Neutron activation is the process in which

neutron radiation Neutron radiation is a form of ionizing radiation that presents as free neutrons. Typical phenomena are nuclear fission or nuclear fusion causing the release of free neutrons, which then react with nuclei of other atoms to form new nuclides— ...

induces

radioactivity Radioactive decay (also known as nuclear decay, radioactivity, radioactive disintegration, or nuclear disintegration) is the process by which an unstable atomic nucleus loses energy by radiation. A material containing unstable nuclei is conside ...

in materials, and occurs when

atomic nuclei The atomic nucleus is the small, dense region consisting of protons and neutrons at the center of an atom, discovered in 1911 by Ernest Rutherford at the University of Manchester based on the 1909 Geiger–Marsden gold foil experiment. Aft ...

capture free neutrons, becoming heavier and entering

excited state In quantum mechanics Quantum mechanics is the fundamental physical Scientific theory, theory that describes the behavior of matter and of light; its unusual characteristics typically occur at and below the scale of atoms. Reprinted, Add ...

s. The excited nucleus decays immediately by emitting

gamma rays A gamma ray, also known as gamma radiation (symbol ), is a penetrating form of electromagnetic radiation arising from high energy interactions like the radioactive decay of atomic nuclei or astronomical events like solar flares. It consists o ...

, or particles such as beta particles,

alpha particle Alpha particles, also called alpha rays or alpha radiation, consist of two protons and two neutrons bound together into a particle identical to a helium-4 nucleus. They are generally produced in the process of alpha decay but may also be produce ...

s, fission products, and neutrons (in

nuclear fission Nuclear fission is a reaction in which the nucleus of an atom splits into two or more smaller nuclei. The fission process often produces gamma photons, and releases a very large amount of energy even by the energetic standards of radioactiv ...

). Thus, the process of

neutron capture Neutron capture is a nuclear reaction in which an atomic nucleus and one or more neutrons collide and merge to form a heavier nucleus. Since neutrons have no electric charge, they can enter a nucleus more easily than positively charged protons, wh ...

, even after any intermediate decay, often results in the formation of an unstable activation product. Such radioactive nuclei can exhibit

half-lives Half-life is a mathematical and scientific description of exponential or gradual decay. Half-life, half life or halflife may also refer to: Film * ''Half-Life'' (film), a 2008 independent film by Jennifer Phang * '' Half Life: A Parable for t ...

ranging from small fractions of a second to many years. Neutron activation is the only common way that a stable material can be induced into becoming intrinsically radioactive. All naturally occurring materials, including air, water, and soil, can be induced (activated) by neutron capture into some amount of radioactivity in varying degrees, as a result of the production of neutron-rich

radioisotope A radionuclide (radioactive nuclide, radioisotope or radioactive isotope) is a nuclide that has excess numbers of either neutrons or protons, giving it excess nuclear energy, and making it unstable. This excess energy can be used in one of three ...

s. Some atoms require more than one neutron to become unstable, which makes them harder to activate because the probability of a double or triple capture by a nucleus is below that of single capture. Water, for example, is made up of hydrogen and oxygen.

Hydrogen Hydrogen is a chemical element; it has chemical symbol, symbol H and atomic number 1. It is the lightest and abundance of the chemical elements, most abundant chemical element in the universe, constituting about 75% of all baryon, normal matter ...

requires a double capture to attain instability as

tritium Tritium () or hydrogen-3 (symbol T or H) is a rare and radioactive isotope of hydrogen with a half-life of ~12.33 years. The tritium nucleus (t, sometimes called a ''triton'') contains one proton and two neutrons, whereas the nucleus of the ...

( hydrogen-3), while natural

oxygen Oxygen is a chemical element; it has chemical symbol, symbol O and atomic number 8. It is a member of the chalcogen group (periodic table), group in the periodic table, a highly reactivity (chemistry), reactive nonmetal (chemistry), non ...

(

oxygen-16 Oxygen-16 (symbol: 16O or ) is a nuclide. It is a stable isotope of oxygen, with 8 neutrons and 8 protons in its nucleus, and when not ionized, 8 electrons orbiting the nucleus. Oxygen-16 has a mass of . It is the most abundant isotope of oxyg ...

) requires three captures to become unstable oxygen-19. Thus water is relatively difficult to activate, as compared to

sodium chloride Sodium chloride , commonly known as Salt#Edible salt, edible salt, is an ionic compound with the chemical formula NaCl, representing a 1:1 ratio of sodium and chloride ions. It is transparent or translucent, brittle, hygroscopic, and occurs a ...

( Na Cl), in which both the sodium and chlorine atoms become unstable with a single capture each. These facts were experienced at the ''

Operation Crossroads Operation Crossroads was a pair of nuclear weapon tests conducted by the United States at Bikini Atoll in mid-1946. They were the first nuclear weapon tests since Trinity on July 16, 1945, and the first detonations of nuclear devices sinc ...

'' atomic test series in 1946.

Examples

An example of this kind of a nuclear reaction occurs in the production of

cobalt-60 Cobalt-60 (Co) is a synthetic radioactive isotope of cobalt with a half-life of 5.2714 years. It is produced artificially in nuclear reactors. Deliberate industrial production depends on neutron activation of bulk samples of the monoisotop ...

within a

nuclear reactor A nuclear reactor is a device used to initiate and control a Nuclear fission, fission nuclear chain reaction. They are used for Nuclear power, commercial electricity, nuclear marine propulsion, marine propulsion, Weapons-grade plutonium, weapons ...

: The cobalt-60 then decays by the emission of a

beta particle A beta particle, also called beta ray or beta radiation (symbol β), is a high-energy, high-speed electron or positron emitted by the radioactive decay of an atomic nucleus, known as beta decay. There are two forms of beta decay, β− decay and � ...

plus

gamma ray A gamma ray, also known as gamma radiation (symbol ), is a penetrating form of electromagnetic radiation arising from high energy interactions like the radioactive decay of atomic nuclei or astronomical events like solar flares. It consists o ...

s into

nickel Nickel is a chemical element; it has symbol Ni and atomic number 28. It is a silvery-white lustrous metal with a slight golden tinge. Nickel is a hard and ductile transition metal. Pure nickel is chemically reactive, but large pieces are slo ...

-60. This reaction has a half-life of about 5.27 years, and due to the availability of cobalt-59 (100% of its

natural abundance In physics, natural abundance (NA) refers to the abundance of isotopes of a chemical element as naturally found on a planet. The relative atomic mass (a weighted average, weighted by mole-fraction abundance figures) of these isotopes is the ato ...

), this neutron bombarded isotope of

cobalt Cobalt is a chemical element; it has Symbol (chemistry), symbol Co and atomic number 27. As with nickel, cobalt is found in the Earth's crust only in a chemically combined form, save for small deposits found in alloys of natural meteoric iron. ...

is a valuable source of

nuclear radiation Ionizing (ionising) radiation, including nuclear radiation, consists of subatomic particles or electromagnetic waves that have enough energy per individual photon or particle to ionize atoms or molecules by detaching electrons from them. Some par ...

(namely gamma radiation) for

radiotherapy Radiation therapy or radiotherapy (RT, RTx, or XRT) is a treatment using ionizing radiation, generally provided as part of cancer therapy to either kill or control the growth of malignant cells. It is normally delivered by a linear particle ...

. : + → In other cases, and depending on the

kinetic energy In physics, the kinetic energy of an object is the form of energy that it possesses due to its motion. In classical mechanics, the kinetic energy of a non-rotating object of mass ''m'' traveling at a speed ''v'' is \fracmv^2.Resnick, Rober ...

of the neutron, the capture of a neutron can cause

—the splitting of the atomic nucleus into two smaller nuclei. If the fission requires an input of energy, that comes from the kinetic energy of the neutron. An example of this kind of fission in a light element can occur when the stable isotope of

lithium Lithium (from , , ) is a chemical element; it has chemical symbol, symbol Li and atomic number 3. It is a soft, silvery-white alkali metal. Under standard temperature and pressure, standard conditions, it is the least dense metal and the ...

lithium-7 Naturally occurring lithium (3Li) is composed of two stable isotopes, lithium-6 (6Li) and lithium-7 (7Li), with the latter being far more abundant on Earth. Both of the natural isotopes have an unexpectedly low nuclear binding energy per nucle ...

, is bombarded with fast neutrons and undergoes the following nuclear reaction: : + → + + +

s +

In other words, the capture of a neutron by lithium-7 causes it to split into an energetic

helium Helium (from ) is a chemical element; it has chemical symbol, symbol He and atomic number 2. It is a colorless, odorless, non-toxic, inert gas, inert, monatomic gas and the first in the noble gas group in the periodic table. Its boiling point is ...

nucleus (

), a hydrogen-3 (

) nucleus and a free neutron. The

Castle Bravo Castle Bravo was the first in a series of high-yield thermonuclear weapon design tests conducted by the United States at Bikini Atoll, Marshall Islands, as part of ''Operation Castle''. Detonated on 1 March 1954, the device remains the most powe ...

accident, in which the thermonuclear bomb test at

Bikini Atoll Bikini Atoll ( or ; Marshallese language, Marshallese: , , ), known as Eschscholtz Atoll between the 19th century and 1946, is a coral reef in the Marshall Islands consisting of 23 islands surrounding a central lagoon. The atoll is at the no ...

in 1954 exploded with 2.5 times the expected yield, was caused by the unexpectedly high probability of this reaction. In the area around a

pressurized water reactor A pressurized water reactor (PWR) is a type of light-water nuclear reactor. PWRs constitute the large majority of the world's nuclear power plants (with notable exceptions being the UK, Japan, India and Canada). In a PWR, water is used both as ...

boiling water reactor A boiling water reactor (BWR) is a type of nuclear reactor used for the generation of electrical power. It is the second most common type of electricity-generating nuclear reactor after the pressurized water reactor (PWR). BWR are thermal neutro ...

during normal operation, a significant amount of radiation is produced due to the fast neutron activation of coolant water oxygen via a (n,p) reaction. The activated oxygen-16 nucleus emits a proton (hydrogen nucleus), and transmutes to nitrogen-16, which has a very short life (7.13 seconds) before decaying back to oxygen-16 (emitting 10.4 MeV beta particles and 6.13 MeV gamma radiations). : + → + (Decays rapidly) : → + + This activation of the coolant water requires extra biological shielding around the nuclear reactor plant. It is the high energy gamma ray in the second reaction that causes the major concern. This is why water that has recently been inside a nuclear reactor core must be shielded until this radiation subsides. One to two minutes is generally sufficient. In facilities that housed a cyclotron, the

reinforced concrete Reinforced concrete, also called ferroconcrete or ferro-concrete, is a composite material in which concrete's relatively low tensile strength and ductility are compensated for by the inclusion of reinforcement having higher tensile strength or ...

foundation can become radioactive due to neutron activation. Six important long-lived radioactive isotopes
⁵⁴Mn
⁵⁵Fe, ⁶⁰Co
⁶⁵Zn¹³³Ba
an
¹⁵²Eu
can be found within concrete nuclei affected by neutrons. The residual radioactivity is predominantly due to trace elements present, and thus the amount of radioactivity derived from cyclotron activation is minuscule, i.e., pCi/g or Bq/g. The release limit for facilities with residual radioactivity is 25 mrem/year. An example of ⁵⁵Fe production from the activation of iron in reinforcement bars found in concrete is shown below: : + →

Occurrence

Neutron activation is the only common way that a stable material can be induced into becoming intrinsically radioactive. Activation is inherently different than contamination. Neutrons are only free in quantity in the microseconds of a nuclear weapon's explosion, in an active nuclear reactor, or in a

spallation Spallation is a process in which fragments of material (spall) are ejected from a body due to impact or stress. In the context of impact mechanics it describes ejection of material from a target during impact by a projectile. In planetary p ...

neutron source. In an atomic weapon, neutrons are generated for only between 1 and 50 microseconds, but in huge numbers. Most are absorbed by the metallic bomb casing, which is only just starting to be affected by the explosion within it. The neutron activation of the soon-to-be vaporized metal is responsible for a significant portion of the

nuclear fallout Nuclear fallout is residual radioactive material that is created by the reactions producing a nuclear explosion. It is initially present in the mushroom cloud, radioactive cloud created by the explosion, and "falls out" of the cloud as it is ...

in nuclear bursts high in the atmosphere. In other types of activation, neutrons may irradiate soil that is dispersed in a mushroom cloud at or near the Earth's surface, resulting in fallout from activation of soil chemical elements.

Effects on materials over time

In any location with high

neutron flux The neutron flux is a scalar quantity used in nuclear physics and nuclear reactor physics. It is the total distance travelled by all free neutrons per unit time and volume. Equivalently, it can be defined as the number of neutrons travelling ...

es, such as within the cores of nuclear reactors, neutron activation contributes to material erosion and periodically the lining materials themselves must be disposed of, as low-level

radioactive waste Radioactive waste is a type of hazardous waste that contains radioactive material. It is a result of many activities, including nuclear medicine, nuclear research, nuclear power generation, nuclear decommissioning, rare-earth mining, and nuclear ...

. Some materials are more subject to neutron activation than others, so a suitably chosen low-activation material can significantly reduce this problem (see International Fusion Materials Irradiation Facility). For example, Chromium-51 will form by neutron activation in chrome steel (which contains Cr-50) that is exposed to a typical reactor neutron flux.

Carbon-14 Carbon-14, C-14, C or radiocarbon, is a radioactive isotope of carbon with an atomic nucleus containing 6 protons and 8 neutrons. Its presence in organic matter is the basis of the radiocarbon dating method pioneered by Willard Libby and coll ...

, most frequently but not solely, generated by the neutron activation of atmospheric nitrogen-14 with a

thermal neutron The neutron detection temperature, also called the neutron energy, indicates a free neutron's kinetic energy, usually given in electron volts. The term ''temperature'' is used, since hot, thermal and cold neutrons are moderated in a medium wit ...

, is (together with its dominant natural production pathway from cosmic ray-air interactions and historical production from atmospheric nuclear testing) also generated in comparatively minute amounts inside many designs of nuclear reactors which contain nitrogen gas impurities in their fuel cladding, coolant water and by neutron activation of the oxygen contained in the water itself.

Fast breeder reactor A breeder reactor is a nuclear reactor that generates more fissile material than it consumes. These reactors can be Nuclear fuel, fueled with more-commonly available isotopes of uranium and Isotopes of thorium, thorium, such as uranium-238 and t ...

s (FBR) produce about an order of magnitude less C-14 than the most common reactor type, the

, as FBRs do not use water as a primary coolant.

Uses

Radiation safety

For physicians and radiation safety officers, activation of sodium in the human body to sodium-24, and phosphorus to phosphorus-32, can give a good immediate estimate of acute accidental neutron exposure.

Neutron detection

One way to demonstrate that

nuclear fusion Nuclear fusion is a nuclear reaction, reaction in which two or more atomic nuclei combine to form a larger nuclei, nuclei/neutrons, neutron by-products. The difference in mass between the reactants and products is manifested as either the rele ...

has occurred inside a fusor device is to use a

Geiger counter A Geiger counter (, ; also known as a Geiger–Müller counter or G-M counter) is an electronic instrument for detecting and measuring ionizing radiation with the use of a Geiger–Müller tube. It is widely used in applications such as radiat ...

to measure the gamma ray radioactivity that is produced from a sheet of

aluminium foil Aluminium foil (or aluminum foil in American English; occasionally called tin foil) is aluminium prepared in thin metal leaves. The foil is pliable and can be readily bent or wrapped around objects. Thin foils are fragile and are sometimes ...

. In the ICF fusion approach, the fusion yield of the experiment (directly proportional to neutron production) is usually determined by measuring the gamma-ray emissions of aluminium or copper neutron activation targets. Aluminium can capture a neutron and generate radioactive

sodium-24 There are 20 isotopes of sodium (11Na), ranging from to (except for the still-unknown 36Na and 38Na), and five isomers (two for , and one each for , , and ). is the only stable (and the only primordial) isotope. It is considered a monoisotopi ...

, which has a half life of 15 hours and a beta decay energy of 5.514 MeV. The activation of a number of test target elements such as

sulfur Sulfur ( American spelling and the preferred IUPAC name) or sulphur ( Commonwealth spelling) is a chemical element; it has symbol S and atomic number 16. It is abundant, multivalent and nonmetallic. Under normal conditions, sulfur atoms ...

, copper,

tantalum Tantalum is a chemical element; it has Symbol (chemistry), symbol Ta and atomic number 73. It is named after Tantalus, a figure in Greek mythology. Tantalum is a very hard, ductility, ductile, lustre (mineralogy), lustrous, blue-gray transition ...

, and

gold Gold is a chemical element; it has chemical symbol Au (from Latin ) and atomic number 79. In its pure form, it is a brightness, bright, slightly orange-yellow, dense, soft, malleable, and ductile metal. Chemically, gold is a transition metal ...

have been used to determine the yield of both pure fission and

thermonuclear weapon A thermonuclear weapon, fusion weapon or hydrogen bomb (H-bomb) is a second-generation nuclear weapon design. Its greater sophistication affords it vastly greater destructive power than first-generation nuclear bombs, a more compact size, a lowe ...

Materials analysis

Neutron activation analysis Neutron activation analysis (NAA) is a nuclear reaction, nuclear process used for determining the concentrations of chemical element, elements in many materials. NAA allows discrete Sampling (statistics), sampling of elements as it disregards the ...

is one of the most sensitive and precise methods of trace element analysis. It requires no sample preparation or solubilization and can therefore be applied to objects that need to be kept intact such as a valuable piece of art. Although the activation induces radioactivity in the object, its level is typically low and its lifetime may be short, so that its effects soon disappear. In this sense, neutron activation is a non-destructive analysis method. Neutron activation analysis can be done in situ. For example, aluminium (Al-27) can be activated by capturing relatively low-energy neutrons to produce the isotope Al-28, which decays with a half-life of 2.3 minutes with a decay energy of 4.642 MeV. This activated isotope is used in oil drilling to determine the

clay Clay is a type of fine-grained natural soil material containing clay minerals (hydrous aluminium phyllosilicates, e.g. kaolinite, ). Most pure clay minerals are white or light-coloured, but natural clays show a variety of colours from impuriti ...

content (clay is generally an alumino-silicate) of the underground area under exploration. Historians can use neutron activation products to authenticate atomic artifacts and materials subjected to neutron fluxes from fission incidents. For example, one of the rare isotopes found in

trinitite Trinitite, also known as atomsite or Alamogordo glass, is the glassy residue left on the desert floor after the plutonium-based Trinity (nuclear test), Trinity nuclear bomb test on July 16, 1945, near Alamogordo, New Mexico. The glass is primaril ...

is barium-133, an activation product formed from the Baratol used in the slow explosive

lens A lens is a transmissive optical device that focuses or disperses a light beam by means of refraction. A simple lens consists of a single piece of transparent material, while a compound lens consists of several simple lenses (''elements'') ...

employed in the Trinity device. This barium isotope can be used to authenticate trinitite samples, with its absence indicating a fraudulent sample.

Semiconductor production

Neutron irradiation may be used for float-zone silicon slices ( wafers) to trigger fractional transmutation of Si atoms into phosphorus (P) and therefore doping it into n-type silicon :

\ce + \mathrm \xrightarrow \ce + \gamma\mathrm\xrightarrow\ce + \beta\mathrm

References

External links

Neutron Activation Analysis webHandbook on Nuclear Activation Cross-Sections, IAEA, 1974
* ttps://web.archive.org/web/20150924072849/http://www.physics.rutgers.edu/~abragg/110/lecture16.html Neutron capture as it relates to nucleosynthesisbr>Neutron capture and the Chart of the nuclidesThe chart of the NuclidesDiscovery of the Chromium isotopes, Chromium-55 by Cr-54 neutron captureORILL
: 1D transmutation, fuel depletion, and radiological protection code