Nikolay Nikolayevich Beketov (; , Alferovka (now Beketovka),
Penza Governorate
Penza Governorate () was an administrative-territorial unit (''guberniya'') of the Russian Empire and Russian Soviet Federative Socialist Republic, Russian SFSR, located in the Volga Region. It existed from 1780 to 1797 and again from 1801 to 1928 ...
,
Russian Empire
The Russian Empire was an empire that spanned most of northern Eurasia from its establishment in November 1721 until the proclamation of the Russian Republic in September 1917. At its height in the late 19th century, it covered about , roughl ...
– ,
St. Petersburg
Saint Petersburg, formerly known as Petrograd and later Leningrad, is the second-largest city in Russia after Moscow. It is situated on the River Neva, at the head of the Gulf of Finland on the Baltic Sea. The city had a population of 5,601, ...
,
Russian Empire
The Russian Empire was an empire that spanned most of northern Eurasia from its establishment in November 1721 until the proclamation of the Russian Republic in September 1917. At its height in the late 19th century, it covered about , roughl ...
) was a Russian Imperial
physical chemist
Physical chemistry is the study of macroscopic and microscopic phenomena in chemical systems in terms of the principles, practices, and concepts of physics such as motion, energy, force, time, thermodynamics, quantum chemistry, statistical mecha ...
and
metallurgist
Metallurgy is a domain of materials science and engineering that studies the physical and chemical behavior of metallic elements, their inter-metallic compounds, and their mixtures, which are known as alloys.
Metallurgy encompasses both the ...
.
He was the father of a well-known Russian architect
Alexei Beketov
Oleksiy Mykolaovych Beketov (; 3 March 1862, Kharkiv, Russian Empire — 23 November 1941, Kharkiv, Ukrainian SSR) was a Ukrainian architect, , who made significant contributions to the architectural landscape of Kharkiv and beyond, primarily work ...
.
Life and work
In 1849 Beketov graduated from
Kazan University
Kazan Federal University (; ) is a public research university located in Kazan, Russia.
The university was founded in 1804 as Imperial Kazan University, which makes it the second oldest continuously existing tertiary education institution in Rus ...
and worked with
Nikolay Zinin.
In 1855 he became a junior scientific assistant in the Department of
Chemistry
Chemistry is the scientific study of the properties and behavior of matter. It is a physical science within the natural sciences that studies the chemical elements that make up matter and chemical compound, compounds made of atoms, molecules a ...
at
Kharkov University
The V. N. Karazin Kharkiv National University (), also known as Kharkiv National University or Karazin University, is a public university in Kharkiv, Ukraine. It was founded in 1804 through the efforts of Vasily Karazin, becoming the second old ...
.
In 1859-1887 Beketov was a professor at the same university.
In 1865 he defended his PhD thesis on "Research into the phenomenon of displacement of one element by another" ("").
In 1886 Beketov moved to
Saint Petersburg
Saint Petersburg, formerly known as Petrograd and later Leningrad, is the List of cities and towns in Russia by population, second-largest city in Russia after Moscow. It is situated on the Neva, River Neva, at the head of the Gulf of Finland ...
, where he worked at the academic chemical
laboratory
A laboratory (; ; colloquially lab) is a facility that provides controlled conditions in which scientific or technological research, experiments, and measurement may be performed. Laboratories are found in a variety of settings such as schools ...
and taught at the University for Women.

In 1890 Beketov delivered
lecture
A lecture (from ) is an oral presentation intended to present information or teach people about a particular subject, for example by a university or college teacher. Lectures are used to convey critical information, history, background, theo ...
s on the "Basics of
Thermochemistry
Thermochemistry is the study of the heat energy which is associated with chemical reactions and/or phase changes such as melting and boiling. A reaction may release or absorb energy, and a phase change may do the same. Thermochemistry focuses on ...
" at
Moscow State University
Moscow State University (MSU), officially M. V. Lomonosov Moscow State University,. is a public university, public research university in Moscow, Russia. The university includes 15 research institutes, 43 faculties, more than 300 departments, a ...
.
Beketov discovered displacement of metals from
solutions
Solution may refer to:
* Solution (chemistry), a mixture where one substance is dissolved in another
* Solution (equation), in mathematics
** Numerical solution, in numerical analysis, approximate solutions within specified error bounds
* Solutio ...
of their salts by
hydrogen
Hydrogen is a chemical element; it has chemical symbol, symbol H and atomic number 1. It is the lightest and abundance of the chemical elements, most abundant chemical element in the universe, constituting about 75% of all baryon, normal matter ...
under pressure. He also established that
magnesium
Magnesium is a chemical element; it has Symbol (chemistry), symbol Mg and atomic number 12. It is a shiny gray metal having a low density, low melting point and high chemical reactivity. Like the other alkaline earth metals (group 2 ...
and
zinc
Zinc is a chemical element; it has symbol Zn and atomic number 30. It is a slightly brittle metal at room temperature and has a shiny-greyish appearance when oxidation is removed. It is the first element in group 12 (IIB) of the periodic tabl ...
displaced other metals from their salts under high
temperature
Temperature is a physical quantity that quantitatively expresses the attribute of hotness or coldness. Temperature is measurement, measured with a thermometer. It reflects the average kinetic energy of the vibrating and colliding atoms making ...
s.
In 1859-1865 Beketov proved that
aluminum
Aluminium (or aluminum in North American English) is a chemical element; it has chemical symbol, symbol Al and atomic number 13. It has a density lower than that of other common metals, about one-third that of steel. Aluminium has ...
restored metals from their
oxide
An oxide () is a chemical compound containing at least one oxygen atom and one other element in its chemical formula. "Oxide" itself is the dianion (anion bearing a net charge of −2) of oxygen, an O2− ion with oxygen in the oxidation st ...
s under high temperatures. Later on, Beketov's experiments served as a starting point for
aluminothermy.
Beketov's biggest merit was his contribution into
physical chemistry
Physical chemistry is the study of macroscopic and microscopic phenomena in chemical systems in terms of the principles, practices, and concepts of physics such as motion, energy, force, time, thermodynamics, quantum chemistry, statistical mech ...
as an independent
science
Science is a systematic discipline that builds and organises knowledge in the form of testable hypotheses and predictions about the universe. Modern science is typically divided into twoor threemajor branches: the natural sciences, which stu ...
. In 1860 he taught a course on "Relations between physical and chemical phenomena" in
Kharkov
Kharkiv, also known as Kharkov, is the second-largest List of cities in Ukraine, city in Ukraine. and a course on "Physical Chemistry" in 1865.
In 1864 a Physical Chemistry Department in Kharkov University was established with his active participation, where students would conduct research and do practical
work.
[
In 1886 Beketov was elected a full member of the ]Petersburg Academy of Sciences
The Russian Academy of Sciences (RAS; ''Rossíyskaya akadémiya naúk'') consists of the national academy of Russia; a network of scientific research institutes from across the Russian Federation; and additional scientific and social units such ...
.[
Beketov's students were ]Alexander Eltekov
Alexander () is a male name of Greek origin. The most prominent bearer of the name is Alexander the Great, the king of the Ancient Greek kingdom of Macedonia who created one of the largest empires in ancient history.
Variants listed here are A ...
, Flavian Flavitsky Flavian may refer to:
* A member of the Flavian dynasty of Roman emperors, during the late 1st century AD, or their works
* Flavian Zeija, a Ugandan lawyer, academic and judge. Principal Judge of Uganda, since December 2019.
* A person named Flavian ...
and others. The poet Alexander Blok
Alexander Alexandrovich Blok ( rus, Алекса́ндр Алекса́ндрович Бло́к, p=ɐlʲɪˈksandr ɐlʲɪˈksandrəvʲɪtɕ ˈblok, a=Ru-Alyeksandr Alyeksandrovich Blok.oga; 7 August 1921) was a Russian lyrical poet, writer, publ ...
was his brother's grandson.
References
External links
{{DEFAULTSORT:Beketov, Nikolay Nikolayevich
Chemists from the Russian Empire
Inventors from the Russian Empire
1827 births
1911 deaths
Academic staff of Moscow State University
Metallurgists from the Russian Empire
Full members of the Saint Petersburg Academy of Sciences
Privy Councillor (Russian Empire)
Burials at Smolensky Cemetery