements. Allotropes are different structural modifications of an element: th ...

oxygen Oxygen is a chemical element; it has chemical symbol, symbol O and atomic number 8. It is a member of the chalcogen group (periodic table), group in the periodic table, a highly reactivity (chemistry), reactive nonmetal (chemistry), non ...

. The most familiar is

molecular oxygen There are several known allotropes of oxygen. The most familiar is molecular oxygen (), present at significant levels in Earth's atmosphere and also known as dioxygen or triplet oxygen. Another is the highly reactive ozone (). Others are: * Atomic ...

(), present at significant levels in

Earth's atmosphere The atmosphere of Earth is composed of a layer of gas mixture that surrounds the Earth's planetary surface (both lands and oceans), known collectively as air, with variable quantities of suspended aerosols and particulates (which create weathe ...

and also known as dioxygen or

triplet oxygen Triplet oxygen, 3O2, refers to the ''S'' = 1 electronic ground state of molecular oxygen (dioxygen). Molecules of triplet oxygen contain two unpaired electrons, making triplet oxygen an unusual example of a stable and commonly encountered diradi ...

. Another is the highly reactive

ozone Ozone () (or trioxygen) is an Inorganic compound, inorganic molecule with the chemical formula . It is a pale blue gas with a distinctively pungent smell. It is an allotrope of oxygen that is much less stable than the diatomic allotrope , break ...

(). Others are: *

Atomic oxygen There are several known allotropes of oxygen. The most familiar is molecular oxygen (), present at significant levels in Earth's atmosphere and also known as dioxygen or triplet oxygen. Another is the highly reactive ozone (). Others are: * Atomic ...

(), a

free radical A daughter category of ''Ageing'', this category deals only with the biological aspects of ageing. Ageing Biogerontology Biological processes Causes of death Cellular processes Gerontology Life extension Metabolic disorders Metabolism ...

. *

Singlet oxygen Singlet oxygen, systematically named dioxygen(singlet) and dioxidene, is a gaseous inorganic chemistry, inorganic chemical with the formula O=O (also written as or ), which is in a quantum state where all electrons are Radical (chemistry), spin p ...

(), one of two

metastable state In chemistry and physics, metastability is an intermediate energetic state within a dynamical system other than the system's state of least energy. A ball resting in a hollow on a slope is a simple example of metastability. If the ball is onl ...

s of molecular oxygen. *

Tetraoxygen The tetraoxygen molecule (O4), also called oxozone, is an Allotropy, allotrope of oxygen consisting of four oxygen atoms. History Tetraoxygen was first predicted in 1924 by Gilbert N. Lewis, who proposed it as an explanation for the failure of l ...

(), another metastable form. *

Solid oxygen Solid oxygen is the solid ice phase of oxygen. It forms below at standard atmospheric pressure. Solid oxygen O2, like liquid oxygen, is a clear substance with a light sky-blue color caused by absorption in the red part of the visible light spec ...

, existing in six variously colored phases, of which one is

octaoxygen Octaoxygen, also known as ε-oxygen or red oxygen, is an allotrope of oxygen consisting of eight oxygen atoms. This allotrope forms at room temperature at pressures between 10 and 96 GPa. Preparation and properties As the pressure of oxygen a ...

(, red oxygen) and another one metallic (ζ-oxygen).

Atomic oxygen

Atomic oxygen, denoted O or O₁, is very reactive, as the individual atoms of oxygen tend to quickly bond with nearby molecules. Its lowest-energy electronic state is a

spin triplet In quantum mechanics, a triplet state, or spin triplet, is the quantum state of an object such as an electron, atom, or molecule, having a quantum spin ''S'' = 1. It has three allowed values of the spin's projection along a given axis ''m''S = � ...

, designated by the

term symbol In atomic physics, a term symbol is an abbreviated description of the total spin and orbital angular momentum quantum numbers of the electrons in a multi-electron atom. So while the word ''symbol'' suggests otherwise, it represents an actual ''valu ...

³P. On Earth's surface, it exists naturally for a very short time. In outer space, the presence of ample

ultraviolet radiation Ultraviolet radiation, also known as simply UV, is electromagnetic radiation of wavelengths of 10–400 nanometers, shorter than that of visible light, but longer than X-rays. UV radiation is present in sunlight and constitutes about 10% of t ...

results in a

low Earth orbit A low Earth orbit (LEO) is an geocentric orbit, orbit around Earth with a orbital period, period of 128 minutes or less (making at least 11.25 orbits per day) and an orbital eccentricity, eccentricity less than 0.25. Most of the artificial object ...

atmosphere in which 96% of the oxygen occurs in atomic form."Out of Thin Air"
.NASA.gov. February 17, 2011. Atomic oxygen has been detected on

Mars Mars is the fourth planet from the Sun. It is also known as the "Red Planet", because of its orange-red appearance. Mars is a desert-like rocky planet with a tenuous carbon dioxide () atmosphere. At the average surface level the atmosph ...

Mariner A sailor, seaman, mariner, or seafarer is a person who works aboard a watercraft as part of its crew, and may work in any one of a number of different fields that are related to the operation and maintenance of a ship. While the term ''sailor' ...

Viking Vikings were seafaring people originally from Scandinavia (present-day Denmark, Norway, and Sweden), who from the late 8th to the late 11th centuries raided, pirated, traded, and settled throughout parts of Europe.Roesdahl, pp. 9� ...

, and the

SOFIA Sofia is the Capital city, capital and List of cities and towns in Bulgaria, largest city of Bulgaria. It is situated in the Sofia Valley at the foot of the Vitosha mountain, in the western part of the country. The city is built west of the Is ...

observatory.

Dioxygen

The common allotrope of elemental oxygen on Earth, , is generally known as oxygen, but may be called ''dioxygen'', ''diatomic oxygen'', ''molecular oxygen'', ''dioxidene'' or ''oxygen gas'' to distinguish it from the element itself and from the triatomic allotrope ''

,'' . As a major component (about 21% by volume) of Earth's

atmosphere An atmosphere () is a layer of gases that envelop an astronomical object, held in place by the gravity of the object. A planet retains an atmosphere when the gravity is great and the temperature of the atmosphere is low. A stellar atmosph ...

, elemental oxygen is most commonly encountered in the diatomic form.

Aerobic organisms An aerobic organism or aerobe is an organism that can survive and grow in an oxygenated environment. The ability to exhibit aerobic respiration may yield benefits to the aerobic organism, as aerobic respiration yields more energy than anaerobic ...

use atmospheric dioxygen as the terminal oxidant in

cellular respiration Cellular respiration is the process of oxidizing biological fuels using an inorganic electron acceptor, such as oxygen, to drive production of adenosine triphosphate (ATP), which stores chemical energy in a biologically accessible form. Cell ...

in order to obtain

chemical energy Chemical energy is the energy of chemical substances that is released when the substances undergo a chemical reaction and transform into other substances. Some examples of storage media of chemical energy include batteries, Schmidt-Rohr, K. (20 ...

. The

ground state The ground state of a quantum-mechanical system is its stationary state of lowest energy; the energy of the ground state is known as the zero-point energy of the system. An excited state is any state with energy greater than the ground state ...

of dioxygen is known as

, , because it has two unpaired electrons. The first excited state,

singlet oxygen Singlet oxygen, systematically named dioxygen(singlet) and dioxidene, is a gaseous inorganic chemistry, inorganic chemical with the formula O=O (also written as or ), which is in a quantum state where all electrons are Radical (chemistry), spin p ...

, , has no unpaired electrons and is

metastable In chemistry and physics, metastability is an intermediate energetic state within a dynamical system other than the system's state of least energy. A ball resting in a hollow on a slope is a simple example of metastability. If the ball is onl ...

. The

doublet Doublet is a word derived from the Latin ''duplus'', "twofold, twice as much", * Theoretical analysis of some and lead-ref for others: {{DEFAULTSORT:Allotropes of oxygen Oxygen