Nitrosonium Octafluoroxenate(VI)
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Nitrosonium octafluoroxenate(VI) is a
chemical compound A chemical compound is a chemical substance composed of many identical molecules (or molecular entities) containing atoms from more than one chemical element held together by chemical bonds. A molecule consisting of atoms of only one element ...
of
xenon Xenon is a chemical element; it has symbol Xe and atomic number 54. It is a dense, colorless, odorless noble gas found in Earth's atmosphere in trace amounts. Although generally unreactive, it can undergo a few chemical reactions such as the ...
with
nitrogen Nitrogen is a chemical element; it has Symbol (chemistry), symbol N and atomic number 7. Nitrogen is a Nonmetal (chemistry), nonmetal and the lightest member of pnictogen, group 15 of the periodic table, often called the Pnictogen, pnictogens. ...
,
oxygen Oxygen is a chemical element; it has chemical symbol, symbol O and atomic number 8. It is a member of the chalcogen group (periodic table), group in the periodic table, a highly reactivity (chemistry), reactive nonmetal (chemistry), non ...
, and
fluorine Fluorine is a chemical element; it has Chemical symbol, symbol F and atomic number 9. It is the lightest halogen and exists at Standard temperature and pressure, standard conditions as pale yellow Diatomic molecule, diatomic gas. Fluorine is extre ...
, having
formula In science, a formula is a concise way of expressing information symbolically, as in a mathematical formula or a ''chemical formula''. The informal use of the term ''formula'' in science refers to the general construct of a relationship betwe ...
. It is an ionic compound containing well-separated
nitrosonium The nitrosonium ion is , in which the nitrogen atom is bonded to an oxygen atom with a bond order of 3, and the overall diatomic species bears a positive charge. It can be viewed as nitric oxide with one electron removed. This ion is usually o ...
cations (NO+) and octafluoroxenate(VI) anions (). The
molecular geometry Molecular geometry is the three-dimensional arrangement of the atoms that constitute a molecule. It includes the general shape of the molecule as well as bond lengths, bond angles, torsional angles and any other geometrical parameters that det ...
of the octafluoroxenate(VI) ion is square antiprismatic, having Xe–F bond lengths of 1.971  Ã…, 1.946 Ã…, 1.958 Ã…, 2.052 Ã…, and 2.099 Ã…. It is synthesized by the reaction of
xenon hexafluoride Xenon hexafluoride is a noble gas compound with the formula XeF6. It is one of the three binary fluorides of xenon that have been studied experimentally, the other two being XeF2 and XeF4. All of them are exergonic and stable at normal temperatur ...
() with nitrosyl fluoride (NOF): : + 2 NOF → Other compounds containing the octafluoroxenate(VI) ion include its alkali metal salts, including Cs2XeF8 and Rb2XeF8, which are stable up to 400 Â°C.


References

Xenon(VI) compounds Fluoro complexes {{inorganic-compound-stub